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Permeable steel bar corrosion inhibitor for durability repair of concrete structure and preparation method thereof

A rust inhibitor technology for concrete structures and steel bars, applied in the field of building materials, can solve the problems of penetration of harmful substances, prone to cracks, corrosion, etc., and achieves the effects of simple preparation process and convenient operation.

Active Publication Date: 2016-03-02
YANTAI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In recent years, the rapid development and application of high-performance concrete has alleviated the durability of concrete to a certain extent. However, due to the characteristics of concrete materials and the complexity of engineering, coupled with the low water-binder ratio of high-performance concrete, cracks are likely to occur if improper maintenance. Cracks will inevitably accelerate the penetration of harmful substances in the environment into the structure, causing the steel bars in the structure to be corroded to varying degrees, reducing the durability and service life of the concrete structure
Years of engineering practice have also shown that only relying on the use of high-performance concrete cannot completely solve the durability of concrete structures in harsh environments
[0003] In order to prevent the corrosion of steel bars in concrete structures in harsh environments such as chloride salts, a relatively simple and effective method has been to add inorganic steel bar rust inhibitors to concrete for a long time. For the corrosion protection and repair of steel bars in existing concrete structures, Incorporated rust inhibitors cannot be applied
The traditional rust inhibitor for steel bars is mainly nitrite. Since nitrite is an anodic rust inhibitor and is carcinogenic, low content will cause accelerated local corrosion of steel bars. The use of this type of steel bar rust inhibitor has been clearly banned in some European countries

Method used

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  • Permeable steel bar corrosion inhibitor for durability repair of concrete structure and preparation method thereof
  • Permeable steel bar corrosion inhibitor for durability repair of concrete structure and preparation method thereof
  • Permeable steel bar corrosion inhibitor for durability repair of concrete structure and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0017] Weigh by weight: 10g oleic acid amine, 10g cyclohexylamine, 15g phytic acid, 5g sarcosine, 5g pentaerythritol ester, 10g lauric acid ester, 45g isomeric alcohol ether phosphate, first oleic acid amine, cyclohexylamine , phytic acid, and sarcosine were stirred and mixed at a temperature of 67°C; after the mixture was evenly mixed, slowly added pentaerythritol ester and laurate; Stir while adding until the mixed liquid turns from cloudy to clear.

Embodiment 2

[0019] Weigh by weight: 10g dimethylethanolamine, 5g oleic acid amine, 10g cyclohexylamine, 5g benzoic acid, 10g succinic acid, 5g lauric acid, 5g N-lauroyl sodium glutamate, 5g sorbitol ester, 5g monohard Fatty acid glyceride, 40g isooctyl phosphate, first stir and mix dimethylethanolamine, oleic acid amine, cyclohexylamine, benzoic acid, succinic acid, and lauric acid at a temperature of 65°C; Slowly add sodium N-lauroyl glutamate, sorbitol ester, and glyceryl monostearate into the mixture; after stirring evenly, slowly add isooctyl phosphate, and stir while adding until the mixed liquid changes from turbid to until clear.

Embodiment 3

[0021] Weigh by weight: 15g monomethylethanolamine, 5g oleic acid amine, 10g cyclohexylamine, 15g benzoic acid, 5g potassium N-lauroyl glycinate, 5g pentaerythritol ester, 5g glyceryl monostearate, 20g isooctyl phosphate , 20g of isomeric alcohol ether phosphate, first stir and mix monomethylethanolamine, oleic acid amine, cyclohexylamine, and benzoic acid at a temperature of 60°C; after the mixture is evenly mixed, slowly add N-lauroyl glycine to the mixture Potassium, pentaerythritol ester, glyceryl monostearate; after stirring evenly, slowly add isooctyl phosphate and isomeric alcohol ether phosphate, and stir while adding until the mixed liquid changes from cloudy to clear.

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Abstract

The invention relates to a permeable organic corrosion inhibitor for durability repair of concrete structure, and belongs to the field of building materials. The permeable organic corrosion inhibitor comprises the following components: 40-60% of an organic corrosion inhibitor, 5-15% of a surfactant and 30-45% of an alkali resistant penetrant. The surfactant is selected from an amino acid surfactant or an aliphatic ester surfactant; and the alkali resistant penetrant is a mixture composed of one or more of isooctanol phosphate, heterogeneous polyoxyethylene aliphatic alcohol phosphate and fatty alcohol-polyoxyethylene ether in arbitrary proportion. The preparation method is as below: mixing the surfactant with the organic corrosion inhibitor; stirring while heating; and after full fusion of the mixture, adding an organic osmotic agent with stirring until the mixed liquid turns from turbid to clear state to obtain the product. The preparation method of the invention is simple; the obtained product can be used in surface treatment or reinforcement of concrete structure in work, has excellent penetration ability and corrosion resistance effect, and can effectively prevent or delay corrosion of steel bar in concrete structure by the chloride salts, and does not have adverse effect on the performance of concrete.

Description

technical field [0001] The invention relates to a permeable steel bar rust inhibitor for durable repair of concrete structures and a preparation method thereof, belonging to the technical field of building materials. Background technique [0002] The steel bars in the concrete structure in the marine environment and deicing salt environment are easily corroded by chloride salts, which greatly reduces the durability and service life of the concrete structure. Therefore, how to prevent the corrosion of steel bars in concrete structures or repair the damaged steel bars in concrete structures that have suffered from chloride corrosion has become the key to maintaining and improving the durability of concrete structures in harsh environments. In recent years, the rapid development and application of high-performance concrete has alleviated the durability of concrete to a certain extent. However, due to the characteristics of concrete materials and the complexity of engineering, c...

Claims

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Application Information

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IPC IPC(8): C04B24/12
Inventor 刘志勇王子潇郑铎周继元杨金良
Owner YANTAI UNIV