Method for preparing surface material with anti-marine biological pollution function
A technology for marine organisms and surface materials, applied in anti-fouling/underwater coatings, paints containing biocides, coatings, etc. The effect of preventing marine pollution
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Embodiment 1
[0038] Take methanol / distilled aqueous solution (volume ratio 1:1) prepared in advance, blow nitrogen into it for 10min, add 4g potassium salt of 3-sulfopropyl methacrylate, 0.2g N-(3,4- Dihydroxyphenyl) ethyl-methacrylamide, 0.1g 2,2'-bipyridine, 0.05g benzyl bromide were reacted at room temperature for 4 hours under the protection of nitrogen, and the copolymer was precipitated with methanol.
[0039] Make the copolymer into an aqueous solution with a concentration of 0.01g / mL, put the titanium or titanium alloy into the solution and soak for 25 hours, wash with water and methanol several times, and dry it in the air.
Embodiment 2
[0041] Take methanol / distilled aqueous solution (volume ratio 1:1) prepared in advance, feed it with nitrogen for 15min, add 4.5g potassium salt of 3-sulfopropyl methacrylate, 0.2g N-(3,4 -dihydroxyphenyl)ethyl-methacrylamide, 0.1g 2,2'-bipyridine, 0.05g benzyl bromide, reacted at room temperature for 4 hours under nitrogen protection, and precipitated the copolymer with methanol.
[0042] Prepare the copolymer into an aqueous solution with a concentration of 0.05g / mL, put titanium or titanium alloy into the solution and soak for 25 hours, wash with water and methanol several times, and dry in the air.
Embodiment 3
[0044] Take methanol / distilled aqueous solution (volume ratio 1:1) prepared in advance, and after blowing it with nitrogen for 20min, add 5g of 3-sulfonic acid propyl potassium salt, 0.3g of N-(3,4- Dihydroxyphenyl) ethyl-methacrylamide, 0.2g 2,2'-bipyridine, 0.06g benzyl bromide were reacted at room temperature for 5 hours under the protection of nitrogen, and the copolymer was precipitated with methanol.
[0045] Make the copolymer into an aqueous solution with a concentration of 0.10g / mL, soak the titanium or titanium alloy in the solution for 20 hours, wash it with water and methanol several times, and dry it in the air.
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