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High-adsorption performance biochar for heavy metal ions and preparation method for high-adsorption-performance biochar

A technology of heavy metal ions and biochar, applied in the field of polluted environment treatment, to achieve high adsorption performance, improve purification effect, and promote the effect of resource utilization

Inactive Publication Date: 2015-07-22
SICHUAN AGRI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, there are many researches on the preparation of biochar from organic materials at home and abroad, such as Zhang Jiyi from Lanzhou University of Technology and others using wheat straw to prepare biochar, Zhejiang University Chen Zaiming from rice straw to prepare biochar, Beijing University of Science and Technology Zhang Yang to prepare biochar from corncobs, etc. However, most of the existing researches use a single raw material to prepare biochar, while there are few studies on the preparation of biochar from mixed materials, especially the lack of targeted optimization of various biomass raw materials to prepare biochar with high adsorption performance for heavy metal ions. bio-charcoal

Method used

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preparation example Construction

[0020] A method for preparing biochar with high adsorption capacity for heavy metal ions, comprising the following steps:

[0021] (1) Naturally air-dry the collected biomass. After air-drying, the water content in the biomass is 2% by weight. After removing non-biological components such as sediment, crush and pass through a 20-100 mesh sieve;

[0022] (2) Mix the above pulverized biomass in proportion, add 5ml of rubidium chloride solution with a concentration of 0.05-1.5mol / L, mix well, seal it and let it stand for 12 hours, and let it dry naturally. The weight percentage of water in the biomass after air drying 4%;

[0023] (3) Put the above-mentioned treated biomass in a porcelain crucible for compaction, cover the lid for anaerobic pyrolysis, after the pyrolysis reaction is completed, take out the crucible after cooling to room temperature, and obtain crude biochar. The anaerobic pyrolysis temperature of biomass is 400-700°C, the pyrolysis time is 60-300min, and the hea...

Embodiment 1

[0028] One, a kind of biochar with high adsorption performance to heavy metal ions is prepared according to the following steps:

[0029] 1. Biomass raw material pretreatment

[0030] The sorghum dregs, rice dregs, glutinous rice dregs, wheat dregs, and corn dregs collected after brewing are air-dried naturally. Mesh sieve.

[0031] 2. Preparation method

[0032] (1) Mix the crushed sorghum dregs, rice dregs, glutinous rice dregs, wheat dregs, and corn dregs in a mass ratio of 4:6:4:3:1, and add 5ml of 0.1mol / L rubidium chloride solution Mix well, seal and let stand for 12 hours, and air dry naturally.

[0033] (2) Put the above-mentioned treated biomass raw material in a porcelain crucible for compaction, cover it, and pyrolyze it at 500°C for 120min, and the heating rate of pyrolysis is 10°C / min. After the pyrolysis reaction is over, take out the crucible after cooling to room temperature.

[0034] (3) Mix the above-prepared biochar with the HCl / HF mixture with an equal...

Embodiment 2

[0047] One, a kind of biochar with high adsorption performance to heavy metal ions is prepared according to the following steps:

[0048]1. Biomass raw material pretreatment: naturally air-dry the sorghum dregs, rice dregs, glutinous rice dregs, wheat dregs, and corn dregs collected after brewing. The biomass components were then pulverized through an 80-mesh sieve.

[0049] 2. Preparation method

[0050] (1) Mix the crushed sorghum dregs, rice dregs, glutinous rice dregs, wheat dregs, and corn dregs in a mass ratio of 5:8:4:4:1, and add 5ml of 0.1mol / L rubidium chloride solution Mix evenly, seal and let stand for 12 hours, and air-dry naturally. After air-drying, the weight percentage of water in the biomass is 5%.

[0051] (2) Put the above-mentioned treated biomass raw material in a porcelain crucible for compaction, cover it, and pyrolyze it at 500°C for 120min, and the heating rate of pyrolysis is 10°C / min. After the pyrolysis reaction is over, take out the crucible...

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Abstract

The invention discloses a high-adsorption performance biochar for heavy metal ions. The high-adsorption performance biochar is prepared by using sorghum residues, rice residues, glutinous rice residues, wheat residues and corn residues which are obtained after wine is brewed as raw materials and performing anaerobic pyrolysis; the high-adsorption performance biochar is characterized by being prepared by uniformly mixing the sorghum residues, the rice residues, the glutinous rice residues, the wheat residues and the corn residues which are crushed to a certain particle size in a certain mass ratio; adding a suitable amount of a rubidium chloride solution with an appropriate concentration; sealing and standing for 12 hours; performing high-temperature anaerobic pyrolysis on a mixture after the solution is dried naturally; soaking the mixture which is subjected to the high-temperature anaerobic pyrolysis by utilizing a mixed solution of HCl / HF; washing the mixture to neutral by utilizing distilled water. According to the biochar prepared by the preparation method, the content of lead, chromium, zinc and copper in water can be effectively reduced; the highest removal rates of the lead, the chromium, the zinc and the copper in the water can reach 99.2 percent, 85.3 percent, 82.9 percent and 85.9 percent.

Description

technical field [0001] The invention relates to a method for treating polluted environment, in particular to a method for preparing biochar with high adsorption performance for heavy metal ions. Background technique [0002] With the rapid development of industry, various industrial (such as smelting, electroplating, mining, etc.) wastewater and solid waste leachate are directly discharged into the water body, resulting in higher and higher heavy metal content in the water body. Heavy metals are not naturally degradable or biodegradable like organic compounds. They are often dissolved in water bodies or deposited at the bottom of water bodies, or absorbed by aquatic plants (phytoplankton, emergent plants), and accumulate through the food chain to damage animal and human health. Therefore, it is urgent to purify the heavy metals in wastewater. [0003] Using activated carbon to adsorb heavy metal wastewater has the advantages of simple treatment method and high adsorption ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/20B01J20/30C02F1/28C02F1/62
Inventor 朱启红伍钧杨刚张小洪漆辉彭宏余小玉李黎张延宗沈飞
Owner SICHUAN AGRI UNIV
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