The invention provides a precise time synchronization method for an industrial wireless network, relating to the industrial wireless network communication technology. Aiming at the characteristics of the industrial wireless network, such as limited energy supply, dynamic and variable network environment, the openness of the wireless network media, and the like, the invention provides a unique precise time synchronization method, wherein, a layering and grading synchronization strategy is adopted to divide the industrial wireless network according to a hierarchical structure; an MAC layer of a parent device generates beacon frames, sends the beacon frames periodically, obtains a time stamp in the processes of sending and receiving beacon frames, obtains the frequency deviation and time deviation of the equipment clock and the universal time clock by fitting the time stamps sent and received in most recently N times, compensates the local clock, realizes the time clock synchronization of a child device and the parent device; time synchronization is carried out in a grade-wise manner and finally the time synchronization of the whole network is realized. On the premise of meeting the performance requirements on the industrial wireless network, the precise time synchronization method of the invention can ensure that the whole network runs within a uniform time scale and guarantee the normal operation of the system.