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Flake zinc powder and nano silica doped epoxy zinc rich primer and preparation method thereof

An epoxy zinc-rich primer and nano-silica technology, which is applied in epoxy resin coatings, coatings, anti-corrosion coatings, etc., can solve the problems of low zinc powder content, affecting the anti-corrosion performance of the coating, and not easy to mix evenly , to achieve the effects of convenient construction, enhanced corrosion shielding ability, and improved corrosion resistance

Inactive Publication Date: 2015-06-17
COSCO KANSAI PAINT & CHEM TIANJIN
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Most of the existing zinc-rich primers are packaged in three components: component A includes film-forming base material, solvent, filler and additives, component B is curing agent, and component C is zinc powder, which are mixed according to the specified ratio during construction It is uniform and used after heating. The disadvantage is that the zinc powder content in the formed coating is low. It is inconvenient to weigh many times during construction, and it is not easy to stir evenly, which will affect the anti-corrosion performance of the coating.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] A kind of flaky zinc powder and nano silicon dioxide doped epoxy zinc-rich primer of the present invention, comprise main agent and curing agent composition, the mass ratio of main agent and curing agent composition is 15:1; Main agent comprises The following components by weight: bisphenol A type epoxy resin: 12 parts, solvent: 5 parts, spherical zinc powder: 68 parts, flake zinc powder: 9 parts, nano silicon dioxide: 4 parts, machine bentonite: 1 parts, wetting and dispersing agent: 1.2 parts, polyamide wax: 1 part; the curing agent composition comprises the following components in parts by weight: GX-460TI60 curing agent: 95 parts, solvent: 5 parts.

Embodiment 2

[0021] A kind of flaky zinc powder and nano silicon dioxide doped epoxy zinc-rich primer of the present invention, comprise main agent and curing agent composition, the mass ratio of main agent and curing agent composition is 19:1; Main agent comprises The following components by weight: bisphenol A type epoxy resin: 6 parts, solvent: 5 parts, spherical zinc powder: 80 parts, flaky zinc powder: 2.6 parts, nano silicon dioxide: 4 parts, fumed silicon dioxide : 1.8 parts, wetting and dispersing agent: 0.4 parts, polyamide wax: 3 parts; the curing agent composition comprises the following components by weight: GX-460TI60 curing agent: 90 parts, solvent: 9 parts.

Embodiment 3

[0023] A kind of flaky zinc powder and nano silicon dioxide doped epoxy zinc-rich primer of the present invention, comprise main agent and curing agent composition, the mass ratio of main agent and curing agent composition is 1571; Main agent contains following weight Parts of components: bisphenol A type epoxy resin: 9 parts, solvent: 5 parts, spherical zinc powder: 75 parts, flake zinc powder: 6 parts, nano-silica: 4 parts, butyl urea resin: 1.5 parts, wetting and dispersing agent: 0.8 parts, polyamide wax: 2 parts; curing agent composition contains the following components by weight: curing agent: 93 parts, solvent: 7 parts.

[0024] The nano-silica is nano-silica prepared by a sol-gel method.

[0025] The anti-sedimentation aid is one or more of organic bentonite, fumed silica, butyl urea resin, and oxidized polyethylene wax.

[0026] The wetting and dispersing agent is one or more of 5044 wetting and dispersing agents.

[0027] The spherical zinc powder is high zinc con...

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Abstract

A flake zinc powder and nano silica doped epoxy zinc rich primer includes a main agent and a curing agent in the weight ratio of 15: 1-19: 1. The main agent comprises the following components by weight: 6-12 parts of epoxy resin, 5 parts of a solvent, 68-80 parts of a spherical zinc powder, 2.6-9 parts of a flake zinc powder, 4 parts of nano silica, 1-1.8 parts of an anti-sedimentation agent, 0.4-1.2 parts of a wetting dispersant and 1-3 parts of polyamide wax. The curing agent composition contains the following components by weight: 90-95 parts of a curing agent and 5-9 parts of a solvent. The preparation method is as below: adding epoxy resin into the solvent, and adding the rest of the main agent, grinding and mixing evenly; evenly mixing the curing agent and solvent into a curing agent composition; preparing the main agent and the curing agent according to the mass ratio of 12: 1-19: 1 for preparation of a coating paint; and drying to reach above 80% of solid in the coating film. Addition of the flake zinc powder and nano silica reduces the pore among the particles in the filler and enhances the corrosion resistance.

Description

technical field [0001] The invention relates to a flaky zinc powder and nano silicon dioxide doped epoxy zinc-rich primer and a preparation method thereof. Background technique [0002] Most of the existing zinc-rich primers are packaged in three components: component A includes film-forming base material, solvent, filler and additives, component B is curing agent, and component C is zinc powder, which are mixed according to the specified ratio during construction It is uniform and used after heating. The disadvantage is that the zinc powder content in the formed coating is low. It is inconvenient to weigh many times during construction. It is not easy to stir evenly and affect the anti-corrosion performance of the coating. [0003] In view of this, the present invention is proposed. Contents of the invention [0004] The object of the present invention is to provide a kind of anti-corrosion flaky zinc powder and nano silicon dioxide doped epoxy zinc-rich primer. [0005...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D163/02C09D7/12C09D5/10
CPCC09D163/00C08K2201/011C08K2201/014C09D5/10C09D7/61C09D7/70C08L77/00C08K13/04C08K7/18C08K7/00C08K2003/0893C08K3/36C08K3/346C08L61/20
Inventor 程煜
Owner COSCO KANSAI PAINT & CHEM TIANJIN
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