Anticorrosive, anti-fading and environmentally-friendly water-based magnesium alloy cutting fluid

Abstract

The invention discloses anticorrosive, anti-fading and environmentally-friendly water-based magnesium alloy cutting fluid. The anticorrosive, anti-fading and environmentally-friendly water-based magnesium alloy cutting fluid is prepared from the following components in percentage by mass: 5 to 10 parts of base oil, 5 to 15 parts of an oiliness agent, 10 to 25 parts of organic amine, 5 to 15 parts of a synthetic rust inhibitor, 15 to 25 parts of a functional polyether surfactant, 0.2 to 3 parts of an extreme pressure additive, 3 to 8 parts of a solubilizer, 0.1 to 2 parts of a metal corrosion inhibitor, 0.1 to 2 parts of a magnesium alloy anti-fading agent, 0.1 to 2 parts of a bactericide, 0.1 to 1 part of an antifoaming agent, 0.1 to 10 parts of a pH regulator and 15 to 30 parts of water. The nticorrosive, anti-fading and environmentally-friendly water-based magnesium alloy cutting fluid is outstanding in ticorrosive and lubricating and has water resisting performances, and is high in cleaning and cooling effects, and effectively reduces the major technical problems such as corrosion, oxidative combustion, fading of magnesium alloy, demulsification and layering of the cutting fluid in the magnesium alloy processing process; the pH ranges from 9 to 11, and therefore, the demand of magnesium alloy cutting process can be met well.

Description

technical field

[0001] The invention relates to the field of fine chemicals, in particular to an anti-corrosion, anti-discoloration and environment-friendly water-based magnesium alloy cutting fluid. Background technique

[0002] Magnesium alloys are mainly divided into Mg-Al-Mn series, Mg-Al-Zn-Mn series, Mg-Al-Si-Mn series, Mg-Al-RE series, Mg-Zn-RE series and Mg -Zn-Zr system. The density of magnesium alloy is small, about 2 / 3 of the density of aluminum. It has high specific strength and specific stiffness, strong shock absorption, strong resistance to electromagnetic interference, good dimensional stability, machinability, Electrical and thermal conductivity, etc.; low temperature dependence, small linear shrinkage, high recycling rate, in line with environmental protection requirements. Therefore, magnesium alloys have gained widespread attention in many fields such as automobiles, electronic appliances, and aviation.

[0003] With the increasing application of magne...

Examples

Embodiment 1

[0034] An anti-corrosion, anti-discoloration and environment-friendly water-based magnesium alloy cutting fluid, which is prepared from the following raw materials:

[0035] Base oil 26# white oil 10g, oily agent rice bran oil fatty acid 9g, organic amine triethanolamine 24g, oleic acid 2g, lauroyl sarcosine 5g, diethylenetriamine 2g, composite surfactant 18g, extreme pressure additive chlorinated paraffin 0.5g, solubilizer ethylene glycol 8g, corrosion inhibitor triazole 0.3g, magnesium alloy anti-discoloration agent DS-175A 0.8g, MBM fungicide 1g, emulsified silicone oil defoamer 0.1g, complexing agent ethylenediaminetetra Disodium acetate (disodium EDTA) 1.2g, pH adjuster boric acid 3g, balance water, total 100.

[0036] The composite surfactant is a compound product of a general-purpose surfactant and a functional polyether surfactant. The general-purpose surfactant is composed of an emulsifier TX-9 and Tween 20 at a ratio of 1:1. The functional polyether surface The acti...

Embodiment 2

[0042] An anti-corrosion, anti-discoloration and environment-friendly water-based magnesium alloy cutting fluid, which is prepared from the following raw materials:

[0043] 500SN base oil 9g, sebacic acid 6g, triethanolamine 14g, diethanolamine 10g, tall oleic acid 11g, N-octanoyl aspartic acid 2g, hydroxyethylethylenediamine 2g, complex surfactant 20g, fatty alcohol Polyoxyethylene ether sulfate sodium salt (AES) 0.8g, diethylene glycol monobutyl ether 5g, benzotriazole 0.2g, magnesium alloy anti-discoloration agent DS-175A 1g, BK triazine fungicide 0.5g, 0.1g of silicone oil defoamer, 1.5g of sodium citrate, 2g of boric acid, and the rest of water.

[0044] Composite surfactants are compounded of general-purpose surfactants and functional polyether surfactants. The general-purpose surfactant is fatty alcohol polyoxyethylene ether AEO-7 and Tween 80 mixed at a ratio of 1:1, and the functional polyether surfactant is propylene glycol as the starting agent, random ethylene ox...

Embodiment 3

[0049] An anti-corrosion, anti-discoloration and environment-friendly water-based magnesium alloy cutting fluid is prepared from the following raw materials:

[0050] 150BS base oil 9g, rapeseed oil fatty acid 12g, triethanolamine 15g, monoethanolamine 10g, ricinoleic acid 6g, N-octanoyl glutamic acid 3g, diethylenetriamine 3g, composite surfactant 15g, MOA-3PK 0.8g , diethylene glycol 7g, urotropine 0.3g, magnesium alloy anti-discoloration agent DS-175A 1.2g, 2-benzisothiazolin-3-one (BIT) 0.1g, silicone oil defoamer 0.1g, times Sodium nitrilotriacetate (NTA sodium salt) 1.2g, boric acid 3g, balance water.

