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Preparation method of a self-humidifying ordered polymer membrane electrode

A polymer membrane and polymer technology, applied in battery electrodes, circuits, fuel cells, etc., can solve problems such as the inability of self-moisturizing three-phase interface, affecting energy conversion efficiency and reaction rate, and destroying proton conductor nanofiber arrays.

Active Publication Date: 2016-04-06
国鸿氢能科技(嘉兴)股份有限公司
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  • Application Information

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Problems solved by technology

The catalytic layer and the interface with material composition and micropore disorder distribution not only reduce the electrochemical performance of the membrane electrode (energy loss is mainly manifested as electrochemical polarization and concentration polarization), but also seriously affect the long-term stability
Therefore, in view of the bottleneck problems existing in the existing membrane electrodes: the three-dimensional structure of the ion, electron, gas, and water channels in the electrode lacks controllable design and corresponding preparation methods, the three-phase interface of the electrochemical reaction in the electrode cannot self-moisture, and the three-phase Fewer interfaces and longer mass transfer microchannels lead to strong electrochemical polarization and concentration polarization of the membrane electrode during energy conversion, which affects energy conversion efficiency and reaction rate
This invention still cannot solve the problem of membrane electrode self-humidification energy conversion application, and from the perspective of the preparation process, because the proton conductor nanofiber is easy to deform at high temperature, the preparation process of the invention using two single-electrode lamination heating molding will bring The destruction of the proton conductor nanofiber array, and the interface in the electrolyte will also increase the ohmic polarization during the energy conversion of the membrane electrode

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preparation example Construction

[0039] The preparation method of the ordered polymer membrane electrode of the present invention specifically includes the following steps, and its technological process is shown in the appendix Figure 2-3 .

[0040] (1) Provide a porous template with array holes, such as AAO, to be used after cleaning;

[0041] (2) Place a piece of polymer electrolyte membrane between the above two symmetrically placed porous templates, and fix it into a three-in-one assembly of porous template|polymer electrolyte membrane|porous template;

[0042] (3) The above-mentioned three-in-one assembly is hot-pressed at a certain temperature and pressure for a certain period of time, so that the polymer electrolyte membrane becomes fluid and enters the array holes of the porous template;

[0043](4) Place the above hot-pressed three-in-one assembly in an acidic or alkaline solution to dissolve the porous templates on both sides of the polymer electrolyte membrane to obtain an ion-exchange polymer na...

Embodiment 1

[0050] Embodiment 1 is used for proton exchange membrane electric fuel cell

[0051] Use 1% (mass fraction) sodium dodecylsulfonate solution to clean the 5cm*5cm AAO porous template (the diameter of the hole can be 400 nanometers and the thickness is 50 microns), put it into a petri dish, and put the petri dish into vacuum oven. The temperature of the oven was set at 50°C, and the vacuum was evacuated to 0.1 atmosphere for 1 hour before use. The aluminum oxide porous template and the 150 micron thick Nafion membrane were fixed on the Cu sheet cleaned with alcohol to form a three-in-one assembly of alumina porous template|Nafion membrane|alumina porous template. Place the above-mentioned three-in-one component in a hot press, set the temperature at 90°C, set the pressure at 10Mpa, and keep the pressure for 1 hour. After hot pressing, take out the three-in-one assembly, put it into a 5mol / L NaOH solution, keep it in a constant temperature box at 60°C, take it out after 1 hour,...

Embodiment 2

[0054] Embodiment 2 is used for alkaline membrane fuel cell

[0055] Use 1% (mass fraction) sodium dodecylsulfonate solution to clean the 5cm*5cm aluminum oxide porous template (pore diameter is 50 nm, thickness 1 micron), put it into a petri dish, put the petri dish into a vacuum oven. The temperature of the oven was set at 50°C, and the vacuum was evacuated to 0.1 atmosphere for 1 hour before use. A stainless steel sheet cleaned with acetone was used to fix the alumina porous template and the quaternized polysulfone membrane with a thickness of 5 microns to form a three-in-one assembly of alumina porous template|quaternized polysulfone membrane|alumina porous template. The above-mentioned three-in-one assembly was placed in a hot press, the temperature was set at 240°C, the pressure was set at 10Mpa, and the pressure was maintained for 1 hour. After hot pressing, take out the three-in-one assembly and put it in a 5mol / L NaOH solution, keep it warm at 60°C in an incubator, ...

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Abstract

The invention discloses a preparation method of a self-humidifying ordered polymer membrane electrode, belonging to the technical field of membrane electrode preparation. An ordered ion exchange polymer nanotube array prepared through the method is fused together with a polymer membrane and is provided with highly ordered ion, electron and gas mass transfer channels, and electrochemical three-phase reaction interfaces are distributed in the outer surfaces of polymer nanotubes with water storage functions, so that a high-efficiency energy conversion process can be carried out in a self-humidifying manner. A catalyst in a nanoparticle or microparticle state is bonded on the surface of the ion exchange polymer nanotube array to form a catalysis layer and is relatively high in specific surface area and catalytic activity, so that the three-phase reaction interfaces of the membrane electrode are greatly added, the electrochemical polarization, the ohmic polarization and the concentration polarization of the electrode are reduced, the energy conversion efficiency is improved, and the reaction speed is increased. According to the preparation method, a membrane electrochemical reactor system is expected to be remarkably simplified, the energy conversion efficiency and the stability are improved, and the operation life is prolonged.

Description

technical field [0001] The invention belongs to the technical field of membrane electrode preparation, and in particular relates to a method for preparing a self-humidifying ordered polymer membrane electrode for energy conversion. Background technique [0002] Polymer Electrolyte Fuel Cell (PEFC), such as proton exchange membrane fuel cell, direct methanol fuel cell, and alkaline membrane fuel cell, can directly convert the chemical energy in fuel into electrical energy through electrochemical reaction, which is an environmentally friendly and efficient Power generation methods with high power density, especially in distributed power stations, zero-emission traffic power, and portable power applications, have extremely attractive prospects. Contrary to the working principle of fuel cells, electrolyzers (SPE electrolyzers for short) with solid polymer membranes (Solid Polymer Electrolyte, SPE) as electrolytes can directly convert electrical energy into chemical energy and st...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/88
CPCH01M4/881H01M8/1004H01M2008/1095Y02E60/50
Inventor 王诚刘锋张剑波王建龙
Owner 国鸿氢能科技(嘉兴)股份有限公司
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