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A kind of method for preparing hydrogenation catalyst

A hydrogenation catalyst and catalyst technology, applied in the direction of molecular sieve catalysts, chemical instruments and methods, physical/chemical process catalysts, etc., can solve the problems of amorphous silicon-aluminum agglomeration, reduction of catalyst specific surface area and pore volume, and influence on catalyst performance. Achieve the effects of enhancing binding force, avoiding agglomeration and improving performance

Active Publication Date: 2015-09-02
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, the carrier material is prepared by directly adding molecular sieves in the process of forming amorphous silica-alumina. In this way, amorphous silica-alumina is prone to agglomeration, and it is also easy to enter the pores of the other party or block the pores of molecular sieves, which affects the amorphous silica-alumina. The distribution on the molecular sieve, the poor connectivity between the molecular sieve and the amorphous silica-alumina channel, reduces the specific surface area and pore volume of the catalyst, and the distribution of active metals is not easy to control, which makes the hydrogenation function of the catalyst mismatch with the cracking function, affecting the catalyst performance

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] Add 1496g of solid aluminum chloride into 1 liter of distilled water while heating and stirring until dissolved to obtain aluminum chloride solution (a). Dilute the concentrated ammonia water with an appropriate amount of distilled water to form about 10wt% dilute ammonia water (b), and dissolve 228g of xylitol in 500ml of water to form a solution (c). Take 10L of water glass (industrial grade, modulus 3.0) and dilute it in 20L of deionized water to prepare solution (d). 171g Y-type molecular sieve Y-1 (SiO 2 / Al 2 o 3 The molar ratio is 11.0, the unit cell constant is 24.42?, and the relative crystallinity is 95%) use an impregnation solution containing 74g sodium tungstate and 65g nickel nitrate hexahydrate for saturated impregnation, after impregnation, dry at 120°C for 180 minutes, and bake at 500°C 4 hours; 66.7g of diethanolamine was dissolved in 100ml of water, heated to 60°C, and metal-containing Y molecular sieve was added under stirring, and beaten for 2 ho...

Embodiment 2

[0041] 426g of solid aluminum sulfate was added to 1 liter of distilled water while heating and stirring until dissolved to obtain aluminum sulfate solution (a). Add an appropriate amount of distilled water to the concentrated ammonia water and dilute it into about 10wt% dilute ammonia water (b), and dissolve 126g of adipic acid in 500ml of water to form a solution (c). Take 10L of water glass (industrial grade, modulus 3.0) and dilute it in 20L of deionized water to prepare solution (d). 275g Y-type molecular sieve Y-1 (SiO 2 / Al 2 o 3 The molar ratio is 11.0, the unit cell constant is 24.42?, and the relative crystallinity is 95%). Use an impregnation solution containing 284g sodium tungstate and 250g nickel nitrate hexahydrate for saturated impregnation, dry at 120°C for 180 minutes after impregnation, and bake at 500°C 4 hours; 55 g of ethanolamine was dissolved in 100 ml of water, heated to 60° C., metal-containing Y molecular sieve was added under stirring, and beaten...

Embodiment 3

[0044]135g of solid aluminum sulfate was added to 1 liter of distilled water while heating and stirring until dissolved to obtain aluminum sulfate solution (a). Prepare the solid sodium metaaluminate to a concentration of 20g Al 2 o 3 / l sodium aluminate solution (b). 96 g of 1,4-butanedioic acid was dissolved in 1 L of water to form solution (c). 597.4g Y-type molecular sieve Y-1 (SiO 2 / Al 2 o 3 The molar ratio is 11.0, the unit cell constant is 24.42?, and the relative crystallinity is 95%) use an impregnation solution containing 207g sodium tungstate and 183g nickel nitrate hexahydrate for saturated impregnation, dry at 120°C for 180 minutes after impregnation, and bake at 500°C 4 hours; 60g of ethylenediamine was dissolved in 500ml of water, heated to 60°C, metal-containing Y molecular sieve was added under stirring, and the slurry (d) was obtained after stirring for 2 hours. Take 10L water glass (industrial grade, modulus 3.0) and dilute it in 20L deionized water t...

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Abstract

The invention discloses a method for preparing a hydrogenation catalyst. The method comprises the following steps: adding a mixture of molecular sieves containing hydrogenation active metal components and organic amines as well as organic alcohols and / or organic acids in the amorphous silica-alumina gel forming process; carrying out aging after amorphous silica-alumina gel forming is completed and then carrying out filtration, washing and drying; then carrying out forming, drying and roasting, thus obtaining the hydrogenation catalyst. By adopting the method, the molecular sieves and amorphous silica-alumina can be organically combined together with good combination degree and dispersion degree, thereby avoiding agglomeration and even blockage of the molecular sieves and amorphous silica-alumina, and meanwhile, the hydrogenation and cracking functions of the catalyst can be effectively adjusted and the usability of the catalyst can be improved. The catalyst prepared by the method is suitable for the shallow cracking and deep hydrogenation processes.

Description

technical field [0001] The invention relates to a method for preparing a hydrogenation catalyst, in particular to a method for preparing a hydrogenation catalyst containing molecular sieves. Background technique [0002] Hydrocracking technology is one of the important means for the secondary processing of crude oil and the lightening of heavy oil. Because of its strong adaptability to raw materials, flexible production operations and product solutions, and good product quality, it has become an important way to produce high-quality light clean oil products and solve the source of chemical raw materials. [0003] Hydrocracking catalysts are generally dual-functional catalysts, and their cracking activity and hydrogenation activity are respectively provided by the acidic component and hydrogenation active component in the catalyst. [0004] The acidic component of the catalyst is generally provided by molecular sieves contained in the catalyst and / or refractory inorganic oxi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J29/16B01J29/78C10G47/20
Inventor 张晔蒋广安郑庆华刘雪玲李宝忠王继锋
Owner CHINA PETROLEUM & CHEM CORP
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