[0051] Composite surfactants are compounded of general-purpose surfactants and functional polyether surfactants. The general-purpose surfactant is isomerized alcohol polyoxyethylene ether E-1009 and nonylphenol polyoxyethylene ether TX-9 mixed at a ratio of 1:1, the functional polyether surfactant is propylene glycol as the initiator, epoxy A random copolymer of ethylen...

technical field

[0001] The invention relates to the field of fine chemicals, in particular to an anti-corrosion, anti-discoloration and environment-friendly water-based magnesium alloy cutting fluid. Background technique

[0002] Magnesium alloys are mainly divided into Mg-Al-Mn series, Mg-Al-Zn-Mn series, Mg-Al-Si-Mn series, Mg-Al-RE series, Mg-Zn-RE series and Mg -Zn-Zr system. The density of magnesium alloy is small, about 2 / 3 of the density of aluminum. It has high specific strength and specific stiffness, strong shock absorption, strong resistance to electromagnetic interference, good dimensional stability, machinability, Electrical and thermal conductivity, etc.; low temperature dependence, small linear shrinkage, high recycling rate, in line with environmental protection requirements. Therefore, magnesium alloys have gained widespread attention in many fields such as automobiles, electronic appliances, and aviation.

[0003] With the increasing application of magne...

Examples

Embodiment 1

[0034] An anti-corrosion, anti-discoloration and environment-friendly water-based magnesium alloy cutting fluid, which is prepared from the following raw materials:

[0035] Base oil 26# white oil 10g, oily agent rice bran oil fatty acid 9g, organic amine triethanolamine 24g, oleic acid 2g, lauroyl sarcosine 5g, diethylenetriamine 2g, composite surfactant 18g, extreme pressure additive chlorinated paraffin 0.5g, solubilizer ethylene glycol 8g, corrosion inhibitor triazole 0.3g, magnesium alloy anti-discoloration agent DS-175A 0.8g, MBM fungicide 1g, emulsified silicone oil defoamer 0.1g, complexing agent ethylenediaminetetra Disodium acetate (disodium EDTA) 1.2g, pH adjuster boric acid 3g, balance water, total 100.

[0036] The composite surfactant is a compound product of a general-purpose surfactant and a functional polyether surfactant. The general-purpose surfactant is composed of an emulsifier TX-9 and Tween 20 at a ratio of 1:1. The functional polyether surface The acti...

Embodiment 2

[0042] An anti-corrosion, anti-discoloration and environment-friendly water-based magnesium alloy cutting fluid, which is prepared from the following raw materials:

[0043] 500SN base oil 9g, sebacic acid 6g, triethanolamine 14g, diethanolamine 10g, tall oleic acid 11g, N-octanoyl aspartic acid 2g, hydroxyethylethylenediamine 2g, complex surfactant 20g, fatty alcohol Polyoxyethylene ether sulfate sodium salt (AES) 0.8g, diethylene glycol monobutyl ether 5g, benzotriazole 0.2g, magnesium alloy anti-discoloration agent DS-175A 1g, BK triazine fungicide 0.5g, 0.1g of silicone oil defoamer, 1.5g of sodium citrate, 2g of boric acid, and the rest of water.

[0044] Composite surfactants are compounded of general-purpose surfactants and functional polyether surfactants. The general-purpose surfactant is fatty alcohol polyoxyethylene ether AEO-7 and Tween 80 mixed at a ratio of 1:1, and the functional polyether surfactant is propylene glycol as the starting agent, random ethylene ox...

Embodiment 3

[0049] An anti-corrosion, anti-discoloration and environment-friendly water-based magnesium alloy cutting fluid is prepared from the following raw materials:

[0050] 150BS base oil 9g, rapeseed oil fatty acid 12g, triethanolamine 15g, monoethanolamine 10g, ricinoleic acid 6g, N-octanoyl glutamic acid 3g, diethylenetriamine 3g, composite surfactant 15g, MOA-3PK 0.8g , diethylene glycol 7g, urotropine 0.3g, magnesium alloy anti-discoloration agent DS-175A 1.2g, 2-benzisothiazolin-3-one (BIT) 0.1g, silicone oil defoamer 0.1g, times Sodium nitrilotriacetate (NTA sodium salt) 1.2g, boric acid 3g, balance water.

[0051] Composite surfactants are compounded of general-purpose surfactants and functional polyether surfactants. The general-purpose surfactant is isomerized alcohol polyoxyethylene ether E-1009 and nonylphenol polyoxyethylene ether TX-9 mixed at a ratio of 1:1, the functional polyether surfactant is propylene glycol as the initiator, epoxy A random copolymer of ethylen...

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