A kind of method for preparing hydrogenation catalyst
A hydrogenation catalyst and catalyst technology, applied in the direction of molecular sieve catalysts, chemical instruments and methods, physical/chemical process catalysts, etc., can solve the problems of amorphous silicon-aluminum agglomeration, reduction of catalyst specific surface area and pore volume, and influence on catalyst performance. Achieve the effects of enhancing binding force, avoiding agglomeration and improving performance
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Embodiment 1
[0038] Add 1496g of solid aluminum chloride into 1 liter of distilled water while heating and stirring until dissolved to obtain aluminum chloride solution (a). Dilute the concentrated ammonia water with an appropriate amount of distilled water to form about 10wt% dilute ammonia water (b), and dissolve 228g of xylitol in 500ml of water to form a solution (c). Take 10L of water glass (industrial grade, modulus 3.0) and dilute it in 20L of deionized water to prepare solution (d). 171g Y-type molecular sieve Y-1 (SiO 2 / Al 2 o 3 The molar ratio is 11.0, the unit cell constant is 24.42?, and the relative crystallinity is 95%) use an impregnation solution containing 74g sodium tungstate and 65g nickel nitrate hexahydrate for saturated impregnation, after impregnation, dry at 120°C for 180 minutes, and bake at 500°C 4 hours; 66.7g of diethanolamine was dissolved in 100ml of water, heated to 60°C, and metal-containing Y molecular sieve was added under stirring, and beaten for 2 ho...
Embodiment 2
[0041] 426g of solid aluminum sulfate was added to 1 liter of distilled water while heating and stirring until dissolved to obtain aluminum sulfate solution (a). Add an appropriate amount of distilled water to the concentrated ammonia water and dilute it into about 10wt% dilute ammonia water (b), and dissolve 126g of adipic acid in 500ml of water to form a solution (c). Take 10L of water glass (industrial grade, modulus 3.0) and dilute it in 20L of deionized water to prepare solution (d). 275g Y-type molecular sieve Y-1 (SiO 2 / Al 2 o 3 The molar ratio is 11.0, the unit cell constant is 24.42?, and the relative crystallinity is 95%). Use an impregnation solution containing 284g sodium tungstate and 250g nickel nitrate hexahydrate for saturated impregnation, dry at 120°C for 180 minutes after impregnation, and bake at 500°C 4 hours; 55 g of ethanolamine was dissolved in 100 ml of water, heated to 60° C., metal-containing Y molecular sieve was added under stirring, and beaten...
Embodiment 3
[0044]135g of solid aluminum sulfate was added to 1 liter of distilled water while heating and stirring until dissolved to obtain aluminum sulfate solution (a). Prepare the solid sodium metaaluminate to a concentration of 20g Al 2 o 3 / l sodium aluminate solution (b). 96 g of 1,4-butanedioic acid was dissolved in 1 L of water to form solution (c). 597.4g Y-type molecular sieve Y-1 (SiO 2 / Al 2 o 3 The molar ratio is 11.0, the unit cell constant is 24.42?, and the relative crystallinity is 95%) use an impregnation solution containing 207g sodium tungstate and 183g nickel nitrate hexahydrate for saturated impregnation, dry at 120°C for 180 minutes after impregnation, and bake at 500°C 4 hours; 60g of ethylenediamine was dissolved in 500ml of water, heated to 60°C, metal-containing Y molecular sieve was added under stirring, and the slurry (d) was obtained after stirring for 2 hours. Take 10L water glass (industrial grade, modulus 3.0) and dilute it in 20L deionized water t...
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