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Inhibitor for separating blue chalcocite and iron pyrite and mineral separation method thereof

A blue chalcocite ore beneficiation method technology, applied in flotation, solid separation, etc., can solve problems such as low recovery rate, easy loss of blue chalcocite, mine wastewater pollution, etc., to improve grade and copper recovery rate, improve Copper-sulfur separation effect, avoiding the effect of pipeline calcium accumulation

Inactive Publication Date: 2015-01-07
NORTHWEST RES INST OF MINING & METALLURGY INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] 1) The pipeline is fouled, easy to block, and the mine wastewater is seriously polluted;
[0004] 2) It is not conducive to the comprehensive recovery of valuable associated elements;
[0005] 3) The collector ester-112 is easy to react with lime, causing sticky copper concentrate foam and affecting the quality of copper concentrate;
[0006] 4) The activity of the secondary blue chalcocite itself is poor, and the blue chalcocite is easily lost in the tailings by using this process, resulting in a low recovery rate;
[0007] 5) Extensive use of lime will increase the cost of beneficiation

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] The ore to be selected is Hongshan copper-sulfur ore. The ore is low-grade blue chalcocite. The raw ore grade is: copper 0.40%, sulfur 6.10%. Grind the above raw ore through a wet ball mill until the minerals with a fineness of -0.074mm account for 75% of all minerals, and the mass concentration of the obtained pulp is 32%. Under this concentration condition, add 30 grams of collector butyl xanthate to the pulp Mix 20 grams of Hester-112, stir for 2 minutes and then carry out copper-sulfur mixed flotation. The flotation time is 6 minutes to obtain copper-sulfur mixed coarse concentrate; the copper-sulfur mixed coarse concentrate is passed through the The copper-sulfur mixed concentrate is obtained by two beneficiation; the copper-sulfur mixed concentrate is added with 450 grams of inhibitor under the condition that the mass concentration of the pulp is 25%, and the mass ratio of the inhibitor is citric acid: sodium sulfite: tannin Acid = 0.5:1.1:1.5, then after stirring...

Embodiment 2

[0031] The raw material ore of this embodiment is blue chalcocite, and the raw ore grade is: copper 0.64%, sulfur 5.18%. Grind the above raw ore until the minerals with a fineness of -0.074mm account for 70% of all minerals, and the mass concentration of the obtained pulp is 35%. Under this concentration condition, add 25 grams of collector butyl xanthate and ester- 112 23 grams, after stirring for 3 minutes, carry out copper-sulfur mixed flotation, and the flotation time is 7 minutes, to obtain copper-sulfur mixed rough concentrate; the copper-sulfur mixed rough concentrate is subjected to two refining processes under the condition that the mass concentration of the pulp is 24%. The copper-sulfur mixed concentrate is selected; the copper-sulfur mixed concentrate is added with 400 grams of inhibitor under the condition that the pulp mass concentration is 24%, and the mass ratio of the inhibitor is citric acid: sodium sulfite: tannic acid=0.6 :1.0:1.6, then after stirring for 5...

Embodiment 3

[0034] The raw material ore of this embodiment is blue chalcocite, and the raw ore grade is: copper 0.52%, sulfur 4.18%. Grind the above raw ore until the minerals with a fineness of -0.074mm account for 65% of the total minerals, and the resulting pulp has a mass concentration of 30%. Under this concentration, add 28 grams of collector butyl xanthate and ester- 112 25 grams, after stirring for 4 minutes, carry out copper-sulfur mixed flotation, and the flotation time is 5 minutes to obtain copper-sulfur mixed rough concentrate; the copper-sulfur mixed rough concentrate is subjected to two refining processes under the condition that the mass concentration of the pulp is 27%. The copper-sulfur mixed concentrate is selected; the copper-sulfur mixed concentrate is added with 350 grams of inhibitor under the condition of 27% pulp mass concentration, and the mass ratio of the inhibitor is citric acid: sodium sulfite: tannic acid=0.65 :1.2:1.65, then after stirring for 7 minutes,...

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PUM

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Abstract

The invention provides an inhibitor for separating blue chalcocite and iron pyrite and a mineral separation method of the inhibitor. The inhibitor is formed by mixing citric acid, sodium sulfite and gallotannic acid according to the mass ratio of 0.5 to 0.65:1.0 to 1.2:1.5 to 1.65. The mineral separation method mainly comprises the technological steps that firstly, raw ore of the blue chalcocite is ground into ore pulp with 30 to 35 percent mass concentration, catching agent sodium n-butylxanthate and ester-112 are added into the ore pulp, stirring is carried out for two minutes to four minutes, copper and sulphur mixing flotation is carried out, and copper and sulphur mixing rough concentrates are obtained; secondly, secondary selection is carried out on the copper and sulphur mixing rough concentrates to obtain copper and sulphur mixing concentrates; thirdly, the inhibitor is added into the copper and sulphur mixing concentrates, copper and sulphur separation is carried through flotation, and copper rough concentrates and sulphur rough concentrates are obtained; fourthly, copper concentrates are obtained through one-time to two-time selection of the copper rough concentrates, and sulphur concentrates are obtained through one-time selection of the sulphur rough concentrates.

Description

technical field [0001] The invention belongs to the technical field of mineral flotation separation, and in particular relates to an inhibitor for separation of blue chalcocite and pyrite and a method for beneficiation using the inhibitor. Background technique [0002] In my country's non-ferrous metal resources, copper ore is a resource with high mining value. There are relatively complete types of copper deposits in my country, mainly copper sulfide, and less secondary blue chalcocite, and the secondary blue chalcocite belongs to the type of copper ore that is difficult to be separated. With the rapid development of my country's economy, the demand for copper metal is increasing, but mineral resources are non-renewable resources, and my country's copper mineral resources are decreasing after years of mining, so there is an urgent need to develop and utilize complex and difficult-to-select resources. The beneficiation of blue chalcocite is mainly to separate blue chalcoci...

Claims

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Application Information

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IPC IPC(8): B03D1/018B03D1/00B03D101/06
Inventor 孙运礼苗梁包玺琳刘剑刘涛柏亚林巩明辉李健民李国栋苗培
Owner NORTHWEST RES INST OF MINING & METALLURGY INST
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