A method for removing endocrine disruptors in water by activating monopersulfate using cerium-iron dual-phase supported graphene oxide
A technology of endocrine disruptors and persulfates, applied in chemical instruments and methods, other chemical processes, adsorption water/sewage treatment, etc., can solve the problems of difficult recovery of adsorbents, low removal efficiency, and many by-products, and achieve easy Recycling and regeneration, fast response, and low cost effects
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specific Embodiment approach 1
[0036] Specific embodiment one: This embodiment is a kind of method that utilizes cerium-iron dual-phase loaded graphene oxide to activate monopersulfate to remove endocrine disruptors in water and is completed according to the following steps:
[0037] 1. Mix the monopersulfate with the pretreated water: Mix the monopersulfate with the pretreated water, and then stir for 20min to 45min at room temperature and at a stirring speed of 160r / min to 250r / min to obtain A mixed solution of monopersulfate and pretreated water;
[0038] The monopersulfate described in the step 1 is one or the mixture of several in potassium monopersulfate, ammonium monopersulfate, sodium monopersulfate and calcium monopersulfate;
[0039] The concentration of the endocrine disruptor in the pretreated water described in step 1 is 0.02mg / L~100mg / L;
[0040] The mass ratio of the quality of the monopersulfate described in the step 1 and the pretreated water is 1:(1000~10000);
[0041] 2. Adjust the pH v...
specific Embodiment approach 2
[0067] Embodiment 2: The difference between this embodiment and Embodiment 1 is that the endocrine disruptors described in step 1 are estrone, 17α-ethinyl estradiol, 17α-estradiol, 17β-estradiol, One or a mixture of estriol, diethylstilbestrol, nonylphenol, bisphenol A and octylphenol. Other steps are the same as in the first embodiment.
specific Embodiment approach 3
[0068] Embodiment 3: The difference between this embodiment and Embodiment 1 or 2 is that the power of the ultrasonic oscillator described in step 3 ① is 100W to 1000W. Other steps are the same as in the first or second embodiment.
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