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A kind of organic-inorganic composite nanofiber membrane filter material and preparation method thereof

A nanofiber membrane and inorganic composite technology, applied in the field of textile materials, can solve the problems of low specific surface area and porosity, difficulty in reaching the nanometer level of fiber diameter, expensive equipment, etc., achieve excellent flexibility and plasticity, and the film forming process is simple and fast , improve the filtering effect

Active Publication Date: 2018-08-10
WUHAN TEXTILE UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The disadvantage of the above technical solution is that this kind of fiber is prepared by ordinary melt spinning method, and the fiber diameter is difficult to reach the nanometer level. Compared with nanofiber, its specific surface area and porosity are low, thus affecting the filtration performance of the filter material
[0008] The disadvantage of the above technical solution is that the nanofiber material is an inorganic carbon material, which has poor plasticity and toughness, and it is difficult to process the filter material into a web; at the same time, the large-scale electrospinning equipment is expensive and costly, and it is difficult to widely apply in the field of filtration.
[0010] Although this method improves the adsorption performance of the nanofiber itself and improves the filtration effect of the material, it is difficult to effectively control the packing density of the fiber during the formation of the nanofiber membrane, so it is difficult to significantly reduce the filtration resistance of the membrane material.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0055] The dried 1KgPVA- co -PE masterbatch and 4Kg cellulose acetate butyrate (CAB) were uniformly mixed, extruded and granulated in a twin-screw extruder at a temperature of 175°C, and 5Kg of PVA-co-PE / CAB composite material was prepared , and then the composite material is spun by a melt spinning machine to obtain a composite fiber; the composite fiber is refluxed in acetone at 60°C for 72 hours to extract cellulose acetate butyrate, and the composite fiber after extracting cellulose acetate butyrate is subjected to normal temperature Dried to prepare PVA with an average diameter of 200 nm- co - PE nanofibers; 10 g of nanofibers and 1.1 g of calcium carbonate microparticles are dispersed in 1 L of ethanol, emulsified by an emulsifier to form a mixed suspension of nanofibers and calcium carbonate microparticles. at 2 m 2 The upper surface of the 20gsm PP melt-blown nonwoven fabric is coated with a mixed suspension, the coating thickness is 10 μm, and dried at room temperat...

Embodiment 2

[0057] After drying, 1Kg of PP masterbatch and 4Kg of cellulose acetate butyrate (CAB) were uniformly mixed, extruded and granulated in a twin-screw extruder at a temperature of 145°C, and 5Kg of PP / CAB composite material was prepared. Then the composite material is spun by a melt spinning machine to obtain a composite fiber; the composite fiber is refluxed in acetone at 60°C for 72 hours to extract cellulose acetate butyrate, and the composite fiber after extraction of cellulose acetate butyrate is dried at room temperature , to prepare PP nanofibers with PP as the continuous phase and an average diameter of 100 nm; disperse 10 g of nanofibers and 1.1 g of titanium dioxide microparticles in 1 L of ethanol, and emulsify them with an emulsifier to form nanofibers and titanium dioxide microparticles mixed suspension. at 2 m 2 The upper surface of 20gsm PP spunbonded nonwoven fabric is coated with mixed suspension, the coating thickness is 8 μm, and dried at room temperature, an...

Embodiment 3

[0059] After drying, 1Kg of PET masterbatch and 4Kg of cellulose acetate butyrate (CAB) were uniformly mixed, extruded and granulated in a twin-screw extruder at a temperature of 240°C, and 5Kg of PET / CAB composite material was prepared. Then the composite material is spun by a melt spinning machine to obtain a composite fiber; the composite fiber is refluxed in acetone at 60°C for 72 hours to extract cellulose acetate butyrate, and the composite fiber after extraction of cellulose acetate butyrate is dried at room temperature , to prepare PET nanofibers with PET as the continuous phase and an average diameter of 80 nm; disperse 10 g of nanofibers and 1.1 g of activated carbon microparticles in 1 L of ethanol, and emulsify through an emulsifier to form a mixture of nanofibers and activated carbon microparticles Mix the suspension. at 2 m 2 The upper surface of the 40gsm PET melt-blown nonwoven fabric is coated with a mixed suspension, the coating thickness is 4 μm, and dried ...

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Abstract

The invention relates to an organic and inorganic composite nanofiber membrane filtering material and a preparation method thereof. The organic and inorganic composite nanofiber membrane filtering material is composed of a non-woven fabric base material and an organic nanofiber membrane, which is attached to the surface of the non-woven fabric base material and scattered with inorganic nano active particles. The preparation process of organic nano fiber comprises performing blend-melt spinning with thermoplastic polymer and cellulose acetate butyrate, and performing solvent extraction to obtain thermoplastic polymer nanofiber; then proportionally dispersing the nanofiber and the inorganic nano active particles into ethanol to obtain a mixed suspension of the nanofiber and the inorganic active particles; lastly, evenly coating the suspension onto the surface of the non-woven fabric base material, and drying the coated non-woven fabric base material at room temperature to obtain the organic and inorganic composite nanofiber membrane filtering material. The preparation process of the organic and inorganic composite nanofiber membrane filtering material has the advantages of being simple in process, low in cost and energy consumption and high in yield. The nanofiber and the nano active particles in the organic and inorganic composite nanofiber membrane filtering material are three-dimensionally uniformly distributed, so that the organic and inorganic composite nanofiber membrane filtering material has the advantage of being stable in structure and excellent in absorbing and filtering performance.

Description

technical field [0001] The invention relates to an organic-inorganic composite nanofiber membrane filter material and a preparation method thereof, belonging to the technical field of textile materials. Background technique [0002] In the field of textile materials, nanofibers refer to ultrafine fibers with a diameter of less than 1000 microns. They have the characteristics of large specific surface area, large aspect ratio and easy film formation. They are widely used in the fields of human protection, biomedicine, energy information and industrial purification. Especially as a membrane filter material for air purification and water treatment. [0003] The nanofiber membrane material has high porosity and small pore size, which increases the probability of blocking and adsorbing small particles in the medium, thereby improving the filtration efficiency. The existing method mainly improves the filtration efficiency of the nanofiber membrane for particulate matter by changi...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D71/16B01D69/12B01D67/00
Inventor 刘轲王栋肖钻李沐芳马鹏飞
Owner WUHAN TEXTILE UNIV
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