Novel halogen-free flame retardant modification thermoplastic elastomer data line sheath material and manufacturing method thereof

A thermoplastic elastomer, data cable technology, used in plastic/resin/wax insulators, conductors, insulated conductors, etc., can solve the problem that phosphate esters are easy to migrate to the surface of materials, flame retardants are easy to migrate to the surface of materials, and flame retardant TPE products Poor electrical properties and other problems, to achieve the effect of blocking the release of heat and the conduction of combustible gases, good flame retardant synergy, and improving mechanical properties

Inactive Publication Date: 2015-12-02
YJH ELECTRICAL EQUIP
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Problems solved by technology

[0004] At present, most of the halogen-free flame-retardant TPE products on the market use aluminum hydroxide, phosphate composite flame retardant and P-N intumescent flame retardant of ammonium polyphosphate system. Flexibility, mechanical properties are greatly reduced, and hardness is increased; the flame-retardant TPE prepared by the phosphate composite flame retardant has poor fla

Method used

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Examples

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Example Embodiment

[0015] A new type of halogen-free flame-retardant modified thermoplastic elastomer data cable sheath material, made of the following parts by weight (kg) of raw materials: SEBS100, paraffin oil 65, polypropylene 29, polypropylene grafted maleic anhydride 21, anti Oxygen agent B2153, magnesium hydroxide 81, expanded graphite 10.5, silane coupling agent A-1711.6, absolute ethanol 8, stearic acid 2, calcium carbonate 9, silicone masterbatch 2, zinc oxide 1, maleic acid 5. Polyvinyl alcohol 1.5.

[0016] The novel halogen-free flame-retardant modified thermoplastic elastomer data cable sheath material of the present invention is made by the following specific steps:

[0017] (1) Dry the magnesium hydroxide in a blast drying oven at 110°C for 4 hours; add silane coupling agent A-171 to absolute ethanol, stir at 500 rpm for 30 minutes, and then spray it On the dry magnesium hydroxide, then send it to a high-speed mixer, add expanded graphite, stir at room temperature for 30 minutes at a...

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Abstract

The invention discloses a novel halogen-free flame retardant modification thermoplastic elastomer data line sheath material. The novel halogen-free flame retardant modification thermoplastic elastomer data line sheath material is characterized by comprising, by weight, 100-104 parts of SEBS, 65-68 parts of paroline, 29-31 parts of polypropylene, 21-23 parts of maleic anhydride grafted polypropylene, 3-4 parts of antioxygen B215, 81-83 parts of magnesium hydroxide, 10.5-12 parts of expanded graphite, 1.6-1.7 parts of a silane coupling agent A-171, 8-9 parts of absolute ethyl alcohol, 2-3 parts of stearic acid, 9-11 parts of calcium carbonate, 2-3 parts of silicone master batch, 1-1.5 parts of zinc oxide, 5-7 parts of maleic acid and 1.5-2 parts of polyvinyl alcohol. According to the novel halogen-free flame retardant modification thermoplastic elastomer data line sheath material, a blend of the paroline modified SEBS and the polypropylene is used as a matrix, and the composition proportion is scientific and reasonable, so that the obtained product is high in tensile strength, good in thermostability, pliable, tough, good in processing fluidity, remarkable in flame retardant efficiency, free of halogen, environmentally friendly, capable of being widely applied to power lines, data lines and the like.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a novel halogen-free flame-retardant modified thermoplastic elastomer data line sheathing material and a preparation method thereof. Background technique [0002] At present, more than 90% of the electronic wire sheath materials, insulating materials and electronic plug materials widely used in the domestic electronic and electrical industry are made of PVC. However, since July 1, 2006, the European Union has issued a decree to prohibit the entry of electronic and electrical products containing certain harmful substances such as halogen flame retardants and heavy metals into the European market. This has had a serious impact on the export of electronic and electrical products in my country. While the European Union issued its ban, some foreign companies have begun to vigorously promote their products to my country's electrical industry, trying to seize the Chinese marke...

Claims

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Application Information

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IPC IPC(8): C08L53/02C08L91/06C08L23/12C08L51/06C08L29/04C08K13/06C08K9/06C08K3/22C08K7/24C08K3/26C08K5/09H01B3/44H01B7/17
Inventor 储运河
Owner YJH ELECTRICAL EQUIP
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