High-adsorption performance biochar for heavy metal ions and preparation method for high-adsorption-performance biochar
A technology of heavy metal ions and biochar, applied in the field of polluted environment treatment, to achieve high adsorption performance, improve purification effect, and promote the effect of resource utilization
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[0020] A method for preparing biochar with high adsorption capacity for heavy metal ions, comprising the following steps:
[0021] (1) Naturally air-dry the collected biomass. After air-drying, the water content in the biomass is 2% by weight. After removing non-biological components such as sediment, crush and pass through a 20-100 mesh sieve;
[0022] (2) Mix the above pulverized biomass in proportion, add 5ml of rubidium chloride solution with a concentration of 0.05-1.5mol / L, mix well, seal it and let it stand for 12 hours, and let it dry naturally. The weight percentage of water in the biomass after air drying 4%;
[0023] (3) Put the above-mentioned treated biomass in a porcelain crucible for compaction, cover the lid for anaerobic pyrolysis, after the pyrolysis reaction is completed, take out the crucible after cooling to room temperature, and obtain crude biochar. The anaerobic pyrolysis temperature of biomass is 400-700°C, the pyrolysis time is 60-300min, and the hea...
Embodiment 1
[0028] One, a kind of biochar with high adsorption performance to heavy metal ions is prepared according to the following steps:
[0029] 1. Biomass raw material pretreatment
[0030] The sorghum dregs, rice dregs, glutinous rice dregs, wheat dregs, and corn dregs collected after brewing are air-dried naturally. Mesh sieve.
[0031] 2. Preparation method
[0032] (1) Mix the crushed sorghum dregs, rice dregs, glutinous rice dregs, wheat dregs, and corn dregs in a mass ratio of 4:6:4:3:1, and add 5ml of 0.1mol / L rubidium chloride solution Mix well, seal and let stand for 12 hours, and air dry naturally.
[0033] (2) Put the above-mentioned treated biomass raw material in a porcelain crucible for compaction, cover it, and pyrolyze it at 500°C for 120min, and the heating rate of pyrolysis is 10°C / min. After the pyrolysis reaction is over, take out the crucible after cooling to room temperature.
[0034] (3) Mix the above-prepared biochar with the HCl / HF mixture with an equal...
Embodiment 2
[0047] One, a kind of biochar with high adsorption performance to heavy metal ions is prepared according to the following steps:
[0048]1. Biomass raw material pretreatment: naturally air-dry the sorghum dregs, rice dregs, glutinous rice dregs, wheat dregs, and corn dregs collected after brewing. The biomass components were then pulverized through an 80-mesh sieve.
[0049] 2. Preparation method
[0050] (1) Mix the crushed sorghum dregs, rice dregs, glutinous rice dregs, wheat dregs, and corn dregs in a mass ratio of 5:8:4:4:1, and add 5ml of 0.1mol / L rubidium chloride solution Mix evenly, seal and let stand for 12 hours, and air-dry naturally. After air-drying, the weight percentage of water in the biomass is 5%.
[0051] (2) Put the above-mentioned treated biomass raw material in a porcelain crucible for compaction, cover it, and pyrolyze it at 500°C for 120min, and the heating rate of pyrolysis is 10°C / min. After the pyrolysis reaction is over, take out the crucible...
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