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High-hardness and high-gloss ultraviolet light polymerization coating used for PVC floor tiles

A technology of curing coatings and high hardness, applied in the field of coatings, can solve the problems of lack of high standard requirements for hardness and gloss, poor effect, influence on appearance and service life, etc., to achieve good surface curing performance, good chemical resistance, The effect of optimum hardness

Active Publication Date: 2015-01-21
HUZHOU LONGZHU POLYMER NEW MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the existing coatings for general PVC floor tiles are not effective, and the hardness and gloss do not meet the high standard requirements, so the appearance and service life are greatly affected

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] The high-hardness, high-gloss UV-curable coating for PVC floor tiles is prepared from the following raw materials in mass percentage:

[0044] Aliphatic polyurethane diacrylate and photosensitive novolac epoxy acrylate mixture: 40%;

[0045] Graphitized nano carbon fiber: 5%;

[0046] Benzophenone: 8%;

[0047] Organic fluorine: 1.5%;

[0048] Glycol ether: 7.5%;

[0049] 4-tert-butylbenzene salicylate, diacrylate mixture: 16.5%;

[0050] Polyacrylate or silicone leveling agent: 1.5%;

[0051] Methylpentanone alcohol: 19%;

[0052] Pigment: 1%.

[0053] Among them, the mass ratio of the mixture of aliphatic polyurethane diacrylate and photosensitive novolac epoxy acrylate is 3:1; the mass ratio of the mixture of p-tert-butylbenzene salicylate and diacrylate is 2:1.

Embodiment 2

[0055] The high-hardness, high-gloss UV-curable coating for PVC floor tiles is prepared from the following raw materials in mass percentage:

[0056] Aliphatic polyurethane diacrylate and photosensitive novolac epoxy acrylate mixture: 40%;

[0057] Graphitized nano-carbon fiber: 4%;

[0058] Alpha-Hydroxyketone: 10%;

[0059] Silicone: 2%;

[0060] Glycol ether: 9%;

[0061] 4-tert-butylbenzene salicylate, diacrylate mixture: 18%;

[0062] Polyacrylate or silicone leveling agent: 1%;

[0063] Methylpentanone alcohol: 14%

[0064] Pigment: 2%.

[0065] Among them, the mass ratio of the mixture of aliphatic polyurethane diacrylate and photosensitive novolac epoxy acrylate is 3.5:1; the mass ratio of the mixture of p-tert-butylbenzene salicylate and diacrylate is 2.5:1.

Embodiment 3

[0067] The high-hardness, high-gloss UV-curable coating for PVC floor tiles is prepared from the following raw materials in mass percentage:

[0068] Aliphatic polyurethane diacrylate and photosensitive novolac epoxy acrylate mixture: 35%;

[0069] Graphitized nano-carbon fiber: 3%;

[0070] Benzophenone, alpha-hydroxy ketone mixture: 12%;

[0071] Organosilicon and organic fluorine mixtures: 3%;

[0072] Glycol ether: 8.5%;

[0073] 4-tert-butylbenzene salicylate, diacrylate mixture: 12%;

[0074] Polyacrylate or silicone leveling agent: 2%;

[0075] Methylpentanone alcohol: 23%

[0076] Pigment: 1.5%.

[0077]Among them, the mass ratio of the mixture of aliphatic polyurethane diacrylate and photosensitive novolac epoxy acrylate is 4:1; the mass ratio of the mixture of benzophenone and α-hydroxy ketone is 2.2:1; The mass ratio of diacrylate mixture is 1.8:1.

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Abstract

The invention relates to a high-hardness and high-gloss ultraviolet light polymerization coating used for PVC floor tiles. The coating is prepared and characterized by comprising the raw materials in percentage by mass: 30-45% of a mixture of aliphatic polyurethane diacrylate and photosensitive phenolic aldehyde epoxy acrylate, 3-5% of graphitized nano carbon fiber, 5-12% of an initiating agent, 1-3% of a surface assisting agent, 5-10% of a cosolvent, 10-20% of a reactive diluent, 1-2% of a polyacrylate or organosilicone leveling agent, 10-30% of an inert solvent and 0-2% of pigment. The coating provided by the invention has the performances of high hardness, high tenacity and high gloss, and besides, is further provided with higher salt fog resistance, ageing resistance, wearing resistance, scratch resisting capability, adhesive force, and cold and hot impact capacity.

Description

technical field [0001] The invention relates to the field of coatings, in particular to a high-hardness, high-gloss ultraviolet light curing coating for PVC floor tiles. Background technique [0002] Since the advent of UV-curable coatings, it has the characteristics of 5E, namely Efficient, Enabling, Economical, Energy Saying, and Environmental-friendly. In the prior art, UV-curable coatings have been widely used in fields closely related to life to beautify and protect objects. [0003] Plastic building materials are a rising star in the building materials industry. With the rapid growth of China's real estate industry and increased investment in infrastructure in recent years, China's plastic building materials industry has become the second largest in the plastics industry after packaging. A pillar industry with an average annual growth rate of more than 15%. In recent years, China's plastic building materials industry has accelerated the pace of research and developme...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D175/14C09D163/10C09D7/12
CPCC08L2205/03C09D7/20C09D7/47C09D7/62C09D7/65C09D7/70C09D175/14C08L63/10C08L33/08C08K9/02C08K7/06
Inventor 习小山王军黄波
Owner HUZHOU LONGZHU POLYMER NEW MATERIAL
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