Preparation method of plant-fiber foamed cement based heat insulating material for buildings

A plant fiber and foamed cement technology, applied in the field of building materials, can solve the problems of uneven mixing, easy aging, poor interface performance, etc., and achieve the effect of reducing the possibility of interface fracture, good thermal insulation performance, and enhanced crack resistance performance.

Inactive Publication Date: 2015-05-27
WUHAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The existing plant fiber building materials are a series of building materials produced by crushing one of various waste crop straws into plant fibers, adding reinforcing materials and bonding materials, including plant fiber cement hollow wall panels, plant Fiber gypsum reinforced blocks, plant fiber roof panels, etc. Most of these materials are directly mixed and bonded by plant fibers and cementitious materials. Generally, there are uneven mixing, easy aging, poor interface performance, and thermal insulation performance that cannot meet the requirements of energy-saving standards. And other issues
[0004] At present, there are many patents on the use of cement and plant fibers to prepare plant fiber cement composite building materials, such as a waste brick tile / straw foam concrete and its preparation method with the publication number of 102464497A, in which the plant fibers are only passed through alkali Direct use after soaking in the solution does not completely disperse the plant fibers. The plant fibers contain more impurities, and the bonding interface with other materials affects the performance of the material, and the lye is not fully utilized, which is likely to cause secondary pollution.
And the publication number is 102199044A a kind of composite fiber reinforced concrete and its preparation method, wherein the fiber mixed is the composite of chemical fiber and plant fiber, the mixing amount of plant fiber is low, the utilization rate of straw is low, and it is not environmentally friendly. purpose, and the surface of the plant fiber used has not been modified, the toughness is poor, and the combination with the cementitious material is poor

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] Example 1: First, put corn stalks with a length of 20-30mm in dilute H at a concentration of 0.1 mol / L 2 SO 4 Soak in the solution for 1 hour and rinse until it is neutral. Add the special grade rosin and industrial gelatin in a ratio of 1:4:4 by mass ratio of plant fiber, special grade rosin and industrial gelatin. After adjusting the pH to 14, the solution is heated to 90°C. Stir for 120 minutes, after stopping heating, add dimethyl silicone oil to treat the surface of the plant fiber, and cool to room temperature; then stir the above-mentioned fiber mixture in a mixer with a rotation speed of 1000r / min for 3 minutes to foam to obtain fiber foam; Ordinary Portland cement is made into a slurry with a ratio of 0.4, then the fiber foam and the slurry are mixed at a ratio of 1:10, stirred evenly, and directly poured into the shape to obtain the final product with a density of 614kg / m 3 , The thermal conductivity can reach 0.1556W / m·K, the equilibrium moisture content is 0.2-...

Embodiment 2

[0017] Example 2: First, put corn stalks with a length of 20-30mm in dilute H at a concentration of 0.1 mol / L 2 SO 4 Soak in the solution for 1 hour, rinse until it is neutral, add first-grade rosin and industrial gelatin in a ratio of 1:2:6 by mass ratio of plant fiber, first-grade rosin, and industrial gelatin. After adjusting the pH to 14, increase the temperature of the solution to 90 ℃, stir for 120min, stop heating, add dimethyl silicone oil to treat the surface of the plant fiber, and cool to room temperature; then stir the above-mentioned fiber mixture in a mixer with a rotation speed of 1000r / min for 3min to foam; according to the water-cement ratio of 0.4 The ordinary Portland cement is made into a slurry, and then the fiber foam and cement slurry are mixed at a ratio of 1:8, stirred evenly, and directly poured into the shape to obtain the final product, with a density of 601kg / m 3 , The thermal conductivity can reach 0.1487W / m·K, the equilibrium moisture content is 0.2...

Embodiment 3

[0018] Example 3: First, the corn stalks with a length of 20-30 mm are mixed in dilute H with a concentration of 0.2 mol / L 2 SO 4 Soak in the solution for 1 hour, rinse until it is neutral, add first-grade rosin and industrial gelatin in a ratio of 1:2:6 by mass ratio of plant fiber, first-grade rosin, and industrial gelatin. After adjusting the pH to 14, increase the temperature of the solution to 90 ℃, stir for 120min, stop heating, add dimethyl silicone oil to treat the surface of the plant fiber, cool to room temperature; then stir the above-mentioned fiber mixture in a mixer with a rotation speed of 1000r / min for 3min to foam; according to the water-cement ratio of 0.3 The ordinary Portland cement is made into a slurry, and then the fiber foam and the cement slurry are mixed at a ratio of 1:6, mixed evenly, and directly poured into the shape to obtain the final product with a density of 587kg / m 3 , The thermal conductivity can reach 0.1401W / m·K, the equilibrium moisture cont...

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Abstract

The invention specifically relates to a preparation method of a plant-fiber foamed cement based heat insulating material for buildings. The preparation method comprises the following steps of: firstly, soaking plant fibers in dilute sulphuric acid with concentration being 0.1-0.2 mol / L for 50-80min, flushing until neutral, adding rosin and gelatin to the plant fibers in a mass ratio of plant fibers: rosin: gelatin being 1: (2-8): (2-10), regulating the pH value to 12-14, and then heating the solution to 85-90 DEG C, stirring for 120-150min, adding a fiber surface modifier after stopping heating, and then cooling to the room temperature, thus obtaining a fiber mixed solution; in use, stirring and foaming the fiber mixed solution in a stirrer having a rotating speed being 600 to 5000r / min for 2-4 min so as to obtain fiber foams; and then adding the fiber foams to cement and moulding, thus obtaining the plant-fiber foamed cement based heat insulating material. The plant-fiber foamed cement based material provided by the invention has the characteristics of excellent thermal insulation properties, low density, air shrinkage resistance, crack resistance and toughening, humidifying and the like.

Description

Technical field [0001] The invention specifically relates to a method for preparing a plant fiber foam cement-based thermal insulation material for building, which is mainly used in the field of building materials. Background technique [0002] Our country is a big agricultural country, with abundant agricultural and sideline products, many varieties and large quantities. According to statistics from relevant departments, the total annual output of crop straw in my country exceeds 700 million tons, including 213 million tons of rice straw, 112 million tons of wheat straw, 212 million tons of corn straw, and 200 million tons of other crop straw. However, in my country, the utilization rate of straw is very low, accounting for only about 5%. After the crops are harvested, in order to ensure the re-cultivation of the land, a large amount of crop stalks are burned, which not only wastes a lot of natural resources, but also pollutes the environment, causing serious carbon dioxide and...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B28/04C04B28/06C04B28/08C04B16/02
Inventor 蹇守卫汪婷马保国苏雷蔡礼雄
Owner WUHAN UNIV OF TECH
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