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Preparation method of coarse whiting special for papermaking

A heavy calcium and calcite technology, applied in the direction of calcium carbonate/strontium/barium, etc., can solve the problems of unstable conditions, large powder particle size, low output, etc., and achieve good environmental benefits, good economic benefits, and high output.

Inactive Publication Date: 2015-07-01
江西科越科技有限公司
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  • Abstract
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Problems solved by technology

The above-mentioned methods are all chemical methods to prepare calcium carbonate, which have the advantages of high yield and high purity compared with traditional methods, and do not need to add Glauber’s salt to convert and evaporate and concentrate sodium sulfate; but the finally synthesized powder has a large particle size and a wide particle size distribution. Complex, unstable conditions, high energy consumption and low output, unable to meet market demand

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  • Preparation method of coarse whiting special for papermaking

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preparation example Construction

[0017] Such as figure 1 Shown, the preparation method step of special heavy calcium for papermaking is as follows:

[0018] S1 Primary crushing: Clean and screen the calcite ore; carry out the primary coarse crushing of the cleaned and screened calcite by 4-6cm; carry out the secondary crushing and fine crushing of the calcite after coarse crushing by 1-2cm; carry out the fine crushing of the calcite dry grinding;

[0019] S2 classification: classify the calcite powder obtained after dry grinding, and collect 600-mesh fine powder;

[0020] S3 slurry preparation: mix the collected 600-mesh calcite powder with water, and the solid content is 70%~80%;

[0021] S4 Wet grinding: wet grinding the slurry obtained by mixing slurry, adding polyacrylic acid grinding medium as zirconia micro-beads in the grinding, the weight ratio of grinding medium to zirconia micro-beads is 1:1.4~1:3.5, The speed of wet grinding is 1300 rpm~1700 rpm;

[0022] S5 passing through a vibrating sieve: p...

Embodiment 1

[0026] The raw material used is calcite ore, which is cleaned and screened, and then sent to a crusher for coarse crushing to a size smaller than or equal to 6 mm; the coarsely crushed calcite is then finely crushed to a size smaller than or equal to 2 mm to produce calcite fine powder; The finely crushed calcite fine powder is sent to Yifeng Mill for dry grinding, and after grinding, it is graded and screened to collect 600-mesh calcite fine powder; the 600-mesh calcite fine powder accounts for 70% of the solid content and 30% of water The ratio of % is made into a slurry; the prepared slurry is sent to a wet grinding machine, and polyacrylic acid and grinding media zirconia microbeads are added to grind it to form a slurry with a 2um content of 80-95. The material and oxidation The weight ratio of zirconium microbeads is 1:2.0, and the rotational speed of the wet grinding machine is 1700 rpm; the slurry obtained after wet grinding is passed through a vibrating sieve, and the ...

Embodiment 2

[0028] The raw material used is calcite ore, which is cleaned and screened, and then sent to the crusher for coarse crushing to less than or equal to 4mm; the coarsely crushed calcite is then finely crushed to be less than or equal to 1mm by the crusher to make calcite fine powder; Send the finely crushed calcite fine powder into dry grinding, and carry out classification treatment after grinding, and screen and collect 600-mesh calcite fine powder; mix 600-mesh calcite fine powder according to the ratio of solid content to 80% and water to 20%. into a slurry; the prepared slurry is sent to a wet grinding machine, and polyacrylic acid and grinding media zirconia microbeads are added to grind it into a slurry with a 2um content of 80-95. The material and zirconia microbeads The weight ratio is 1:3.5, and the speed of the wet grinding machine is 1300 rpm; the slurry obtained after wet grinding is passed through a vibrating sieve, and impurities such as zirconia microbeads and lar...

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Abstract

The invention provides a preparation method of coarse whiting special for papermaking. The preparation method comprises the steps of primary smashing, classifying, slurry mixing, wet grinding, vibrating screen passing and drying. The preparation method is characterized in that calcite fine powder with the particle size of 600 meshes is adopted by the wet grinding for slurry mixing, and the solid content of slurry is 70%-80%; polyacrylic acid is added during grinding, a grinding medium is zirconia microspheres, and the weight ratio of materials to the zirconia microspheres is 1:1.5-1:3.5. According to the invention, the coarse whiting special for papermaking is prepared by wet grinding, and compared with a chemical method for preparing the coarse whiting special for papermaking, the preparation method has the characteristics of low energy consumption, high yield, low cost and suitability for scale production. Since a physical method is adopted for preparation, no solvent, acid or alkali needs to be added during a preparation process, and no chemical pollution is generated to the environment. The preparation method is applicable to preparation of the coarse whiting special for papermaking, and meanwhile is applicable to preparation of other similar inorganic compound micron-scale products.

Description

technical field [0001] The invention relates to a method for preparing heavy calcium specially used for papermaking, and belongs to the technical field of preparing calcium carbonate by physical methods. Background technique [0002] Micron-sized calcium carbonate has the characteristics of high specific surface area, high activity, and good dispersion, and is widely used in papermaking, coatings, paints, and plastics. [0003] At present, the Glauber's salt-black ash method is generally used in China to produce ordinary calcium carbonate. The average particle size of the product is large (10μm), and the product quality is low. In the 1990s, Nippon Chemical Corporation developed a method for preparing precipitated calcium carbonate, namely the sulfuric acid precipitation method. In this method, an appropriate amount of alkali or alkaline silicate was added to the sulfuric acid solution and barium sulfide solution to control the pH value and continuously The mate...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01F11/18
Inventor 仇路
Owner 江西科越科技有限公司