Desulphurization synergist for wet-method smoke desulphurization system of fire plant

A technology for wet flue gas desulfurization and thermal power plants, which is applied in separation methods, chemical instruments and methods, and separation of dispersed particles. It can solve problems such as acid rain, acid fog, sulfur dioxide emissions, and human carcinogenicity, and accelerate absorption. and conversion process, reducing dosage, and improving the effect of existing ratio

Active Publication Date: 2016-02-03
CNOOC TIANJIN CHEM RES & DESIGN INST +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Sulfur dioxide is extremely harmful to the environment, causing acid rain and acid fog, corrosive to the environment, and carcinogenic to the human body
[0008] However, for the sulfur dioxide limit value after

Method used

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  • Desulphurization synergist for wet-method smoke desulphurization system of fire plant
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  • Desulphurization synergist for wet-method smoke desulphurization system of fire plant

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Experimental program
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Effect test

Embodiment 1

[0027] Embodiment one: a kind of synergist of wet flue gas desulfurization of the present invention, by mass percentage, its composition and content are as follows: sodium dodecanoate 60%, sodium chloride 20%, sodium benzoate 15%, sodium oxide 5% %. The desulfurization synergist can be obtained by mixing sodium dodecanoate, sodium chloride, sodium benzoate and calcium oxide and stirring evenly. Such as figure 1 As shown, under normal operating conditions, when the operating temperature, dosage and intake air concentration are constant, the desulfurization efficiency after using the desulfurization synergist is significantly higher than that of the blank control data without using the chemical agent under the same pH conditions.

Embodiment 2

[0028] Embodiment two: a kind of wet flue gas desulfurization synergist of the present invention, by mass percentage, its composition and content are as follows: sodium octadecanoate 40%, potassium carbonate 40%, sodium terephthalate 15%, tetroxide Tri iron 5%. The desulfurization synergist can be obtained by mixing sodium octadecanoate, sodium carbonate, sodium terephthalate and ferric iron tetroxide and stirring evenly. Such as figure 2 As shown, under normal operating conditions, when the operating temperature, dosage and intake air concentration are constant, the desulfurization efficiency after using the desulfurization synergist is significantly higher than that of the blank control data without using the chemical agent under the same pH conditions.

Embodiment 3

[0029] Embodiment three: a kind of wet flue gas desulfurization synergist of the present invention, by mass percentage, its composition and content are as follows: sodium myristate 50%, potassium oxalate 40%, sodium dodecylbenzene potassium 5%, Iron Tetroxide 5%. The desulfurization synergist can be obtained by mixing sodium myristate, potassium oxalate, sodium dodecyl benzoate and ferric iron tetroxide and stirring evenly. Such as image 3 As shown, under normal operating conditions, when the operating temperature, dosage and intake air concentration are constant, the desulfurization efficiency after using the desulfurization synergist is significantly higher than that of the blank control data without using the chemical agent under the same pH conditions.

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Abstract

The invention discloses a desulphurization synergist for a wet-method smoke desulphurization system used for a fire plant. The desulphurization synergist consists of the following ingredients: an interface active agent, a cosolvent, a pH buffer agent and an oxidation catalyst, wherein the preferable weight percent of each ingredient is as follows: 40 to 60 percent of interface active agent, 20 to 40 percent of cosolvent, 5 to 15 percent of pH buffer agent and 2 to 5 percent of oxidized catalyst. The desulphurization synergist is added into a calcium absorption agent, and the application concentration is 150mg/L to 600mg/L. By adopting the desulphurization synergist, the solubility equilibrium of calcium absorption agent can be promoted to move towards a positive direction, and the solubility of the calcium can be improved; the pH of a gas-liquid interface is stabilized, and the dissolving speed of sulfur dioxide is increased; the oxidation speed is increased, and the generation of gypsum is accelerated; the circulation amount of absorption slurry is reduced, the consumption of the absorption slurry is reduced, an energy-saving and consumption-reducing purpose is achieved, the cost is reduced, and benefit increasing can be achieved.

Description

technical field [0001] The invention relates to an auxiliary agent for improving the efficiency of limestone-gypsum wet desulfurization, in particular to a desulfurization synergist used in a limestone-gypsum wet flue gas desulfurization system of a thermal power plant. Background technique [0002] my country is a large coal producing country, and the energy structure determines that my country's market structure is dominated by thermal power generation. Taking 2014 as an example, my country's coal production reached 3.87 billion tons, nearly half of the world's output; in the same year, my country's thermal power generation was 398 billion kWh, accounting for more than 70% of the country's coal consumption, and it is the main source of air pollution. Among them, the emission of sulfur dioxide in flue gas accounts for more than 90% of the total emission of sulfur dioxide in the country, and the total emission in 2014 reached 19.744 million tons. [0003] Sulfur dioxide is ...

Claims

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Application Information

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IPC IPC(8): B01D53/80B01D53/50
Inventor 王超王昊秦立娟陶蕾
Owner CNOOC TIANJIN CHEM RES & DESIGN INST
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