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A kind of composite conductive fiber and preparation method thereof

A composite conductive and fiber technology, applied in the direction of conductive/antistatic filament manufacturing, fiber treatment, conjugated synthetic polymer artificial filament, etc., can solve the problem of affecting fiber mechanics, textile performance, and reducing the spinnability of fiber-forming polymers , fiber yield decline and other issues, to achieve the effect of good spinnability, low surface resistivity, excellent electrical conductivity

Active Publication Date: 2017-07-04
SHANGHAI VITA SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, adding a large amount of conductive particles reduces the spinnability of the fiber-forming polymer, reduces the yield of the fiber, increases the cost, and also affects the mechanical and textile properties of the fiber.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Water-soluble polyester, polyester masterbatch containing conductive titanium dioxide and polyester chips are dried separately, and a certain amount of water-soluble polyester chips are input into the cortex screw extruder by using sheath-core composite spinning equipment. The polyester masterbatch and polyester chips containing conductive titanium dioxide are input into the core layer screw extruder for compound melt spinning, and the metering pump is respectively metered and then input into the spinning box, and passed through the circular skin-core composite spinning spinneret After extrusion, it is blown to cool and oiled to form a tow.

[0026] The weight ratio of the sheath to the core of the composite fiber is 20:80. In the core layer, the weight ratio of the conductive polyester masterbatch to the polyester chips is 50:50, and the mass percentage of the conductive titanium dioxide in the core layer is 30%.

[0027] After the fiber tow is wound (speed 900m / min),...

Embodiment 2

[0030] Water-soluble polyester, polyamide masterbatch containing silver powder and polyamide slices are dried separately, and a certain amount of water-soluble polyester slices are input into the cortex screw extruder by using sheath-core composite spinning equipment. The polyamide masterbatch and polyamide slices of silver powder are input into the core layer screw extruder for compound melt spinning, and the metering pump is respectively metered and then input into the spinning box, and extruded through the cross-shaped sheath-core composite spinning spinneret, Cooled by blowing, oiled and integrated tow.

[0031] The sheath-core layer weight ratio of the composite fiber is 60:40. In the core layer, the weight ratio of the conductive polyamide masterbatch to the polyamide chips is 70:30, and the mass percentage of the conductive silver powder in the core layer is 50%.

[0032] The prepared composite fiber tow is drawn (drawing temperature 85°C, draw ratio 2 times), shaping ...

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PUM

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Abstract

The invention discloses a novel composite conductive fiber which has a skin-core type structure, wherein the component of the skin layer is water-soluble polyester, and the component of the core layer is polymer containing conductive micro-powder, including polyester, polyamide and the like. The weight ratio of the skin layer to the core layer is 10:90-80:20; the content of the conductive micro-powder in the core layer is 20%-50%; structures of the skin and core layers of the fiber can be round or special-shaped. The fiber of the invention is produced by composite spinning equipment and composite spinning technology; the prepared skin-core type fiber is subjected to alkali treatment to remove the water-soluble polyester in the skin layer, so as to obtain the conductive fiber formed by the polymer containing conductive micro-powder of the core layer; the conductive component is high in content, a lot of conductive micro-powder contact a surface, so the fiber is low in surface resistivity, excellent in conductivity, and widely applicable to various antistatic fabrics and products; good antistatic effect can be achieved by only adding a few of the fibers.

Description

technical field [0001] The invention belongs to the technical field of functional fiber manufacturing, and relates to a conductive fiber with excellent electrical conductivity and a preparation process thereof. Background technique [0002] Composite conductive fiber is a kind of conductive fiber obtained by adding conductive particles such as carbon black, TiO2, SnO2, ZnO, CuI, etc. to the polymer. Its conductive principle is that when the content of conductive filler in the polymer filling system reaches a critical point, The conductive particles form a conductive channel in the matrix, and the polymer changes from an insulator to a semiconductor, so that its own resistance drops sharply, and it plays the role of conduction, that is, anti-static. Its conductivity mainly depends on the type of particles used, the type of polymer, the dispersion form of conductive particles in the matrix, the content of conductive particles, the morphology of the polymer matrix, and the mold...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01F8/14D01F8/12D01F6/92D01F6/90D01F1/09D01D5/34
Inventor 赵茂成陈琳钱君杰曾彬雅
Owner SHANGHAI VITA SCI & TECH
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