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Hexagonal boron nitride/polypropylene polymer composite and preparation method

A technology of hexagonal boron nitride and composite materials, which is applied in the field of hexagonal boron nitride/polypropylene polymer composite materials and its preparation, can solve the problems of poor insulation performance, complicated processing technology, and low thermal conductivity, and achieve bending strength and flexural modulus improvement, the preparation method is simple and easy to operate, and the effect of excellent mechanical properties

Active Publication Date: 2015-08-26
LIAONING UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, its low thermal conductivity and poor mechanical properties cannot meet the industrial needs of heat dissipation and high strength.
At present, the common way to improve the thermal conductivity and enhance the mechanical properties of polypropylene is to add fillers with high thermal conductivity and high mechanical properties. Adding some fillers can improve the mechanical properties and thermal conductivity, but it will bring other defects, such as adding metal materials After that, its corrosion resistance is poor, the price is high, and it is not easy to process and shape; adding metal oxide materials will lead to high production costs and complicated processing technology; adding graphite materials will cause its insulation performance to deteriorate

Method used

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  • Hexagonal boron nitride/polypropylene polymer composite and preparation method
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  • Hexagonal boron nitride/polypropylene polymer composite and preparation method

Examples

Experimental program
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Effect test

Embodiment 1

[0024] Example 1 Hexagonal boron nitride / polypropylene polymer composite material

[0025] (1) The preparation method is as follows:

[0026] 1) Pretreatment of hexagonal boron nitride: dry the hexagonal boron nitride in a vacuum drying oven at 90°C for 8 hours. Then add 30% hydrogen peroxide to the dried hexagonal boron nitride to prepare a mixed solution with a concentration of 0.1g / mL, ultrasonicate for 30min, put it into the reaction kettle and stir at 100°C for 24h, after the reaction kettle is cooled to room temperature, The reactant was filtered, washed with deionized water until neutral, and then dried in a vacuum oven at 50° C. for 24 hours for later use.

[0027] 2) According to the following ratio, put the treated hexagonal boron nitride, polypropylene, antioxidant, lubricant and compatibilizer into the high-speed mixer and mix for 3-5 minutes, and put the evenly mixed materials into the same direction Melt extrusion in a screw extruder. The extruder adopts four-...

Embodiment 2

[0033] Example 2 Hexagonal boron nitride / polypropylene polymer composite material

[0034] The preparation method is the same as in Example 1, except that the mass ratio of hexagonal boron nitride and polypropylene is 1:15. The hexagonal boron nitride / polypropylene polymer composite material obtained in this example was tested for mechanical properties and thermal conductivity, and the results are shown in Table 1.

Embodiment 3

[0035] Example 3 Hexagonal boron nitride / polypropylene polymer composite material

[0036] The preparation method is the same as in Example 1, except that the mass ratio of hexagonal boron nitride and polypropylene is 1:10. The hexagonal boron nitride / polypropylene polymer composite material obtained in this example was tested for mechanical properties and thermal conductivity, and the results are shown in Table 1.

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Abstract

The invention discloses hexagonal boron nitride / polypropylene polymer composite and a preparation method thereof. According to the composite, polypropylene is taken as a main material, hexagonal boron nitride is taken as filler, an antioxidant, a lubricating agent and a compatilizer are added, and the composite is prepared, wherein the mass ratio of hexagonal boron nitride to polypropylene is 1: (2.2-18.8); the adding amount of the antioxidant accounts for 0.2%-1% of the total weight of hexagonal boron nitride and polypropylene, the adding amount of the lubricating agent accounts for 0.3%-1% of the total weight of hexagonal boron nitride and polypropylene, and the adding amount of the compatilizer accounts for 0.5%-1% of the total weight of hexagonal boron nitride and polypropylene. Compared with a polypropylene material matrix, the hexagonal boron nitride / polypropylene polymer composite prepared through a twin-screw extruder can enhance the mechanical property and can increase the thermal conductivity coefficient. The preparation process of the composite is simple to operate and environment-friendly, and the composite can obtain higher mechanical property and heat conductivity coefficient under the condition of the lower filler mixing amount and has important application value.

Description

technical field [0001] The invention relates to a hexagonal boron nitride / polypropylene polymer composite material with high mechanical and thermal conductivity and a preparation method thereof, belonging to the technical field of polymer material modification and processing. Background technique [0002] In recent years, in the field of polymer composite materials, polymer composite materials with high mechanical properties and high thermal conductivity have gradually become one of the research hotspots and priorities, and have attracted great attention from researchers. Various fields in the national economy have increasingly stringent performance requirements for high mechanical properties and high thermal conductivity materials. Traditional high mechanical properties and high thermal conductivity materials have different defects that are difficult to overcome, and it is difficult to meet the functional diversity of modern industries. requirements. Therefore, the develop...

Claims

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Application Information

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IPC IPC(8): C08L23/12C08K9/02C08K3/38C08K5/134C08K5/526C08K5/20C08K5/098
CPCC08L23/12C08L51/06C08K9/02C08K2003/385C08K5/1345C08K5/20C08K5/526C08K5/098C08L33/14
Inventor 张向东韩维坊吕通建葛春华关宏宇刘世财
Owner LIAONING UNIVERSITY
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