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Fullerene derivative micrometer flower and preparation method thereof

A technology of fullerene derivatives and micron flowers, applied in organic chemistry and other fields, can solve the problems of large powder size and inability to obtain products, and achieve the effects of increased specific surface area, cheap raw materials, and low production costs

Inactive Publication Date: 2013-09-25
HUANGSHAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Although this powdery product has a wide range of uses, it is difficult to play a better role in the fields of detergents, catalysts, and hydrophobic materials because of its large powder size; besides, its preparation method cannot obtain a smaller scale. product of

Method used

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  • Fullerene derivative micrometer flower and preparation method thereof
  • Fullerene derivative micrometer flower and preparation method thereof
  • Fullerene derivative micrometer flower and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] The concrete steps of preparation are:

[0025] Concentration is the N-methyl-2-[4-dimethylamino] phenyl-3,4-fullerenyl pyrrolidine carbon tetrachloride solution that concentration is 0.75g / L and concentration is 7mmol / L ten After mixing the hexaalkyltrimethylammonium bromide isopropanol solution, stir at 10°C for 30 minutes to obtain a mixed solution; wherein, N-methyl-2-[4-dimethylamino]phenyl-3 , The volume ratio of 4-fullerenylpyrrolidine carbon tetrachloride solution to cetyltrimethylammonium bromide isopropanol solution is 1:1. After the mixed solution is alternately subjected to solid-liquid separation and washing for 3 times, it is placed at room temperature and dried for 10 minutes; wherein, the solid-liquid separation process is centrifugation, and the rotating speed during centrifugation is 4000r / min, and the time is 12min, the washing process is to use ethanol to clean the solid matter obtained after centrifugation, and obtain a product similar to figure 1...

Embodiment 2

[0027] The concrete steps of preparation are:

[0028] Concentration is the N-methyl-2-[4-dimethylamino] phenyl-3,4-fullerenyl pyrrolidine carbon tetrachloride solution that concentration is 1.06g / L and the decathyl chloride solution that concentration is 6mmol / L After mixing the hexaalkyltrimethylammonium bromide isopropanol solutions, stir at 17°C for 28 minutes to obtain a mixed solution; wherein, N-methyl-2-[4-dimethylamino]phenyl-3 , The volume ratio of 4-fullerenylpyrrolidine carbon tetrachloride solution to cetyltrimethylammonium bromide isopropanol solution is 1:2.3. After the solid-liquid separation and washing treatment were carried out alternately to the mixed solution for 3 times, it was placed at normal temperature and dried for 10 minutes; wherein, the solid-liquid separation process was centrifugation, and the rotating speed during centrifugation was 4500r / min, and the time was 11min, the washing process is to use ethanol to clean the solid matter obtained afte...

Embodiment 3

[0030] The concrete steps of preparation are:

[0031] Concentration is the N-methyl-2-[4-dimethylamino] phenyl-3,4-fullerenyl pyrrolidine carbon tetrachloride solution of 1.37g / L and the decathyl chloride solution of 5mmol / L After mixing the hexaalkyltrimethylammonium bromide isopropanol solutions, stir at 25°C for 25 minutes to obtain a mixed solution; wherein, N-methyl-2-[4-dimethylamino]phenyl-3 , The volume ratio of 4-fullerenylpyrrolidine carbon tetrachloride solution to cetyltrimethylammonium bromide isopropanol solution is 1:3.5. After carrying out 4 times of solid-liquid separation and washing alternately to the mixed solution, it is placed at normal temperature and dried for 10 minutes; wherein, the solid-liquid separation process is centrifugation, and the rotating speed during centrifugation is 5000r / min, and the time is 10min, the washing treatment is to use ethanol to clean the solid matter obtained after centrifugation, and obtain such as figure 1 and figure...

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Abstract

The invention discloses a fullerene derivative micrometer flower and a preparation method thereof. The micrometer flower is formed by a fullerene C60 derivative, and particularly is formed by the fullerene C60 derivative N-methyl-2-[4-dimethylamino] phenyl-3,4-fulleropyrrolidine which is shaped like a spherical flower, and the spherical flower is formed by mutually crossed and standing micrometer fragments having a fragment length of 3-5[mu]m, a fragment height of 1-3[mu]m, and a fragment thickness of 20-30 [mu]m, and is of a single crystalline state structure. The method comprises the following steps: a carbon tetrachloride solution of the N-methyl-2-[4-dimethylamino] phenyl-3,4-fulleropyrrolidine and an isopropanol solution of hexadecyl trimethyl ammonium bromide are mixed and stirred to obtain a mixed liquor, wherein the volume ratio of the carbon tetrachloride solution of the N-methyl-2-[4-dimethylamino] phenyl-3,4-fulleropyrrolidine and the isopropanol solution of hexadecyl trimethyl ammonium bromide is 1:1-6. The mixed liquor is treated by alternative solid-liquid separating and washing and then the fullerene derivative micrometer flower is obtained. The fullerene derivative micrometer flower can be widely used in the field of cleaning agents, catalyst and hydrophobic materials and the like.

Description

technical field [0001] The invention relates to a derivative micron flower and a preparation method thereof, in particular to a fullerene derivative micron flower and a preparation method thereof. Background technique [0002] Existing studies have shown that N-methyl-2-[4-dimethylamino]phenyl-3,4-fullerenylpyrrolidine, one of the fullerene C60 derivatives, can be widely used in Optical materials, detergents, catalysts, hydrophobic materials and animal anti-cancer substances in the medical field. Recently, various efforts have been made to obtain N-methyl-2-[4-dimethylamino]phenyl-3,4-fullerenylpyrrolidine, such as Photoinduced Intramolecular Electron Transfer in a Bridged C 60 (Acceptor)-Aniline (Donor) System. Photophysical Properties of the First “Active” Fullerene Diad, J.Am.Chem.Soc.1995, 117, 4093-4099 (in C 60 (Electron-withdrawing group)-aniline (electron-donating group) as a bridge system, through photo-induced intramolecular electron transfer, studying the physic...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07D209/70
Inventor 黄飞魏先文
Owner HUANGSHAN UNIV
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