Water-soluble multifunctional CoFe2O4@MnFe2O4@polypyrrole satellite structure nanomaterial and preparation method and application thereof
A cofe2o4mnfe2o4, pyrrole satellite technology, applied in the field of nanomaterials, to achieve the effect of uniform shape, good biocompatibility, and less toxic and side effects
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Embodiment 1
[0026] Preparation of CoFe 2 o 4 MnFe 2 o 4 For magnetic composite nanomaterials, refer to the literature Journal of the American Chemical Society2004126(1), 273-279.
Embodiment 2
[0028] CoFe prepared in Example 1 2 o 4 MnFe 2 o 4 200 mg of nanomaterials were dispersed in 20 mL of n-hexane. Weigh 0.14gNOBF 4 , dissolved in 20 mL of chloroform. The above two solutions were mixed and reacted for 5 minutes, then centrifuged, washed once with ethanol and water, and dispersed in 8 mL of secondary water to obtain water-soluble CoFe 2 o 4 MnFe 2 o 4 nanomaterials.
Embodiment 3
[0030] Weigh 0.8g polyvinyl alcohol (PVA) and dissolve it in 10mL of secondary water to make a solution, then weigh 0.8g FeCl 3 ·6H 2 O solution in it, forming PVA and FeCl 3 mixed solution. The above mixed solution was mixed with the solution obtained in Example 2 and mechanically stirred for 12 h. Subsequently, 0.2 mL of pyrrole monomer was slowly added to the above solution under stirring, and reacted for 24 hours. After the reaction was completed, 40 mL of absolute ethanol was added to the reaction system, and the product was centrifuged, washed three times with absolute ethanol, and finally dispersed in secondary water.
[0031] figure 1 This is the TEM image of the material prepared in this example. It can be seen from the figure that the synthesized material has a spherical structure, uniform shape, and an average particle size of 70 nm.
[0032] figure 2Be the infrared spectrogram of making material in the present embodiment, wherein 1554 and 1450cm -1 The char...
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