A kind of flue gas desulfurization and denitrification process method

A desulfurization and denitration technology, which is applied in the field of boiler flue gas and refinery FCC flue gas desulfurization and denitrification technology, can solve the problems of unutilized NOx, substandard exhaust particulate matter, excessive ammonia, etc. The effect of improving quality and quantity, and large denitration load

Active Publication Date: 2016-05-18
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0013] CN1895744A introduces a high-dust composite SCR flue gas denitrification process and denitrification catalytic reaction device. This SCR process is mainly aimed at NOx in power plant flue gas, and is not suitable for NOx in FCC flue gas. x governance
[0014] In the denitrification→desulfurization process in the prior art, NOx is first reduced to nitrogen, which consumes a lot of ammonia, and at the same time, NOx is not utilized at all
At the same time, in the follow-up desulfurization process, if the ammonia process is adopted, the problem of non-compliance of exhaust particulate matter cannot be solved

Method used

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Examples

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Comparison scheme
Effect test

Embodiment 1

[0030] The flue gas of a coal-fired boiler has a SOx content of 2050mg / m 3 , NOx content is 1650mg / m 3 .

[0031] By adopting the method of the present invention, the flue gas is washed with water at first, and a packed tower is adopted, and the liquid-gas volume ratio of spraying is 5L / M 3 .

[0032] The washed flue gas enters the desulfurization tower from the bottom. The desulfurization tower adopts a packed tower. The desulfurization tower is divided into two parts, the upper part and the lower part. The liquid phase material and the introduced spray liquid, the introduced spray liquid is a mixture of circulating desulfurization liquid and ammonia water with a mass concentration of 4%, and the pH value of the mixture is 6.4. The volume ratio of the upper and lower fillers is generally 1:4. The upper liquid-gas volume ratio is 5L / M 3 , the lower liquid-gas volume ratio is 8L / M 3 . The total volumetric space velocity of the flue gas passing through the desulfurization...

Embodiment 2

[0036] The flue gas of a coal-fired boiler has a SOx content of 1800mg / m 3 , NOx content is 840mg / m 3 .

[0037] Adopt the method of the present invention, flue gas is washed with water at first, adopt packed tower, the liquid-gas volume ratio of spraying is 4L / M 3 .

[0038] The washed flue gas enters the desulfurization tower from the bottom. The desulfurization tower adopts a packed tower. The desulfurization tower is divided into two parts, the upper part and the lower part. The liquid phase material and the introduced spray liquid, the introduced spray liquid is a mixed material of circulating desulfurization liquid and ammonia water with a mass concentration of 5%, and the pH value of the mixed material is 6.8. The volume ratio of the upper and lower fillers is generally 1:5. The upper liquid-gas volume ratio is 4L / M 3 , the liquid-gas volume ratio of the lower part is 6L / M 3 . The total volume space velocity of the flue gas passing through the desulfurization tow...

Embodiment 3

[0042] A catalytic cracking regeneration flue gas, SOx content is 1250mg / m 3 , NOx content is 1050mg / m 3 .

[0043] Adopt the method of the present invention, flue gas is washed with water at first, adopt packed tower, the liquid-gas volume ratio of spraying is 10L / M 3 .

[0044] The washed flue gas enters the desulfurization tower from the bottom. The desulfurization tower adopts a packed tower. The desulfurization tower is divided into two parts, the upper part and the lower part. The liquid phase material and the introduced spray liquid, the introduced spray liquid is a mixture of circulating desulfurization liquid and ammonia water with a mass concentration of 6%, and the pH value of the mixture is 6.8. The volume ratio of the upper and lower fillers is generally 1:6. The liquid-gas volume ratio of the upper part is 8L / M 3 , the lower liquid-gas volume ratio is generally 15L / M 3 . The total volume space velocity of the flue gas passing through the desulfurization to...

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Abstract

The invention discloses a flue gas desulfurization and denitrification process method. The method comprises the following steps: (1) spraying and washing flue gas containing NOx and SOx; (2) allowing a gas phase exhausted in step (1) to enter a desulfurization tower to be subjected to desulfurization treatment, wherein the desulfurization treatment adopts the ammonia desulphurization technology, part of NOx is removed during desulphurization, a low-concentration ammonia water desulfurization section is arranged at the upper part of the 0.5%-1.0%; (3) performing selective reduction denitrification reaction on gas exhausted from the top of the desulfurization tower. Compared with the prior art, the flue gas desulfurization and denitrification are combined organically, so that the overall effectiveness and economic efficiency of flue gas treatment are improved.

Description

technical field [0001] The invention relates to a treatment process for flue gas containing NOx and SOx, in particular to a desulfurization and denitrification process for boiler flue gas and refinery FCC flue gas. Background technique [0002] NOx (nitrogen oxides in flue gas, generally NO, NO 2 and N 2 A mixture of nitrogen oxides such as O) and SOx (sulfur oxides in flue gas, generally SO 2 and SO 3 mixture) is one of the main sources of air pollution. NOx and SOx in the atmosphere mainly come from exhaust gases from industrial processes related to combustion processes and exhaust emissions from motor vehicles and ships. [0003] Nitrogen oxides are collectively referred to as NOx, and the most harmful ones are: NO, NO 2 . The main hazards of NOx are as follows: (1) toxic to the human body; (2) toxic to plants; (3) can form acid rain and acid fog; (4) form photochemical smog with hydrocarbons; (5) destroy the ozone layer . [0004] In the atmosphere, SO 2 It will...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D53/78B01D53/90B01D53/60B01D47/06
CPCY02A50/20
Inventor 刘忠生廖昌建王明星李勇彭德强
Owner CHINA PETROLEUM & CHEM CORP
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