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Antistatic halogen-free flame retardation polypropylene sheet and making method thereof

A flame-retardant polypropylene and anti-static technology, applied in the field of anti-static halogen-free flame-retardant polypropylene sheet and its preparation, can solve the problems of the decline of physical properties of the sheet, the falling of burning objects, and the limitation of use, and achieve flame retardant High performance, good anti-static performance

Inactive Publication Date: 2015-08-19
POLYNOVA MATERIALS SUZHOU
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Chinese patent CN200810218610.3 discloses a halogen-free flame-retardant polypropylene composite insulating sheet, which adopts a three-layer composite structure. The flame retardant grade is gradually increased from HB, V-2, V-1 to V-0; the test standard of V-2 grade is: after two 10-second combustion tests on the sample, the flame is extinguished within 60 seconds; burning things may fall
However, the flame retardant performance of this patent has been improved, and the improvement of antistatic performance is not mentioned; moreover, the flame retardant, an inorganic powder substance, is added to the three layers of the structure, which will lead to a decrease in the overall physical properties of the sheet.
[0005] The existing technology generally achieves antistatic and antistatic properties by adding inorganic conductive particles such as carbon black and graphene, so generally it can only be made into black, which has caused great limitations to its use

Method used

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  • Antistatic halogen-free flame retardation polypropylene sheet and making method thereof
  • Antistatic halogen-free flame retardation polypropylene sheet and making method thereof
  • Antistatic halogen-free flame retardation polypropylene sheet and making method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0032] Weigh 60kg extrusion grade polypropylene, 7kg injection molding grade polypropylene, 23kg phosphorus nitrogen composite flame retardant, 1.5kg polytetrafluoroethylene dripping agent, 0.2kg antioxidant 1010, 0.2kg zinc stearate lubricant, by The twin-screw extruder extruded and granulated at 195°C to obtain halogen-free flame-retardant polypropylene pellets; put the pure polypropylene pellets into the main screw hopper of the three-layer co-extrusion sheet equipment, and the halogen-free flame-retardant polypropylene pellets Put it into the auxiliary screw hopper, melt and plasticize at 195°C respectively, and calender and extrude through the three-layer co-extruded sheet equipment. Propylene: Polythiophene is used as a conductive polymer, and isopropanol is used as a solvent to prepare a conductive polymer solution, and the conductive polymer is coated on the outside of the above-mentioned flame-retardant layer, polypropylene pure material layer, and flame-retardant laye...

Embodiment 2

[0035] Weigh 65kg of extrusion grade polypropylene, 8kg of injection molding grade polypropylene, 25kg of phosphorus nitrogen composite flame retardant, 2kg of polytetrafluoroethylene dripping agent, 0.3kg of antioxidant 1010, and 0.3kg of zinc stearate lubricant. The screw extruder is extruded and granulated at 190°C to obtain halogen-free flame-retardant polypropylene pellets; put the pure polypropylene pellets into the main screw hopper of the three-layer co-extrusion sheet equipment, and put the halogen-free flame-retardant polypropylene pellets Enter the auxiliary screw hopper, melt and plasticize separately at 190°C, calender and extrude through a three-layer co-extrusion sheet equipment, cool and trim after forming to obtain a flame-retardant layer, polypropylene pure material layer, flame-retardant layer, halogen-free flame-retardant polypropylene ; Polypyrrole is used as the conductive polymer, and ethanol / water (1:1 mass ratio) is used as the solvent to prepare the co...

Embodiment 3

[0037] Weigh 70kg of extrusion grade polypropylene, 5kg of injection molding grade polypropylene, 25kg of phosphorus nitrogen composite flame retardant, 1kg of polytetrafluoroethylene dripping agent, 0.2kg of antioxidant 1010, and 0.2kg of zinc stearate lubricant. The screw extruder is extruded and granulated at 190°C to obtain halogen-free flame-retardant polypropylene pellets; put the pure polypropylene pellets into the main screw hopper of the three-layer co-extrusion sheet equipment, and put the halogen-free flame-retardant polypropylene pellets Enter the auxiliary screw hopper, melt and plasticize separately at 190°C, calender and extrude through a three-layer co-extrusion sheet equipment, cool and trim after forming to obtain a flame-retardant layer, polypropylene pure material layer, flame-retardant layer, halogen-free flame-retardant polypropylene ; Polypyrrole is used as the conductive polymer, and ethanol / water (1:1 mass ratio) is used as the solvent to prepare the co...

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Abstract

The invention discloses an antistatic halogen-free flame retardation polypropylene sheet. The sheet comprises an antistatic layer, a flame retardation layer, a pure polypropylene layer, a flame retardation layer and an antistatic layer, wherein the pure polypropylene layer is made of an extrusion grade pure polypropylene material. The flame retardation layer of the antistatic halogen-free flame retardation polypropylene sheet has a flame retardation performance by adding a phosphorus-nitrogen flame retardant; and the antistatic layer realizes an antistatic performance by coating a conductive polymer solution, so the antistatic halogen-free flame retardation polypropylene sheet has the advantages of high flame retardation and good antistatic performance, and can be widely used in the electron industry.

Description

technical field [0001] The invention belongs to the field of composite plastic sheets, and in particular relates to an antistatic halogen-free flame-retardant polypropylene sheet and a preparation method thereof. Background technique [0002] Halogen-containing polymers or flame-retardant mixtures combined with halogen-containing flame retardants have excellent flame-retardant properties and have been widely used as flame-retardant materials. However, when a fire occurs, such halogen-containing flame-retardant materials will produce a large amount of smoke and toxic and corrosive hydrogen halide gas, causing secondary hazards. Halogen-free flame retardant material is to add halogen-free flame retardant to the material, this material does not volatilize and does not produce corrosive gas when burned. Halogen-free flame retardants are mainly phosphorus compounds and metal hydroxides, and there are also silicon-based flame retardants and nitrogen-based flame retardants. These ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B27/06B32B27/18B32B27/32B32B37/02C08L23/12C08L27/18
Inventor 朱木兰葛英黄哲军
Owner POLYNOVA MATERIALS SUZHOU
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