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A kind of polypropylene microcrystalline ceramic composite material and preparation method thereof

A technology of microcrystalline ceramics and composite materials, which is applied in the field of functionalized, high-performance polypropylene microcrystalline ceramic composite materials and its preparation, can solve problems such as the influence of mechanical properties, and achieve improved mechanical strength, toughness, and interface bonding strength Effect

Inactive Publication Date: 2017-08-29
QINGDAO UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the addition of a large amount of fillers, while enhancing at least one mechanical property of the composite, often adversely affects other mechanical properties

Method used

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  • A kind of polypropylene microcrystalline ceramic composite material and preparation method thereof
  • A kind of polypropylene microcrystalline ceramic composite material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] A kind of composite material, concrete preparation method is as follows:

[0036] 1) Weigh 30kg of silicate microcrystalline ceramics, 60kg of zinc oxide (fineness ≥ 800 mesh), 2kg of montmorillonite, and 2kg of isopropyl triisostearyl titanate (TTS), and knead each component In the kneader, knead for 20 minutes under the conditions of kneader stirring blade rotation speed 1000 rpm and kneader temperature 100°C, then discharge and cool to room temperature;

[0037] 2) The weight components are polypropylene (PP) 100kg, maleic anhydride functionalized EPDM rubber (EPDM) 5kg, silicone powder 2kg, antioxidant 1010 0.4kg and other components are mixed, and taken out from the mixture 75kg, and 20kg of the composite material prepared in step 1 are put into a high-speed kneader for high-speed blending. The speed of the high-speed kneader is 1000 rpm, the kneading temperature is 80°C, and the kneading time is 10 minutes, then the material is discharged to form a mixture, and c...

Embodiment 2

[0040] A kind of composite material, concrete preparation method is as follows:

[0041] 1) Weigh 30kg of silicate microcrystalline ceramics, 60kg of zinc oxide (fineness ≥ 800 mesh), 2kg of montmorillonite, and 2kg of isopropyl triisostearyl titanate (TTS), and knead each component In the kneader, knead for 20 minutes under the conditions of kneader stirring blade speed 1000 rpm and kneader temperature 110°C, then discharge and cool to room temperature;

[0042] 2) The weight components are polypropylene (PP) 100kg, elastomer graft toughening agent 5kg, silicone powder 3kg, antioxidant 1010 0.5kg and other components are mixed in proportion, take out 70kg from the mixture and step 30kg of the compound material prepared in 1 was put into a high-speed kneader for high-speed blending. Then the speed of the high-speed kneader is 1000 rpm, the kneading temperature is about 80°C, and the kneading time is 10 minutes, then the material is discharged to form a mixture, and cooled to ...

Embodiment 3

[0045] A kind of composite material, concrete preparation method is as follows:

[0046] 1) Weigh 30kg of silicate microcrystalline ceramics, 60kg of zinc oxide (fineness ≥ 800 mesh), 2kg of montmorillonite, and 2kg of isopropyl triisostearyl titanate (TTS), and knead each component In the kneader, knead for 20 minutes under the conditions of kneader stirring blade rotation speed 1000 rpm and kneader temperature 100°C, then discharge and cool to room temperature;

[0047] 2) The weight components are mixed with components such as polypropylene (PP) 100kg, elastomer graft toughening agent 8kg, silicone powder 2kg, 1010 antioxidant 0.4kg, and take out 80kg from the mixture with step 1 20kg of the prepared composite material was put into a high-speed kneader for high-speed blending. The speed of the high-speed kneader is 1000 rpm, the kneading temperature is about 80°C, and the kneading time is 10 minutes, then the material is discharged to form a mixture, and cooled to room tem...

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Abstract

The invention discloses a polypropylene ceramic composite material including, by weight, a polypropylene resin matrix system: 100 parts of polypropylene (PP), 1-5 parts of silicone powder, 5-10 parts of an elastomer graft toughening modifying agent, 0.5-1 part of antioxygen 1010; a microcrystal ceramic system: 30-56 parts of metasilicate microcrystal ceramic, 60-66 parts of zinc oxide, 2-3 parts of montmorillonoid, 2-3 parts of a titanate coupling reagent; weight ratio of the polypropylene resin matrix system to the microcrystal ceramic system is 70-80 : 30-20. The polypropylene ceramic composite material and a preparation method of the polypropylene ceramic composite material have the advantages that the problems of corrosion and abrasion in the process of using traditional oil and gas gathering and transferring pipelines are solved. The silicone powder in the formula system not only improves the liquidity of the system, but also increases the toughness of the system; as the same of the elastomer graft, the elastomer graft can improve interface adhesive strength of a PP matrix and the microcrystal ceramic, improve the mechanical strength of the composite material, and toughen the matrix.

Description

technical field [0001] The invention relates to the technical field of composite materials and their preparation, in particular to a functionalized high-performance polypropylene microcrystalline ceramic composite material with special properties such as high anticorrosion, high strength, high temperature resistance, and high wear resistance, and a preparation method thereof. Background technique [0002] The transportation of oil and natural gas resources in my country mainly depends on pipelines, which are generally steel spiral welded pipes. Due to the complex terrain that the pipeline traverses, the environment is not only spatially different, but also subject to erosion by various media over time. 28% of leaks in these pipelines were due to corrosion perforation. Corrosion of pipelines will not only cause oil and gas leakage loss caused by perforation, fire, etc., but also waste materials and manpower caused by maintenance. [0003] The composite material of the prese...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/12C08L83/04C08L51/04C08K13/06C08K9/04C08K5/134C08K3/34C08K3/22B29C47/92B29C48/92
CPCB29C48/92C08K2201/005C08L23/12C08L2201/08C08L2203/18C08L2205/03C08L83/04C08L51/04C08K13/06C08K9/04C08K3/34C08K2003/2296C08K3/346C08K5/1345
Inventor 邱桂学潘炯玺陈明孟北谢雁李宁赵猛周泽衡
Owner QINGDAO UNIV OF SCI & TECH