A kind of method for electroplating cupronickel tin on permanent magnet material
A technology of permanent magnet material and cupronickel, which is applied in the field of anticorrosion of permanent magnet material to achieve the effect of saving electroplating cost and good anticorrosion effect
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Embodiment 1
[0018] First, 2.5kg of ¢24×¢15×18mm sintered NdFeB permanent magnet materials were mechanically vibrated in a vibrating mill for 2 hours, and then were washed with an alkaline solution (sodium phosphate 20g / L, sodium carbonate 10g / L and hydrogen Sodium oxide 10g / L) degreasing and degreasing, then pickling in 1% nitric acid solution, electroplating nickel, see (CN200910244404) for details using Watt nickel formula nickel sulfate 220 g / L, nickel chloride 40 g / L, boric acid 40 g / L, pH 4.8, temperature 42°C. The thickness of the nickel layer is 5 microns, and electroplating copper is carried out after washing with water. The formulation of the electroplating solution is as follows: copper pyrophosphate 60 g / L, potassium pyrophosphate 300 g / L, pH 8.2, temperature 50°C, and the thickness of the electroplated copper layer is 7 microns. Electroplated copper-tin alloy after water washing. Copper-tin alloy plating solution includes Cu 2 P 2 o 7 ·3H 2 O 16g / L, Sn 2 P 2 o 7 12g / ...
Embodiment 2
[0021] According to the method of embodiment 1, carry out surface pretreatment to the NdFeB permanent magnet material of 2.5kg ¢ 24 * ¢ 15 * 18mm, adopt nickel plating on the surface of permanent magnet material and then electroplate copper, electroplate copper-tin alloy after water washing. Electroplated copper-tin alloy after water washing. Copper-tin alloy plating solution includes Cu 2 P 2 o 7 ·3H 2 O19g / L, Sn 2 P 2 o 7 15g / L, K 4 P 2 o 7 ·3H 2 O250g / L, K 2 HPO 4 80g / L, complexing agent FCS-A 120ml / L, stabilizer FCS-B 30ml / L, brightener FCS-C 20ml / L (complexing agent FCS-A, stabilizer FCS-B and brightener FCS-C Both were purchased from Guangzhou Medis). The electroplating temperature is 25° C., the pH is 8.5, and the thickness of the Cu—Sn alloy plating layer is 20 μm.
[0022] It can be seen from the neutral salt spray test that the NdFeB permanent magnet obtained by the surface protection method of the NdFeB permanent magnet of the present invention has a g...
Embodiment 3
[0024] According to the method of embodiment 1, carry out surface pretreatment to the NdFeB permanent magnet material of 2.5kg ¢ 24 * ¢ 15 * 18mm, adopt nickel plating on the surface of permanent magnet material and then electroplate copper, electroplate copper-tin alloy after water washing. Electroplated copper-tin alloy after water washing. Copper-tin alloy plating solution includes Cu 2 P 2 o 7 ·3H 2 O17g / L, Sn 2 P 2 o 7 14g / L, K 4 P 2 o 7 ·3H 2 O220g / L, K 2 HPO 4 70g / L, complexing agent FCS-A 100ml / L, stabilizer FCS-B 20ml / L, brightener FCS-C 16ml / L (complexing agent FCS-A, stabilizer FCS-B and brightener FCS-C Both were purchased from Guangzhou Medis). The temperature of the electroplating is 22° C., the pH is 8.6, and the thickness of the Cu—Sn alloy plating layer is 12 μm.
[0025] It can be seen from the neutral salt spray test that the NdFeB permanent magnet obtained by the surface protection method of the NdFeB permanent magnet of the present invention ...
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