Electrolyte used for waste lithium battery discharge, and waste lithium battery discharge method

A waste lithium battery and electrolyte technology, applied in the field of electrolyte, can solve the problems of unfeasible large-scale discharge, overheating, corrosion of electrodes, etc., to solve polarization and pollution of reaction products, promote anode reaction, and achieve high reaction speed Effect

Active Publication Date: 2014-03-26
ELECTRIC POWER RES INST OF GUANGDONG POWER GRID
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  • Abstract
  • Description
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  • Application Information

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Problems solved by technology

However, in the process of dissipating the waste lithium-ion batteries in batches (i.e. releasing the residual power inside the waste lithium-ion batteries), due to the process of short circuit and fragmentation during the decomposition process, the residual power of the batteries will be released sharply, causing local overheating and even explosion. Therefore, waste lithium-ion batteries must be fully discharged before recycling, and waste lithium-ion batteries must be de-energized.
[0003] At present, there are mainly two methods for the safe discharge of waste lithium-ion batteries. One is physical discharge, which mainly uses an external load to dissipate electricity, that is, the battery is connected to a resistor, and the power in the battery is consumed through heat release. However, this method It is only a laboratory test, an

Method used

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  • Electrolyte used for waste lithium battery discharge, and waste lithium battery discharge method
  • Electrolyte used for waste lithium battery discharge, and waste lithium battery discharge method
  • Electrolyte used for waste lithium battery discharge, and waste lithium battery discharge method

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[0022] Example 1

[0023] An electrolyte for discharging waste lithium ion batteries, in which CuSO 4 The concentration is 0.1mol / L.

[0024] When investigating the discharge of the electrolyte, a laboratory test method was used, including the following steps:

[0025] Lead the positive and negative electrodes of the used lithium-ion battery with wires and connect them to the nickel sheets respectively, and then put the nickel sheets into the above electrolyte respectively, and then measure the current and / or voltage changes with time during the battery discharge process. At the same time, observe the changes in the surface of the positive and negative nickel sheets in the electrolyte until the current and voltage stabilize, then the discharge ends.

Example Embodiment

[0026] Example 2

[0027] An electrolyte for discharging waste lithium ion batteries, in which CuSO 4 The concentration is 0.3mol / L;

[0028] Please refer to Example 1 for a method for safe discharge of used lithium ion batteries.

Example Embodiment

[0029] Example 3

[0030] An electrolyte for discharging waste lithium ion batteries, in which CuSO 4 The concentration is 0.5mol / L;

[0031] Please refer to Example 1 for a method for safe discharge of used lithium ion batteries.

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Abstract

The invention discloses an electrolyte used for waste lithium battery discharge, and a waste lithium battery discharge method. The electrolyte contains copper sulfate and the concentration of copper sulfate is 0.1-1mol/L; the electrolyte also contains ascorbic acid; and the discharge method comprises a step that a waste lithium battery is immersed in the electrolyte until the voltage tends toward stability. The electrolyte used for waste lithium battery discharge is obtained through a large amount of experiments and researches by the inventors of the invention, and has the advantages of safety, environmental protection, high discharge efficiency, no precipitation of the above solution in the discharge process, and no dissolving loss of the shell of the battery. The waste lithium ion battery discharge method has the advantages of simple technology, easy operation, and suitableness for the industrial application.

Description

technical field [0001] The invention relates to the field of electrolytes, in particular to an electrolyte and a discharge method for discharging waste lithium batteries. Background technique [0002] With the widespread application of lithium-ion batteries, a large number of waste lithium-ion batteries have been produced. At present, waste lithium-ion batteries contain a large amount of toxic rare metal cobalt, but because cobalt is an important strategic metal, the current comparison of waste lithium-ion batteries Research on ion batteries mostly focuses on the recovery and reuse of precious metals. For example, the current ternary lithium batteries also contain precious metals such as manganese and nickel. At the same time, lithium-ion batteries also contain valuable metals such as aluminum and copper. However, in the process of dissipating the waste lithium-ion batteries in batches (i.e. releasing the residual power inside the waste lithium-ion batteries), due to the pro...

Claims

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Application Information

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IPC IPC(8): H01M10/54H01M10/44
CPCY02W30/84H01M10/54
Inventor 魏增福谈天任平刘世念钟国彬苏伟
Owner ELECTRIC POWER RES INST OF GUANGDONG POWER GRID
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