Processing method for high-purity titanium sheet for coating titanium anode base material

A processing method and technology of titanium anodes, which are applied in the field of processing high-purity titanium sheets for coated titanium anodes, can solve the problems of greatly reduced corrosion resistance, high prices, and increased operating costs of enterprises, and achieve uniform grain size and orientation Effect

Inactive Publication Date: 2015-12-23
LUOYANG SUNRUI TI PRECISION CASTING
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  • Summary
  • Abstract
  • Description
  • Claims
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Problems solved by technology

[0003] The substrate of coated titanium anode is generally pure titanium, and the purity of the material is required to reach at least TA1 standard. If the purity of the substrate used is not enough, the corrosion resistance will be greatly reduced, and the service life of the anode will also be greatly affected. The raw materials used in the anode are expensive, the preparation cost is high, and the service life is generally 1 to 2 years, which increases the operating costs of related enterprises

Method used

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Embodiment Construction

[0017] The invention relates to a processing method of a high-purity titanium thin plate used as a coated titanium anode base material. The high-purity titanium thin plate produced by the processing method has a mass purity of not less than 99.9%, an unevenness of not more than 3mm / m, and an average crystal grain The particle size is 15-30 μm, and the size and orientation of the grains are relatively uniform, which meets the technical requirements of high-end coated titanium anode substrates.

[0018] The processing method of the present invention includes five processes of slab preparation, hot coil preparation, cold coil preparation, annealing, leveler straightening or stretch bending straightening, wherein the slab preparation process uses an electron beam cooling hearth furnace or a VAR furnace The hot coil preparation process uses a steel coil mill or a hot tandem rolling mill, the cold coil preparation process uses a reversible cold rolling mill or a cold tandem rolling m...

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Abstract

Provided is a processing method for a high-purity titanium sheet for a coating titanium anode base material. O-stage sponge titanium with the average particle size being 3-25.4 mm is placed in an electron beam cold hearth and melted in a vacuum state so that a high-purity titanium slab can be obtained through purification; a hot coil which is 2.5-5 mm thick is manufactured through rolling of a steckel mill, and annealing is performed; shot blasting and pickling treatment need to be performed after annealing; the hot coil is placed on a reversible cold rolling machine to be subjected to many times of rolling; finally, a cold coil which is 0.5-2 mm thick can be obtained; the deformation rate is controlled to be 40-60% during each time of rolling; then the cold coil is subjected to degreasing treatment; then complete recrystallization annealing is performed in the vacuum state or the argon protection state, wherein the annealing temperature is controlled to be 600-720 DEG C and a titanium coil is obtained. As is detected, the average grain size of the titanium is controlled to be 15-30 microns, and the high-purity titanium sheet for the coating titanium anode base material is obtained after the titanium coil is straightened. The unevenness of the high-purity titanium sheet is smaller than or equal to 3 mm/m, and no strip-shaped flow direction lines exist after the high-purity titanium sheet is used as a coating.

Description

technical field [0001] The invention belongs to the technical field of processing rare metal materials, and in particular relates to a processing method for a high-purity titanium thin plate for a coated titanium anode. Background technique [0002] Coated titanium anodes are mainly used in two sectors of electrochemistry and electrometallurgy. In the electrochemical process, titanium anode has good corrosion resistance, high catalytic activity, and can maintain the stability of size and shape in the electrolysis process. It has been widely used in electroplating, wastewater treatment, organic electrosynthesis, cathodic protection and Chlor-alkali industry and other fields. [0003] The substrate of coated titanium anode is generally pure titanium, and the purity of the material is required to reach at least TA1 standard. If the purity of the substrate used is not enough, the corrosion resistance will be greatly reduced, and the service life of the anode will also be greatl...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B21C37/02C22F1/18
Inventor 顾新盛刘喜波王树军王卫超
Owner LUOYANG SUNRUI TI PRECISION CASTING
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