Coal tar hydrogenation process for maximizing utilization of coal tar residues
A technology of coal tar and process, applied in the field of new hydrogenation process, can solve the problem that solid residual oil has not been effectively utilized, and achieve the effects of saving heating equipment, expanding production scale, and being easy to dissolve and extract
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Embodiment 1
[0034] The coal tar hydrogenation process described in the present embodiment comprises the following steps:
[0035] (1) Send the coal tar raw material into the distillation tower, carry out distillation treatment under normal pressure, and divide it into light distillate oil of ≤350°C and heavy distillate oil of >350°C;
[0036] (2) Mixing the heavy distillate obtained in step (1) with γ-FeOOH and a sulfur catalyst to form an oil slurry, wherein the added amount of the γ-FeOOH is calculated as Fe in the heavy distillate 1 wt%, the molar ratio of S in the sulfur to Fe in γ-FeOOH is 1:3; the oil slurry is mixed with hydrogen and sent to a slurry bed hydrogenation reactor at 420°C, 15MPa, The hydrogenation reaction is carried out under the condition that the gas-liquid ratio is 500NL / kg;
[0037] (3) Using a high-temperature separator to separate gas-liquid from the outlet material of the hydrogenation reactor, the temperature of the high-temperature separator is 300°C;
[00...
Embodiment 2
[0043] The coal tar hydrogenation process described in the present embodiment comprises the following steps:
[0044] (1) Send the coal tar raw material into the distillation tower for distillation treatment, and divide it into light distillate oil ≤ 320 °C and heavy distillate oil > 320 °C;
[0045] (2) Mixing the heavy distillate obtained in step (1) with γ-FeOOH and a sulfur catalyst to form an oil slurry, wherein the added amount of the γ-FeOOH is calculated as Fe in the heavy distillate 3 wt%, the molar ratio of S in the sulfur to Fe in γ-FeOOH is 1:3; the oil slurry is mixed with hydrogen and sent to a slurry bed hydrogenation reactor at 460°C, 19MPa, The hydrogenation reaction is carried out under the condition that the gas-liquid ratio is 1500NL / kg;
[0046] (3) Using a high-temperature separator to separate the gas-liquid from the outlet material of the hydrogenation reactor, the temperature of the high-temperature separator is 400°C;
[0047] (4) The liquid phase m...
experiment example
[0053] In order to prove the technical effect of the coal tar hydrogenation process described in the present invention, this experimental example measured the yield in the hydrogenation process described in the above-mentioned embodiment 1 and embodiment 2. in:
[0054] Yield of light distillate oil %= Light distillate oil / coal tar raw material of ≤350°C or ≤320°C obtained in step (1) distillation tower×100%;
[0055] Gas yield % = gas fraction generated during the entire hydrogenation process / coal tar raw material × 100%;
[0056] Water yield % = water generated in the whole hydrogenation process / coal tar raw material × 100%;
[0057] Hydrogen consumption % = hydrogen consumed in the whole hydrogenation process / coal tar raw material × 100%;
[0058] Needle coke yield % = needle coke produced by delayed coking system / coal tar raw material × 100%;
[0059] The above yields are all percentages by mass, and the coal tar raw material is analyzed on an anhydrous and ash-fr...
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