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Sulfur-containing tail gas purifying and recycling method

A tail gas purification and tail gas technology, applied in chemical instruments and methods, sulfur compounds, separation methods, etc., can solve the problems of low economic value and high energy consumption of sodium sulfide products, and achieve the effect of reducing energy consumption and high economic value

Active Publication Date: 2014-02-05
XINZHONGTIAN ENVIRONMENTAL PROTECTION
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Problems solved by technology

What this method its alkali washing obtains is sodium sulfide solution, obtains sodium sulfide product through evaporation, crystallization, separation, energy consumption is high, and the economic value of sodium sulfide product is also relatively low

Method used

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  • Sulfur-containing tail gas purifying and recycling method

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Embodiment Construction

[0025] see figure 1 , the implementation process of the inventive method is as follows:

[0026] Firstly, the straight-through sulfur recovery method is used to recover the sulfur-containing tail gas (carbon disulfide tail gas produced from natural gas), according to the O in the air 2 The converted amount is H in the exhaust gas 2 The amount of 1-1.5 times the S content controls the amount of air dosage, so that the tail gas of the once-through sulfur recovery process is mainly hydrogen sulfide.

[0027] 1. Dissolve the purifying agent barium sulfide with steam, let it stand for precipitation and filter, and make a purification solution with a concentration required by the process (concentration is controlled at 25%), store it in the purification solution storage tank, and transport it to the purification treatment with a delivery pump The tower (1 / 3---1 / 2 liquid level of the tower body) is ready for use.

[0028] 2. Pass the tail gas into the purification treatment tower,...

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Abstract

The invention relates to a sulfur-containing tail gas purifying and recycling method. The method comprises the following steps: firstly adopting a direct current sulfur recovery method to recover the sulfur-containing tail gas and controlling the air dosage during recovery; then feeding the tail gas to a purifying column with barium sulfide solution, reacting to obtain a barium sulfite precipitate and a barium carbonate precipitate and exhausting the hydrogen sulfide refined gas, feeding the hydrogen sulfide refined gas to three stages of alkali liquor (sodium hydroxide solution) absorption columns in sequence and discharging the gas up to the standard after absorption; finally concentrating the solution to obtain the solution containing 70% of sodium hydrosulfide and flaking, thus obtaining the sodium hydrosulfide product. By adopting the method, the sodium hydrosulfide product which has higher quality and is widely applied to the industries such as mining, tanning and the like can be produced and up-to-standard exhaust of the tail gas can be realized.

Description

technical field [0001] The invention relates to a sulfur-containing waste gas treatment technology and belongs to the technical field of chemical process application. Background technique [0002] Natural gas wet desulfurization tail gas and the use of natural gas to produce carbon disulfide tail gas are mixed gases containing hydrogen sulfide, carbon dioxide and sulfur dioxide. The traditional treatment method generally adopts the direct-flow sulfur recovery process, and the sulfur recovery rate of the direct-flow sulfur recovery process is 92--98%. , and its tail gas needs to be further incinerated and absorbed before it can be discharged. The residue produced by its incineration and absorption is sodium sulfite or sodium metabisulfite, both of which contain impurities such as sodium sulfide and sodium sulfate, which have basically no economic value and need to be further disposed of as hazardous waste. Therefore, the purification rate of the tail gas by this method is no...

Claims

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Application Information

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IPC IPC(8): B01D53/75B01D53/48C01B17/32
CPCY02P20/151
Inventor 周红星
Owner XINZHONGTIAN ENVIRONMENTAL PROTECTION
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