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High-abrasion-resistance antistatic shoe sole rubber material and preparation method thereof

A rubber material, anti-static technology, applied in the field of rubber materials, can solve the problems of short life, insufficient wear resistance, no wear resistance, etc., to achieve the effect of improving wear resistance, improving antistatic performance, and high mechanical strength

Inactive Publication Date: 2015-12-23
高山
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Shoes are the necessities of people's life. They can keep warm and protect feet. However, soles are very important for shoes, because they are often in contact with the ground and encounter the greatest friction. The wear resistance of general materials is not enough, and their lifespan is very short. Some use natural rubber. The advantage of natural rubber is that it is very soft, elastic and good, but the disadvantage is that it is not wear-resistant.

Method used

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  • High-abrasion-resistance antistatic shoe sole rubber material and preparation method thereof

Examples

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Effect test

Embodiment 1

[0015] A high wear-resistant and anti-static sole rubber material, which is prepared from the following raw materials in parts by weight (kg): natural rubber 90, styrene-butadiene rubber 12, coumarone resin 8, trishydroxyethylmethyl quaternary ammonium methylsulfuric acid Salt 4, dibutyloctyl phthalate 7, 3-aminopropyltriethoxysilane 4, 2,6-di-tert-butyl p-cresol 5, triisodecyl trimellitate 2, Cocamidopropyl amine oxide 7, nano-ferric oxide 2, organic montmorillonite 20, nano-zirconium carbide 25, high wear-resistant carbon black 20, paraffin oil 5, tetrabutylthiuram disulfide 3, o-toluene 0.2 base thiourea, 1 sulfur, 4 stearic acid, 6 N-phenyl-1-naphthylamine, 10 basic magnesium carbonate, 5 nanometer zinc oxide.

[0016] A preparation method of a high wear-resistant antistatic shoe sole rubber material, comprising the following steps:

[0017] (1) First put natural rubber, styrene-butadiene rubber, and coumarone resin in a drying oven to dry for 10-15 minutes, then add them...

Embodiment 2

[0022] A high wear-resistant and anti-static sole rubber material, which is prepared from the following raw materials in parts by weight (kg): natural rubber 100, styrene-butadiene rubber 14, coumarone resin 10, trishydroxyethylmethyl quaternary ammonium methylsulfuric acid Salt 5, dibutyloctyl phthalate 8, 3-aminopropyltriethoxysilane 5, 2,6-di-tert-butyl p-cresol 6, triisodecyl trimellitate 2.5, Cocamidopropyl amine oxide 8, nano-ferric oxide 3, organic montmorillonite 22.5, nano-zirconium carbide 30, high wear-resistant carbon black 25, paraffin oil 6, tetrabutylthiuram disulfide 3.5, o-toluene 0.3 base thiourea, 1.5 sulfur, 4.5 stearic acid, 8 N-phenyl-1-naphthylamine, 11 basic magnesium carbonate, and 6 nanometer zinc oxide.

[0023] The preparation method is the same as in Example 1.

Embodiment 3

[0025] A high wear-resistant and anti-static shoe sole rubber material, which is prepared from the following raw materials in parts by weight (kg): natural rubber 110, styrene-butadiene rubber 16, coumarone resin 12, trihydroxyethylmethyl quaternary ammonium methylsulfuric acid Salt 6, dibutyloctyl phthalate 9, 3-aminopropyltriethoxysilane 6, 2,6-di-tert-butyl p-cresol 7, triisodecyl trimellitate 3, Cocamidopropyl amine oxide 9, nano-ferric oxide 4, organic montmorillonite 25, nano-zirconium carbide 35, high wear-resistant carbon black 30, paraffin oil 7, tetrabutylthiuram disulfide 4, o-toluene 0.4 base thiourea, 2 sulfur, 5 stearic acid, 10 N-phenyl-1-naphthylamine, 12 basic magnesium carbonate, and 7 nanometer zinc oxide.

[0026] The preparation method is the same as in Example 1.

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Abstract

The invention discloses a high-abrasion-resistance antistatic shoe sole rubber material and a preparation method thereof. The high-abrasion-resistance antistatic shoe sole rubber material is prepared by adopting the following raw materials in part by weight: 90 to 110 parts of natural rubber, 12 to 16 parts of butadiene styrene rubber, 8 to 12 parts of coumarone resin, 4 to 6 parts of tri-hydroxyethyl methyl quaternary ammonium methyl sulfate, 7 to 9 parts of dibutyl octyl phthalate, 4 to 6 parts of 3-aminopropyl triethoxy silane, 5 to 7 parts of 2, 6-tert butyl p-methyl phenol, 2 to 3 parts of benzenetricarboxylic acid triisodecyl ester, 7 to 9 parts of cocamidopropyl dimethylamine oxide, 2 to 4 parts of nano ferroferric oxide, 20 to 25 parts of organic montmorillonite, 25 to 35 parts of nano zirconium carbide, 20 to 30 parts of high-abrasion-resistance carbon black, 5 to 7 parts of paroline, 3 to 4 parts of tetrabutyl thiuram disulfide, 0.2 to 0.4 part of o-tolylthiourea, 1 to 2 parts of sulfur, 4 to 5 parts of stearate, 6 to 10 parts of N-phenyl-1-naphthylamine, 10 to 12 parts of basic magnesium carbonate and 5 t o 7 parts of nano zinc oxide. The high-abrasion-resistance antistatic shoe sole rubber material integrates the advantages of the raw materials such as the natural rubber, butadiene styrene rubber and the like, thereby not only having excellent performance of the butadiene styrene rubber such as aging resistance, heat resistance and abrasion resistance, but also improving the abrasion resistance by adding high-abrasion-resistance carbon black, and the added cocamidopropyl dimethylamine oxide has a good antistatic effect.

Description

technical field [0001] The invention relates to a rubber material, in particular to a high wear-resistant and anti-static shoe sole rubber material and a preparation method thereof. Background technique [0002] Shoes are the necessities of people's life. They can keep warm and protect feet. However, soles are very important for shoes, because they are often in contact with the ground and encounter the greatest friction. The wear resistance of general materials is not enough, and their lifespan is very short. Some use natural rubber. The advantage of natural rubber is that it is very soft, elastic and good, but the disadvantage is that it is not wear-resistant. Due to the insulating properties of polymer materials, when the surface is rubbed, static charges accumulate to form static electricity. When the charge accumulates to a certain amount, it will cause electric shock or even fire. In order to ensure the safety of personal property, anti-static shoes that can remove sta...

Claims

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Application Information

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IPC IPC(8): C08L7/00C08L9/06C08L45/02C08L91/06C08K13/02C08K3/04C08K3/14C08K5/20C08K5/19C08K5/12C08K3/22C08K3/34A43B13/04
Inventor 高山
Owner 高山
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