Manufacturing method of heat-shrinkable auto-adhesive vacuum plating protective film

A protective film and manufacturing method technology, applied in the direction of flat products, applications, household appliances, etc., can solve the problems of the user's material loss of brand image, inability to play a protective role, damage to the surface quality of the product, etc., to achieve good re-peeling performance, Excellent barrier and mechanical properties, solve the effect of easy warping

Active Publication Date: 2015-07-22
WUXI HAITE NEW MATERIAL RES INST
View PDF7 Cites 8 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Since these materials have a relatively low glass transition temperature and molecular weight, the temperature resistance is greatly reduced. Therefore, it is difficult to peel off the surface of the substrate after the process protection is completed, and the adhesive resin is often transferred and remains on the protected body after peeling off. On the surface of the surface, alth

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Manufacturing method of heat-shrinkable auto-adhesive vacuum plating protective film

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0021] Example 1

[0022] A manufacturing method of heat-shrinkable self-adhesive vacuum plating protective film, including the following steps:

[0023] (1) Synthesize polyvinyl polyacrylate first: Dissolve 5 kg of glycidyl acrylate, 30 kg of methyl methacrylate, 10 kg of ethyl acrylate, 50 kg of butyl acrylate, and 5 kg of hydroxyethyl methacrylate in 200 mL of ethyl acetate. Obtain the comonomer solution from the ester, take out 1 / 2 comonomer solution, add 0.5kg azobisisoheptonitrile initiator and polymerize for 1 h at 80℃, then add the remaining 1 / 2 comonomer solution and the remaining 0.5 kg of azobis-isoheptonitrile initiator, after the addition is complete, continue to react for 3h, then, maintaining the reaction temperature unchanged, slowly add 0.2kg of triethylamine catalyst and 5kg of acrylic functional monomer, after the addition, continue React for 3 hours, and finally, use a rotary evaporator to concentrate the solution, let the solvent volatilize, and then obtain th...

Example Embodiment

[0025] Example 2

[0026] A manufacturing method of heat-shrinkable self-adhesive vacuum plating protective film, including the following steps:

[0027] (1) Synthesize polyvinyl polyacrylate first: Dissolve 10 kg of allyl glycidyl ester, 32 kg of methyl methacrylate, 40 kg of butyl acrylate, 10 kg of isooctyl acrylate, and 8 kg of hydroxyethyl methacrylate. Obtain the comonomer solution in 200L of toluene, take out 1 / 2 comonomer solution, add 0.6kg azobisisobutyronitrile initiator and polymerize at 85℃ for 1 h, then add the remaining 1 / 2 comonomer solution dropwise And the remaining 0.4 kg of azobisisobutyronitrile initiator, after the addition is complete, continue to react for 3h, then, maintaining the reaction temperature unchanged, slowly add 0.2kg of cetyltrimethylammonium bromide catalyst and 5kg of coat After the addition of the functional monomer of aconic acid, the reaction is continued for 3 hours. Finally, the solution is concentrated using a rotary evaporator to allow...

Example Embodiment

[0029] Example 3

[0030] A manufacturing method of heat-shrinkable self-adhesive vacuum plating protective film, including the following steps:

[0031] (1) Synthesize polyvinyl polyacrylate first: Dissolve 5 kg of glycidyl acrylate, 30 kg of methyl methacrylate, 10 kg of ethyl acrylate, 50 kg of butyl acrylate, and 5 kg of hydroxyethyl methacrylate in 200 mL of ethyl acetate. Obtain the comonomer solution from the ester, take out 1 / 2 comonomer solution, add 0.5kg azobisisoheptonitrile initiator and polymerize for 1 h at 80℃, then add the remaining 1 / 2 comonomer solution and the remaining 0.5 kg of azobis-isoheptonitrile initiator, after the addition is complete, continue to react for 3h, then, maintaining the reaction temperature unchanged, slowly add 0.2kg of triethylamine catalyst and 5kg of acrylic functional monomer, after the addition, continue React for 3 hours, and finally, use a rotary evaporator to concentrate the solution, let the solvent volatilize, and then obtain th...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses a manufacturing method of a heat-shrinkable auto-adhesive vacuum plating protective film. The manufacturing method comprises the following steps: (1) firstly, synthesizing polyvinyl polyacrylate; (2) then, performing melt blending on the polyvinyl polyacrylate, polyethylene resin, a first initiator and an antioxidant according to a weight proportion, extruding and granulating, and finally performing extrusion film blowing and UV curing to obtain the heat-shrinkable auto-adhesive vacuum plating protective film. The manufactured protective film wraps a local part, required to be protected, of a vacuum plating component in a heat shrinkage way; in a vacuum plating process, the surface of the film does not crease and deform, the adhesion force is stable, the attachment property is good, the re-peeling performance is excellent, the phenomenon of adhesive residue is avoided, and the barrier and mechanical properties are excellent; the heat-shrinkable auto-adhesive vacuum plating protective film is an excellent vacuum plating protective film material which is non-toxic, environmentally-friendly, safe and practical.

Description

technical field [0001] The invention relates to the field of protective films, in particular to a method for manufacturing a heat-shrinkable self-adhesive vacuum plating protective film. Background technique [0002] Vacuum coating protective film is a modified film material, which has the characteristics of self-adhesive and thermal shrinkage. It is actually a special pressure-sensitive adhesive film, which is mainly composed of substrate and pressure-sensitive materials. Compared with surface protection coatings, it has the advantages of convenient use, low price, and reliable effect, and has attracted much attention in the field of material surface protection. Since polyethylene material is cheap and its viscosity can be adjusted in a wide range according to different application requirements, the current substrate layer mainly uses polyethylene as raw material and is prepared by extrusion molding, injection molding, extrusion blown film molding and other methods. Howeve...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C08L33/08C08L23/06C08L23/08C08K5/134C08K5/526C08K5/13C08F220/18C08F220/14C08F220/28C08F220/32C08F220/06C08F222/02B29C35/08B29L7/00
Inventor 白永平李卫东魏群丁荣炎黄玉东
Owner WUXI HAITE NEW MATERIAL RES INST
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap