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Cellulose acetate electrostatic-spun film loaded AgCl-Ag catalyst and preparation method and application thereof

A cellulose acetate and electrospinning technology, applied in the direction of physical/chemical process catalysts, chemical instruments and methods, chemical/physical processes, etc., to achieve good practical application value, reduce usage, and cheap and easy-to-obtain raw materials

Active Publication Date: 2015-10-21
SOUTH CHINA UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Solar energy is an emerging renewable resource. It is particularly important to make full use of solar energy and realize its direct use. However, most semiconductors can only be excited and applied under ultraviolet light conditions.

Method used

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  • Cellulose acetate electrostatic-spun film loaded AgCl-Ag catalyst and preparation method and application thereof
  • Cellulose acetate electrostatic-spun film loaded AgCl-Ag catalyst and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] (1) Weighing cellulose acetate, using acetone and N,N-dimethylacetamide with a mass ratio of 2:1 as a solvent, configured as a cellulose acetate electrospinning solution with a mass fraction of 12%;

[0027] (2) the cellulose acetate electrospinning solution of step (1) is transferred in the electrospinning equipment, under the condition that the static voltage is 15kv, the receiving distance is 11cm, and the advancing speed of the electrospinning solution is 1ml / h Carry out electrospinning, obtain cellulose acetate electrospinning film;

[0028] (3) Place the cellulose acetate electrospun membrane between two 80ml test tubes, and inject 0.02mol / L AgNO into the two test tubes respectively. 3 solution and NaCl solution, placed in the dark for 72 hours to obtain a cellulose acetate electrospun membrane supported AgCl catalyst;

[0029] (4) washing the AgCl catalyst supported on the cellulose acetate electrospun membrane with deionized water, irradiating with sunlight, an...

Embodiment 2

[0032] (1) Weighing cellulose acetate, using acetone and N,N-dimethylacetamide with a mass ratio of 2:1 as a solvent, configured as a cellulose acetate electrospinning solution with a mass fraction of 15%;

[0033] (2) the cellulose acetate electrospinning solution of step (1) is transferred in the electrospinning equipment, under the condition that the static voltage is 20kv, the receiving distance is 15cm, and the advancing speed of the electrospinning solution is 3ml / h Carry out electrospinning, obtain cellulose acetate electrospinning film;

[0034] (3) Place the cellulose acetate electrospun membrane between two 80ml test tubes, and inject 0.01mol / L AgNO into the two test tubes respectively. 3 solution and NaCl solution, placed in the dark for 72 hours to obtain a cellulose acetate electrospun membrane supported AgCl catalyst;

[0035] (4) washing the AgCl catalyst supported on the cellulose acetate electrospun membrane with deionized water, irradiating with sunlight, an...

Embodiment 3

[0038] (1) Weighing cellulose acetate, using acetone and N,N-dimethylacetamide with a mass ratio of 2:1 as a solvent, configured as a cellulose acetate electrospinning solution with a mass fraction of 14%;

[0039] (2) the cellulose acetate electrospinning solution of step (1) is transferred in the electrospinning equipment, under the condition that the static voltage is 18kv, the receiving distance is 12cm, and the advancing speed of the electrospinning solution is 2ml / h Carry out electrospinning, obtain cellulose acetate electrospinning film;

[0040] (3) Place the cellulose acetate electrospun membrane between two 80ml test tubes, and inject 0.02mol / L AgNO into the two test tubes respectively. 3 solution and NaCl solution, placed in the dark for 12 hours to obtain the AgCl catalyst supported on the cellulose acetate electrospun membrane;

[0041] (4) washing the AgCl catalyst supported on the cellulose acetate electrospun membrane with deionized water, irradiating with sun...

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Abstract

The invention belongs to the technical field of catalyst preparation and discloses a cellulose acetate electrostatic-spun film loaded AgCl-Ag catalyst and preparation method and application thereof. The preparation method comprises the steps of preparing cellulose acetate into electrostatic spinning solution by using a solvent, then preparing an electrostatic-spun film in electrostatic spinning equipment, enabling an AgNO3 solution and a NaCl solution to be diffused on the electrostatic-spun film through a double-diffusion method to grow AgCl crystals in situ, and finally obtaining the cellulose acetate electrostatic-spun film loaded AgCl-Ag catalyst through sunlight irradiation. Since the catalyst disclosed by the invention uses cellulose acetate as a substrate, the catalytic efficiency is high, the raw materials are cheap and easy to obtain, and the catalyst is convenient to use and simple to recover and has a good actual application value.

Description

technical field [0001] The invention belongs to the technical field of catalyst preparation, and in particular relates to an AgCl-Ag catalyst loaded on a cellulose acetate electrospun membrane and its preparation and application. Background technique [0002] With the increasing energy problems, how to more effectively and fully utilize green energy such as biomass energy and solar energy to replace traditional petrochemical energy has received widespread attention from the society. [0003] As the most widely existing resource in nature, cellulose is a renewable, green and environmentally friendly natural polymer material. Cellulose acetate, that is, cellulose acetate, was first prepared in 1865. It is an industrialized product with good processing properties and is easy to form film and silk. Cellulose acetate is used in photography as a base for film negatives and also as a rayon. Silver chloride-silver is a semiconductor material. In 2008, Huang et al. used silver chlo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J27/08C02F1/30
Inventor 彭新文周子丹宋美娜钟林新孙润仓
Owner SOUTH CHINA UNIV OF TECH
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