Method for jointly producing hydrogen and methane by carrying out coupling anaerobic fermentation on preprandial garbage and kitchen garbage

A technology for kitchen waste and pre-meal waste, applied in fermentation, biosynthesis, waste fuel, etc., can solve the problems of increasing the cost of anaerobic fermentation, fast acidification, slow system startup, etc., to improve energy utilization efficiency, The effect of increasing organic load and shortening start-up time

Active Publication Date: 2013-12-18
CHINESE RES ACAD OF ENVIRONMENTAL SCI
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Problems solved by technology

At present, the overall one-stage method occupies a dominant position in China's food waste treatment industry. Its main advantages are less investment, simple process operation, and short gas production cycle, but its shortcomings are also obvious. Compared with the two-stage process, the overall one-stage process In terms of the method, the gas production fluctuates greatly, and it is difficult to achieve precise control in the process, thereby affecting the stability of the long-term operation of the system. Moreover, when it is applied to the fermentation of mixed materials, the fermentation cycle of different materials is quite different, and it is difficult to achieve high organic matter in the materials. Efficient utilization, incomplete material treatment is more obvious, and a large amount of biogas residue and biogas slurry produced cannot meet the discharge standard, and usually needs to be treated again, which increases the cost of anaerobic fermentation
Food waste is often mixed with pre-meal waste. Pre-meal waste is mainly vegetable leaves, semi-rotten fruits and vegetables and other plant residues with high cellulose content. Food waste is mainly leftovers mixed together, and its oil content, moisture content, and organic matter content are high. When anaerobic fermentation is performed, the acidification speed is usually fast, resulting in the system generally operating under low load, and it is difficult to maintain the stability of the system operation.
The optimal conditions for the cogeneration of hydrogen and methane for these two kinds of waste are different, and the overall treatment technology is not perfect enough. Further systematic research is needed on how to further improve the energy recovery efficiency of food waste.
[0004] Therefore, it is necessary to develop a method of using different pretreatment methods to treat pre-meal and kitchen waste separately, and to couple pre-meal waste and kitchen waste for anaerobic fermentation to co-produce hydrogen and methane, so that the advantages of the two can complement each other and effectively improve the kitchen Waste energy recovery efficiency, and can ensure the long-term stable operation of the anaerobic fermentation cogeneration reactor, not only solves the problem that food waste is difficult to dispose of by traditional methods, and is prone to secondary pollution, but also treats food waste more than ordinary anaerobic fermentation technology Garbage improves the ability to produce green bio-energy, reduces dependence on traditional energy materials, and contributes to the optimization of my country's energy structure, improvement of sustainable development capabilities, and improvement of the ecological environment.

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  • Method for jointly producing hydrogen and methane by carrying out coupling anaerobic fermentation on preprandial garbage and kitchen garbage
  • Method for jointly producing hydrogen and methane by carrying out coupling anaerobic fermentation on preprandial garbage and kitchen garbage
  • Method for jointly producing hydrogen and methane by carrying out coupling anaerobic fermentation on preprandial garbage and kitchen garbage

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Embodiment 1

[0029] Use pre-meal waste and kitchen waste from canteens.

[0030] The pre-meal garbage is crushed to a particle size of 2-20mm, and the anaerobic fermentation broth is filtered through a sieve with a pore size of 1mm to obtain the filtrate, and anaerobic is maintained during the sieve filtration process; the pre-meal garbage and the anaerobic fermentation broth are in a mass ratio of 1: 2 proportion mixing, the mass of pre-meal garbage is calculated on a dry basis; blow with high-purity nitrogen for 5 minutes, and maintain an anaerobic environment, keep the temperature at about 35°C, stir at a rate of 80r / min, stir for 10 minutes per hour, soak for 2 God, to be used;

[0031] Crush the food waste to a particle size of 2-40mm, add water at a rate of 50%, keep the pressure at 2Pa, stir at a rate of 100r / min, heat at 90°C for 30 minutes in wet heat pretreatment, and centrifuge at 8000r / min to remove the buoyant waste after cooling to room temperature. oil, spare;

[0032] The k...

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Abstract

The invention discloses an environment-friendly method for jointly producing hydrogen and methane by carrying out coupling anaerobic fermentation on preprandial garbage and kitchen garbage, and belongs to the technical field of solid waste treatment and biological energy. The method comprises the following steps: firstly carrying out soaking pretreatment on the preprandial garbage by utilizing biogas slurry generated through the anaerobic fermentation, and carrying out damp heat flash evaporation pretreatment on the kitchen garbage; then mixing the pretreated preprandial garbage and kitchen garbage to prepare the hydrogen and the methane through an anaerobic fermentation process by taking biogas residues discharged by a system after a methane production stage as inocula. The method disclosed by the invention is suitable for recovering the biomass energy contained in solid organic matters with multiple high-organic matters, high-water ratio and high-cellulose organic solid wastes in hydrogen and methane forms, integrates energy conservation, emission reduction, renewable resource utilization and pollution control into a whole, is a pollution-free, low-energy consumption and high-productive capacity kitchen garbage anaerobic fermentation treatment process and has the advantages of important environmental benefit and wide application prospect.

Description

technical field [0001] The invention belongs to the technical field of solid waste treatment and bioenergy, and relates to a technology for the co-production of hydrogen and methane by anaerobic fermentation, in particular to a green method for coupling anaerobic fermentation of pre-meal garbage and kitchen waste to co-produce hydrogen and methane . Background technique [0002] With the increasing depletion of global non-renewable energy and the environmental air pollution caused by the combustion of fossil fuel energy, it has seriously threatened the sustainable development and living environment of human beings. Hydrogen is considered to be one of the important clean energy sources in the 21st century, and methane is also the most likely renewable energy source to replace natural gas, which has attracted people's attention. Among many biogas preparation methods, anaerobic fermentation has attracted a large number of domestic and foreign scholars to study it because of it...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C12P3/00C12P5/02
CPCY02E50/30Y02P20/59
Inventor 祝超伟李鸣晓夏天明席北斗贾璇宋彩红
Owner CHINESE RES ACAD OF ENVIRONMENTAL SCI
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