Method for oil removal from wastewater in field of coal chemical industry

A technology for coal chemical industry and waste water, which is applied in separation methods, extraction water/sewage treatment, grease/oily substances/suspton removal devices, etc., which can solve the difficulty and cost of increasing management, affect waste water treatment, and it is difficult to remove dissolved oil, etc. problems, to achieve the effect of simplifying the wastewater treatment process and time, optimizing the extraction effect and recovery efficiency, and reducing the cost of sewage treatment

A technology for coal chemical industry and waste water, which is applied in separation methods, extraction water/sewage treatment, grease/oily substances/suspton removal devices, etc., which can solve the difficulty and cost of increasing management, affect waste water treatment, and it is difficult to remove dissolved oil, etc. problems, to achieve the effect of simplifying the wastewater treatment process and time, optimizing the extraction effect and recovery efficiency, and reducing the cost of sewage treatment

CN103964544AInactive Publication Date: 2014-08-06HENAN DRAGON INTO COAL TECH CO LTD

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  • Method for oil removal from wastewater in field of coal chemical industry
  • Method for oil removal from wastewater in field of coal chemical industry
  • Method for oil removal from wastewater in field of coal chemical industry

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] In a coal chemical plant, the coal chemical wastewater treatment capacity is 53 tons / hour, of which the oil content is 1257 mg / L, and the soluble oil content in the oil content is 420 mg / L. figure 1 The process equipment flow chart for wastewater degreasing, the steps are as follows:

[0039] a. Wastewater pretreatment: First, the wastewater enters the adjustment tank and adds acid to make the pH at 5.0, and then cools to 40℃ through a cooler;

[0040] b. Extraction and degreasing: the pretreated wastewater is pumped to the top of the extraction tower, and countercurrent extraction is performed with the n-hexane entering from the bottom. The volume ratio of the extractant to the wastewater is 1:20, the number of plates is 4, and the tower The top pressure is 0.1MPa, the temperature is 40°C, the bottom pressure is 0.3MPa, and the temperature is 45°C; the extraction phase is extracted from the top of the tower; the water phase after extraction and degreasing is extracted from t...

Embodiment 2

[0044] In a coal chemical plant, the coal chemical wastewater treatment capacity is 65 tons / hour, of which the oil content is 1322mg / L, and the soluble oil content in the oil content is 480mg / L. figure 1 The process equipment flow chart for wastewater degreasing, the steps are as follows:

[0045] a. Wastewater pretreatment: First, the wastewater enters the adjustment tank and adds acid to make the pH 4.0, and then cools to 35°C through a cooler;

[0046] b. Extraction and degreasing: The pretreated wastewater is pumped to the top of the extraction tower, and it is extracted countercurrently with the petroleum ether entering from the bottom. The volume ratio of extractant to wastewater is 1:12, the number of plates is 7, and the tower The top pressure is 0.2MPa, the temperature is 34°C, the bottom pressure is 0.8MPa, and the temperature is 35°C. The extraction phase is extracted from the top of the tower; the water phase after extraction and degreasing is extracted from the bottom o...

Embodiment 3

[0050] In a coal chemical plant, the coal chemical wastewater treatment capacity is 80 tons / hour, of which the oil content is 1530 mg / L, and the soluble oil content in the oil content is 570 mg / L. figure 1 The process equipment flow chart for wastewater degreasing, the steps are as follows:

[0051] a. Wastewater pretreatment: First, the wastewater enters the adjustment tank and adds acid to make the pH at 3.0, and then cools to 30°C through a cooler;

[0052] b. Extraction and degreasing: The pretreated wastewater is pumped to the top of the extraction tower, and the hexane and petroleum ether (3:1) entering from the bottom are subjected to countercurrent extraction. The volume ratio of extractant to wastewater is 1:7 , The number of trays is 10, the pressure at the top of the tower is 0.1MPa, the temperature is 60°C, the pressure at the bottom of the tower is 1.0MPa, and the temperature is 30°C. The extraction phase is extracted from the top of the tower; the water phase after ext...

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Abstract

The invention discloses a method for oil removal from wastewater in the field of coal chemical industry, which is characterized in that oil contains soluble oil; and the method comprises the following steps: wastewater pretreatment, extraction and oil removal, and extraction agent recovery. Through the method, the oil contained in the wastewater, in particular to the soluble oil can be effectively removed. The invention further provides normal hexane and / or petroleum ether as an extraction agent; and through a practical application experiment, after the method is adopted, the oil contained in the treated wastewater is the soluble oil basically, the removal rate of the oil reaches 95.31-97.91 percent, and the removal rate of the soluble oil reaches 87.08-94.17 percent, so that a good oil removal effect is reached, and particularly, the effect of removing the soluble oil is good.

Description

Technical field [0001] The invention belongs to the technical field of coal chemical wastewater treatment, and specifically relates to a method for removing oil from wastewater in the coal chemical industry. technical background [0002] In the deep processing of coal gasification, liquefaction to oil, combustion power generation, coking, etc., a large amount of highly polluting wastewater is inevitably produced. These wastewater contains a large amount of pollutants such as oil, ammonia, and acid gas, which can only be removed after purification. After the oil is removed, it can be further deacidified, ammoniated, and phenol removed. Finally, advanced treatment such as biochemical treatment can be carried out to meet the emission requirements. At the same time, the oil contained in the water can be recovered to realize its value. [0003] The oily substances in the coal chemical wastewater mainly have the following occurrence states: (1) floating oil (particle size> 100μm), eas...

Claims

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Application Information

Patent Timeline
06 Aug 2014
Publication
CN103964544A
IPC
C02F1/40; C02F1/26
Inventors
白太宽; 王洪博