Halogen-free red phosphorus-free heat shrinkable tube and its preparation method
A heat-shrinkable sleeve, red phosphorus technology, applied in the field of materials, can solve the hidden dangers of safety accidents, slow chemical reactions, red phosphorus pungent snuff, etc., to avoid safety accidents, promote uniform dispersion, and good flame retardant effect. Effect
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Embodiment 1
[0042] A halogen-free and red phosphorus-free heat-shrinkable sleeve, the components of which are calculated in parts by weight:
[0043] 45 parts of EVA U5110J (ethylene-acetic acid copolymer) as the base material;
[0044] EVA 2803 (ethylene-acetic acid copolymer) 10 parts;
[0045] 5 parts of ethylene-octene copolymer elastomer;
[0046] 30 parts of halogen-free flame retardant;
[0047] 15 parts of magnesium hydroxide;
[0048] 10 parts of nano calcium carbonate;
[0049] 1 part of maleic anhydride copolymerized modified polymer;
[0050] Antioxidant 1 part;
[0051] Among them, the halogen-free flame retardant is composed of 85% by weight of aluminum diethyl hypophosphite ALDP, 5% by weight of melamine pyrophosphate MPP, and 10% by weight of a triazine char-forming agent.
[0052] The vinyl acetate weight content of the ethylene-acetic acid copolymer is 17%-20%, the melt index is 1-5g / 10min (190°C), and the tensile strength is greater than 10MPa.
Embodiment 2
[0054] A halogen-free and red phosphorus-free heat-shrinkable sleeve, the components of which are calculated in parts by weight:
[0055] 40 parts of EVA U5110J (ethylene-acetic acid copolymer) as the base material;
[0056] EVA 2803 (ethylene-acetic acid copolymer) 15 parts;
[0057] 2 parts of ethylene-octene copolymer elastomer;
[0058] 40 parts of halogen-free flame retardant;
[0059] 30 parts of magnesium hydroxide;
[0060] 5 parts of nano calcium carbonate;
[0061] 3 parts of maleic anhydride copolymerized modified polymer;
[0062] 1 part lubricant;
[0063] 4 parts coloring agent;
[0064] 0.5 part of antioxidant;
[0065]Among them, the halogen-free flame retardant is composed of 95% by weight of aluminum diethyl hypophosphite, 3% by weight of melamine pyrophosphate, and 2% by weight of a triazine char-forming agent.
[0066] The vinyl acetate weight content of the ethylene-acetic acid copolymer is 17%-20%, the melt index is 1-5g / 10min (190°C), and the ten...
Embodiment 3
[0068] A halogen-free and red phosphorus-free heat-shrinkable sleeve, the components of which are calculated in parts by weight:
[0069] 40 parts of EVA 4110 (ethylene-acetic acid copolymer) as the base material;
[0070] EVA U5110J (ethylene-acetic acid copolymer) 5 parts;
[0071] 5 parts of ethylene-octene copolymer elastomer;
[0072] 30 parts of halogen-free flame retardant;
[0073] 1 part aluminum hydroxide;
[0074] 1 part talcum powder;
[0075] 0.1 part of maleic anhydride copolymerized modified polymer;
[0076] 1.5 parts of lubricant;
[0077] 3 parts carbon black;
[0078] Antioxidant 0.1 part;
[0079] Among them, the halogen-free flame retardant is composed of 90% by weight of aluminum diethyl hypophosphite, 5% by weight of melamine pyrophosphate, and 5% by weight of triazine char-forming agent.
[0080] The vinyl acetate weight content of the ethylene-acetic acid copolymer is 17%-20%, the melt index is 1-5g / 10min (190°C), and the tensile strength is gr...
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