Heat exchanger electrochemically-induced film formation method in circulating cooling water micro-alkalifying transition period
A technology of circulating cooling water and film forming method, which is applied in the field of combining cathodic protection and oxidant passivation to achieve great social and economic benefits, reduce thermal resistance, and protect metal substrates
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Examples
Embodiment 1
[0018] Off-line chemical cleaning for new construction systems with brass heat exchangers or for older systems during overhaul. Choose 500mm×500mm×10mm zinc plate or aluminum plate as sacrificial anode and immerse in circulating cooling water, use 12mm 2 Thick copper wires connect the anode to both ends of the heat exchanger, forming the primary cell. Then use hydrochloric acid, sulfuric acid or a solution with a ratio of 1:1 to citric acid to adjust the circulating water to acidity, pH=2~4, and circulate for 24 hours. During the cleaning process, measure Cu once every 2 hours. 2+ Content, and check the pH, if the pH rises, then replenish the acid in time. Draw the concentration versus time curve, the curve rises to the highest point, stop pickling.
[0019] Add NaOH, Na 2 CO 3 , NaHCO 3 One or more combinations of them are made into a carbonate buffer solution, the pH of the circulating water is adjusted to 8~9, and then hydrogen peroxide is added to make the H in the ci...
Embodiment 2
[0022] For new construction systems with carbon steel heat exchangers or older systems during overhaul, use the method in Example 1 for off-line chemical cleaning.
[0023] After cleaning, add FeSO 4 , Fe(NO 3 ) 2 or FeCl 2 A ferrous salt in the circulating water makes Fe 2+ The ion content is 1mmol / L~10mmol / L, Fe 2+ The ions move to the cathode under the action of the electric field of the primary battery, are adsorbed on the surface of the heat exchanger, and are reduced to iron atoms to form a pre-membrane of the same material as the matrix, which can effectively cover the surface dirt or corrosion points and prevent the alkaline oxidation environment. Localized accelerated corrosion occurs.
[0024] Then use the same steps as Example 1 to carry out alkalization and passivation, and finally form a dense iron oxide film on the surface of carbon steel, and realize self-renewal and leakage repair in a stable alkaline buffer solution, and control the corrosion rate of carb...
Embodiment 3
[0026] For old systems that require uninterrupted operation, online chemical cleaning is used. Adopt the cathodic protection scheme in Example 1, add strong acid and citric acid in a ratio of 1:1, adjust the pH of the system to 3~4, and monitor the metal ions and pH in the circulating water every day, add cleaning acid in time, and run for about 15 days , Complete in-line chemical cleaning.
[0027] For copper heat exchangers, directly use the method of example 1 to alkalinize and oxidize to obtain an oxide pre-film and complete the slight alkalization transition. For carbon steel heat exchangers, use Example 2 to perform ferrous iron adsorption and reduction pre-film first, and then use the alkalization oxidation method in Example 1 to obtain oxide pre-film to complete the transition.
PUM
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com