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A method for manufacturing high-performance bleached impregnated flame-retardant insulating paper

A manufacturing method and technology of insulating paper, applied in paper, papermaking, paper coating and other directions, can solve the problem of low flame retardant loading efficiency, export manufacturing obstacles, and hinder the healthy development of bleaching impregnated insulating paper and environmentally friendly paper-based copper clad laminate industries and other problems, to achieve the effect of excellent breakdown voltage and simplified processing technology

Inactive Publication Date: 2016-06-29
SOUTH CHINA UNIV OF TECH +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This form of flame retardant treatment may cause two adverse consequences: (1) Compatibility of flame retardants and solvents; considering the narrow range of flame retardants compatible with solvents, most of them are halogen-containing and non-environmentally friendly flame retardants (2) Due to the high viscosity and permeability of the solvent, the loading efficiency of the flame retardant on the insulating paper is low, resulting in the need to add a high content of flame retardant and solvent to make the product reach Anticipated strength and flame retardancy requirements, thereby increasing the production cost of the end product
There are few enterprises producing impregnated and bleached insulating paper in my country, and the relevant performance indicators and technical level are still far behind those of developed countries such as Japan, Europe and the United States. Some key technologies are still monopolized by foreign companies, because of their high price, hindering The healthy development of my country's related bleached impregnated insulating paper and environmentally friendly paper-based copper-clad laminate industries

Method used

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  • A method for manufacturing high-performance bleached impregnated flame-retardant insulating paper

Examples

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Effect test

Embodiment 1

[0030] A manufacturing method of high-performance impregnated bleached flame-retardant insulating paper includes the following steps and process conditions:

[0031] (1) Pulp fiber selection and slurry preparation: Wash the bleached sulphate eucalyptus pulp with water, and disperse it with a decomposer, adjust its beating degree to 20°SR through a free-form beating process, and dilute it to a mass concentration of 0.1 % Pulp suspension.

[0032] (2) Preparation of treatment liquid added in the pulp: The cationic modified starch adhesive (model YZ-121, produced by Hangzhou Zhiyou Technology Co., Ltd.) was gelatinized in an aqueous solution at 90°C for 2 hours, and the prepared starch mass concentration was 5% starch solution for use; dilute and mix polyamide polyepichlorohydrin resin (PPE type, produced by Foshan Nanhai Junneng Paper Material Factory) in an aqueous solution to prepare a PPE solution with a mass concentration of 2%. Use; Sodium carboxymethyl cellulose (CMC) as a wet...

Embodiment 2

[0042] A method for manufacturing high-performance bleach-impregnated flame-retardant insulating paper includes the following steps and process conditions:

[0043] (1) Selection of pulp fiber and preparation of pulp: Wash the bleached sulphate eucalyptus pulp with water, and disperse and disperse it with a decomposer, adjust its beating degree to 22°SR through the free-form beating process, and dilute it to a mass concentration It is a 0.1% pulp suspension.

[0044] (2) Preparation of treatment solution added in the pulp: an appropriate amount of modified cationic starch (YZ-121, produced by Hangzhou Zhiyou Technology Co., Ltd.) was gelatinized in an aqueous solution at 90°C for 2 hours, and the prepared starch mass concentration was 5% The cationic modified starch adhesive solution is ready for use; the modified urea-formaldehyde resin wet strength agent (YM02, produced by Jiangmen Xinhui Dongrun Paint Co., Ltd.) is diluted and mixed in an aqueous solution to prepare a PPE with a...

Embodiment 3

[0050] A manufacturing method of high-performance impregnated bleached flame-retardant insulating paper includes the following steps and process conditions:

[0051] (1) Pulp fiber selection and slurry preparation: Wash the bleached kraft pine wood pulp with water, and use a decomposing machine to decompose and disperse, adjust its beating degree to 25°SR through the free beating process, and dilute it to a mass concentration of 0.1% pulp suspension.

[0052] (2) Preparation of treatment liquid added to the pulp: an appropriate amount of modified anionic starch (model YZ-171, produced by Hangzhou Zhiyou Technology Co., Ltd.) was gelatinized in an aqueous solution at 90°C for 2 hours to prepare anionic modified starch glue The anionic modified starch adhesive solution with the adhesive concentration of 5% is ready for use; the polyamide polyepichlorohydrin resin (PPE type, produced by Foshan Nanhai Junneng Paper Material Factory) is diluted and mixed in the aqueous solution to prepa...

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Abstract

The invention discloses a method for making high-performance bleached impregnated flame-retardant insulating paper. The method is used for making the bleached insulating paper through paper making technology with bleached paper pulp as the base material, and comprises the following steps: adding starch, a wet strength agent and sodium carboxymethyl cellulose in the pulp; performing sizing, squeezing and drying in insulating paper pulp; impregnating the insulating paper in a mixture impregnation liquid for 10-120 seconds, extruding, squeezing and drying, wherein the mixture impregnation liquid is prepared by mixing a flame retardant solution, a modified starch solution and a sodium carboxymethyl cellulose to the homogeneous state under the condition of room temperature. The bleached impregnated flame-retardant insulating obtained according to the method contains no halogen elements, is low-carbon and environmentally friendly, and has excellent breakdown voltage and dielectric strength; and the flame retardant level of the insulating paper is V0, the paper white degree is not less than 80 percent, the dry tensile strength is 3.0-4.2 KN / m, the wet tensile strength is 0.30-0.65 KN / m, and the volume resistivity is (0.8-1.2)*10<6>.

Description

Technical field [0001] The invention relates to a high-performance impregnated bleached insulating paper product, in particular to a method for manufacturing a new type of insulating paper product with ultra-high insulation performance composed of nearly 100% vegetable pulp fibers. The ultra-high performance new type of insulating aramid material can In the field of electronic and electrical insulation, such as PCB copper clad laminates, transformers, electrodes, ships, missiles and other military and civilian applications. Background technique [0002] With the rapid development of electronic technology, copper clad laminates have been widely used, especially environmentally friendly paper-based copper clad laminates made of environmentally friendly paper as the base material, which is in line with the current environmental and low-carbon development direction of electronic products. Bleached impregnated insulating paper is a special substrate for the insulating layer of copper-...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D21H17/26D21H17/28D21H21/20D21H21/34D21H19/54D21H19/52D21H11/06D21H11/12D21H11/14
Inventor 刘德桃周佩君吴寿强程凡杨忠岩陈进波刘斯丹潘小磊沈珊静陈克复
Owner SOUTH CHINA UNIV OF TECH
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