A kind of plate-type hydrophobic polymer double-effect MVR system and wastewater concentration method

A hydrophobic polymer, plate evaporator technology, applied in the field of water treatment, can solve the problems of high heat loss, poor anti-scaling and anti-corrosion performance of the heat exchange surface, unable to achieve zero discharge of sewage, etc., to reduce the loss of heat transfer temperature difference , the effect of enhancing the heat transfer effect of condensation and reducing the risk of scaling

Active Publication Date: 2017-12-19
TSINGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The current MVR system still has problems such as high energy consumption, poor anti-scaling and anti-corrosion performance of the heat exchange surface, inability to achieve zero sewage discharge, and small water treatment volume. At the same time, the steam compressor has high energy consumption and high cost. for further improvement
For example, the plate evaporators used in the current MVR system mostly use S316L stainless steel as the base material of the heat exchange surface. , usually apply a high polymer coating on the surface of the stainless steel substrate, which increases the risk of coating peeling off

Method used

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  • A kind of plate-type hydrophobic polymer double-effect MVR system and wastewater concentration method
  • A kind of plate-type hydrophobic polymer double-effect MVR system and wastewater concentration method
  • A kind of plate-type hydrophobic polymer double-effect MVR system and wastewater concentration method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0055] Embodiment 1, plate polymer double-effect MVR system

[0056] Such as figure 1 As shown, the double-effect MVR system of the present invention comprises a raw material storage tank (1), a booster, a preheater (3), an adjustable one-effect flow mixer (three-way flow control valve) (4-1) , a first-effect MVR device, a second-effect mixer (4-2), a second-effect MVR device, a concentrated liquid recovery tank (7-2) and a condensate recovery device; the booster device includes a raw material pump (2-1), a first-effect Circulation pump (2-2), inter-effect booster pump (2-3) and second-effect circulation pump (2-4); feed inlet, discharge outlet, condensed water inlet and condensed water outlet are provided on the preheater The one-effect MVR device includes a one-effect MVR evaporator and a centrifugal fan (5-4); the one-effect MVR evaporator is a reactor, which is separated into a one-effect evaporation unit (5-3) by a plug-in detachable plate evaporator And a one-effect co...

Embodiment 2

[0064] Embodiment 2, the control of total dissolved solid content of feed liquid

[0065] When the double-effect MVR system in Example 1 is used to concentrate the feed liquid, the BPE value of the feed liquid, that is, the boiling point elevation value, is in the range of 0-2.1°C. According to the law of solution boiling point rise (the inference of Raoult's law, the calculation formula

[0066]

[0067] Among them, ΔT is the boiling point liter, K; R is the gas constant, for water vapor, R is 0.462kJ / (kg K); T 0 is the boiling point temperature of pure solvent, K; γ 0 For pure solvent at T 0 molar latent heat of vaporization, kJ / kg; is the mole fraction increment of the solute in the dilute solution.

[0068] Since the calculation here is the boiling point liter relative to the pure solution, it can be regarded as adding a solute to a pure solvent with a concentration of 0, that is, the mole fraction increase of the solute and the mole fraction of solute (x 2 ) ar...

Embodiment 3

[0073] Example 3, the relationship between the power of the one-effect circulation pump and the temperature rise of the solution in the one-effect evaporation unit

[0074] Take the NaCl solution with a solute mass fraction of 5% as an example, as Figure 6 As shown, the power consumption of the one-effect circulating pump (2-2) decreases as the temperature rise of the solution in the one-effect evaporation unit (5-3) increases, because the higher the temperature rise, the less the amount of circulating solution required; At the same time, when the temperature rises 1.5-2.5°C, the pump power drops more obviously, so the more suitable temperature rise range should be 2.5-5.5°C; image 3 It can also be seen that the evaporation temperature of the solution in the first-effect evaporation unit (5-3) (the evaporation temperatures of the three curves in the figure are 50°C, 60°C and 70°C respectively) has no obvious influence on the pump power.

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Abstract

The invention discloses a plate-type hydrophobic polymer double-effect MVR system. The first-effect MVR evaporator and the second-effect MVR evaporator in the double-effect MVR system are both reactors, which are divided into one-effect evaporation unit and one-effect condensation unit by the plate evaporator, and the plates in the plate evaporator are hydrophobic polymerization physical film. The thickness of the hydrophobic polymer film is 15-60 μm; the contact angle is 110°-150°, the water absorption rate is 0.0042%-0.41%, the thermal expansion coefficient is 44.1-100 μm / (m·℃) at 20°C, and the thermal expansion coefficient at 100°C The temperature is 39.2-140μm / (m·℃), the melting point is 330-340℃, the glass transition temperature is 140-220℃, and the thermal conductivity is 0.2-0.35W / (m·K). The polymer film is used as the base material of the heat exchange surface, and more heat exchange surfaces can be placed in a limited volume. The thermal resistance generated by the polymer film under this film thickness is only equivalent to that of 0.75-1.5mm 316L stainless steel, which can Realize low-temperature differential heat exchange at 2-3°C, reduce heat supplementation, and reduce the weight of the MVR device. At the same time, the existence of flexible groups such as C-N bonds in the polymer film can cause a thermal expansion rate ten times that of stainless steel, which can accelerate the scale layer. The falling off reduces the loss of heat transfer temperature difference.

Description

technical field [0001] The invention relates to a plate-type hydrophobic polymer double-effect MVR system and a wastewater concentration method, belonging to the technical field of water treatment. Background technique [0002] MVR is the abbreviation of Mechanical Vapor Recompression technology (Mechanical Vapor Recompression). The basic principle is to compress the steam evaporated from the evaporation unit and increase the heat enthalpy, and reuse it as a heat source. The advantage of adopting MVR technology is: one effect of evaporation in the MVR system is equivalent to 20 to 30 effects in multi-effect evaporation, and the economy is good, and the operating cost is only about 30% of the traditional multi-effect evaporator; no external steam is needed, and the stand-alone is independent Good performance; using low-temperature evaporation technology, the evaporation temperature is 55-60°C, which is more than 10°C lower than the top temperature of the low-temperature multi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F1/04
Inventor 吴晓敏朱毅褚福强
Owner TSINGHUA UNIV
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