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Organic carrier for crystalline silicon solar cell electrode slurry and preparation method thereof

A solar cell and electrode slurry technology, applied to conductive materials dispersed in non-conductive inorganic materials, applications, household appliances, etc., can solve the problem of ignoring the recovery of slurry shear thinning characteristic viscosity and increasing the electrode grid line Problems such as shading area and affecting conversion efficiency can be achieved to improve rheological characteristics and process performance, low cost and good storage stability

Active Publication Date: 2013-12-11
NAT UNIV OF DEFENSE TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, the traditional organic vehicle only pays attention to the fluidity of the slurry, that is, the printability, but ignores the shear thinning characteristics of the slurry and the viscosity recovery after shear thinning, resulting in the preparation of the slurry in the printing of large height and width. There are difficulties in the thinner electrode grid lines, and the printed film layer is easy to collapse, which makes the film layer wider and lower in height, which in turn increases the shading area of ​​the electrode grid lines and affects the conversion efficiency.

Method used

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  • Organic carrier for crystalline silicon solar cell electrode slurry and preparation method thereof
  • Organic carrier for crystalline silicon solar cell electrode slurry and preparation method thereof
  • Organic carrier for crystalline silicon solar cell electrode slurry and preparation method thereof

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Embodiment 1

[0039]An organic vehicle for crystalline silicon solar cell electrode paste of the present invention comprises the following components: 1.04g organic resin, 9.07g organic solvent, 0.5g thixotropic agent and 0.5g wetting and dispersing agent, wherein the organic resin consists of 0.187 g ethyl cellulose 200, 0.053 g ethyl cellulose 300 and 0.8 g acrylic resin NeoCryl B-723, the organic solvent consists of 5.57 g alcohol ester dodeca (i.e. 2,2,4-trimethyl-1,3- Pentylene glycol monoisobutyrate) and 3.5g dimethyl nylon acid (DBE), the thixotropic agent is 0.5g polyamide wax MT ST, the wetting and dispersing agent is 0.5g N-tallow-1,3- Propylenediamine dioleate, HLB value 12.

[0040] A method for preparing an organic carrier for the above-mentioned crystalline silicon solar cell electrode paste of the present invention, comprising the following steps:

[0041] (1) Dissolution of organic resin: Weigh 0.187g of ethyl cellulose 200, 0.053g of ethyl cellulose 300 and 0.8g of acrylic...

Embodiment 2

[0049] An organic vehicle for crystalline silicon solar cell electrode paste of the present invention comprises the following components: 2.86g organic resin, 15.103g organic solvent, 1.0g thixotropic agent and 0.5g wetting and dispersing agent, wherein the organic resin consists of 0.28 g ethyl cellulose 200, 0.08 g ethyl cellulose 300 and 2.5 g acrylic resin NeoCryl B-842, the organic solvent is composed of 8.355 g alcohol ester dodeca and 6.748 g DBE, the thixotropic agent is 1.0 g polyamide wax MT ST, wetting and dispersing agent is 0.5g N-tallow-1,3-propanediamine dioleate, HLB value is 12.

[0050] A method for preparing an organic carrier for the above-mentioned crystalline silicon solar cell electrode paste of the present invention, comprising the following steps:

[0051] (1) Dissolution of organic resin: Weigh 0.28g of ethyl cellulose 200, 0.08g of ethyl cellulose 300 and 2.5g of acrylic resin NeoCryl B-842 as organic resin components, 8.355g of alcohol ester dodeca ...

Embodiment 3

[0058] An organic vehicle for crystalline silicon solar cell electrode paste of the present invention comprises the following components: 2.86g organic resin, 17.488g organic solvent, 1.0g thixotropic agent and 0.5g wetting and dispersing agent, wherein the organic resin consists of 0.28 g ethyl cellulose 200, 0.08 g ethyl cellulose 300 and 2.5 g acrylic resin NeoCryl B-805, the organic solvent is composed of 10.74 g alcohol ester dodeca and 6.748 g DBE, the thixotropic agent is 1.0 g polyamide wax MT ST, wetting and dispersing agent is 0.5g N-tallow-1,3-propanediamine dioleate, HLB value is 12.

[0059] A method for preparing an organic carrier for the above-mentioned crystalline silicon solar cell electrode paste of the present invention, comprising the following steps:

[0060] (1) Dissolution of organic resin: Weigh 0.28g of ethyl cellulose 200, 0.08g of ethyl cellulose 300 and 2.5g of acrylic resin NeoCryl B-805 as organic resin components, 10.74g of alcohol ester dodeca ...

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Abstract

The invention discloses an organic carrier for crystalline silicon solar cell electrode slurry and a preparation method thereof. The organic carrier comprises the following components by mass percent: 5-20% of organic resin, 60-85% of an organic solvent, 1-10% of a thixotropic agent and 1-10% of a wetting dispersant. The preparation method comprises the following steps: (1) mixing and dissolving the organic resin and the organic solvent to obtain transparent resin solution; and (2) adding the thixotropic agent and the wetting dispersant to the transparent resin solution to mix and activate, so as to obtain the organic carrier for the crystalline silicon solar cell electrode slurry. The organic carrier disclosed by the invention is good in thixotropy, significant in shear thinning effect, high in printing resolution, simple in preparation method and process, convenient to operate and low in cost, and can print a thin electrode grid line with large depth-width ratio.

Description

technical field [0001] The invention relates to the field of crystalline silicon solar cells, in particular to an organic carrier for crystalline silicon solar cell electrode paste and a preparation method thereof. Background technique [0002] For crystalline silicon solar cells, in order to output the electric energy of the battery, two positive and negative electrodes must be made on the battery. The current manufacturing method of electrodes for commercial crystalline silicon solar cells is to print rear aluminum paste, rear silver paste and front silver paste respectively on the manufactured silicon wafers, and then form electrodes by co-firing once. The back aluminum, back silver and front silver pastes, which are necessary materials in the metallization process of crystalline silicon solar cells, are the key materials required for the production of crystalline silicon solar cell devices, and their performance will directly affect the performance of crystalline silicon...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L1/28C08L33/00C08L93/04C08L61/06C09D11/14C09D11/10C09D11/08H01B1/22H01B1/16
Inventor 刘卓峰张为军白书欣秦峻马振兴曾长光
Owner NAT UNIV OF DEFENSE TECH
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