In-situ carbon-coating hexagon K0.7[Fe0.5Mn0.5]O2 nano material as well as preparation method and application thereof
A nanomaterial, hexagonal technology, applied in the field of nanomaterials and electrochemistry, can solve the problems of high capacity, poor conductivity, difficult morphology, etc., and achieve good cycle stability and energy consumption. The effect of low and high discharge specific capacity
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0036] In-situ carbon-coated hexagon K 0.7 [Fe 0.5 Mn 0.5 ]O 2 The preparation method of nanomaterials comprises the following steps:
[0037] 1) Put 7.0mmol KNO 3 , 5.0mmol Fe(NO 3 ) 3 .9H 2 O, 5.0 mmol Mn (CH 3 COO) 2 Add 6.0 g of oxalic acid to 20 mL of deionized water, and stir at 25°C until the solution is light yellow and transparent;
[0038] 2) The solution obtained in step 1) was moved to an 80°C water bath and stirred for 4 hours to obtain a brown-red transparent solution;
[0039] 3) Transfer the solution obtained in step 2) into a petri dish, and dry it at a constant temperature of 80°C;
[0040] 4) The solid obtained in step 3) is then rapidly transferred to a high temperature of 180 ° C and baked for 12 hours to obtain a loose solid structure;
[0041] 5) grinding the product obtained in step 4), and then calcining for 3 hours at 300° C. in air;
[0042] 6) Step 5) was moved to 600, 800 and 1000 °C and calcined for 8 hours under argon conditions to ob...
Embodiment 2
[0052] 1) Put 3.5 mmol K 2 CO 3 , 2.5mmol Fe 2 (SO 4 ) 3 .9H 2 O, 2.5 mmol Mn 2 CO 3 Add 2.0 g of citric acid to 20 mL of deionized water, and stir at 25°C until the solution is light yellow and transparent;
[0053] 2) The solution obtained in step 1) was moved to a 60°C water bath and stirred for 6 hours to obtain a brown-red transparent solution;
[0054] 3) Transfer the solution obtained in step 2) into a petri dish, and dry it at a constant temperature of 60°C;
[0055] 4) The solid obtained in step 3) is then rapidly transferred to a high temperature of 120 ° C and baked for 10 hours to obtain a loose solid structure;
[0056] 5) grinding the product obtained in step 4), and then calcining at 400° C. for 3 hours in air;
[0057] 6) Move step 5) to 600°C for calcination under argon for 12 hours to obtain in-situ carbon-coated hexagon K 0.7 [Fe 0.5 Mn 0.5 ]O 2 nanomaterials.
[0058] Coating hexagon K with in-situ carbon obtained in this example 0.7 [Fe 0.5...
Embodiment 3
[0060] 1) Put 3.5mmol KNO 3 , 1.75mmol K 2 SO 4 , 2.5mmol Fe(NO 3 ) 3 .9H 2 O, 1.25mmol Fe 2 (SO 4 ) 3 .7H 2 O, 2.5 mmol Mn (CH 3 COO) 2 , 1.25mmol Mn 2 CO 3 , 2.0g of oxalic acid and 2.0g of citric acid were added to 40mL of deionized water, and stirred at 25°C until the solution was light yellow and transparent;
[0061] 2) The solution obtained in step 1) was moved to a 50°C water bath and stirred for 6 hours to obtain a brown-red transparent solution;
[0062] 3) Transfer the solution obtained in step 2) into a petri dish, and dry it at a constant temperature of 90°C;
[0063] 4) The solid obtained in step 3) is then rapidly transferred to a high temperature of 200 ° C and baked for 10 hours to obtain a loose solid structure;
[0064] 5) Grind the product obtained in step 4). Then calcined at 500°C in air for 2 hours;
[0065] 6) Move step 5) to 1000°C for calcination under argon for 10 hours to obtain in-situ carbon-coated hexagon K 0.7 [Fe 0.5 Mn 0.5 ]...
PUM
Property | Measurement | Unit |
---|---|---|
Diameter | aaaaa | aaaaa |
Thickness | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com