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Mildew-resistant PVC modified material and preparation method therefor

A technology of modified material and PVC resin, which is applied in the field of mildew-resistant PVC modified material and its preparation, which can solve the problems of poor thermal stability, poor mildew-proof performance, and poor fluidity, and achieve excellent processing performance, temperature resistance and weather resistance. , good compatibility effect

Inactive Publication Date: 2016-03-23
广东祺龙科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Polyvinyl chloride (PVC) is one of the earliest industrialized and widely used general-purpose thermoplastics. It has light weight, high strength, insulation, flame retardancy, corrosion resistance, It has the advantages of excellent comprehensive performance, low price and wide source of raw materials; but it also has the following disadvantages: 1. Poor toughness, easy to be brittle when impacted, so it cannot be used as a structural material. In addition, the brittleness of polyvinyl chloride is greatly affected by temperature. Large, the lower limit of general PVC products is -15°C, and the lower limit of soft PVC is -30°C; 2. Poor thermal stability, it begins to decompose HCl at 100°C, and decomposes more rapidly when it is higher than 150°C. The melting temperature of PVC is about 210°C; 3. The viscosity of PVC is extremely high and its fluidity is extremely poor, which limits its use to a certain extent.
[0005] The above-mentioned existing PVC materials have poor anti-mold properties and cannot reliably meet the needs of long-term use under humid conditions. Therefore, it is particularly necessary to develop a anti-mold PVC material.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0055] A kind of mildew-resistant PVC modified material, described mildew-proof PVC modified material comprises the raw material of following weight portion:

[0056] 80 parts of PVC resin

[0057] 50 parts of plasticizer

[0058] Filling agent 20 parts

[0059] 3 parts heat stabilizer

[0060] 1 part anti-fungal agent

[0061] Synergist 0.6 parts

[0062] 0.2 parts of lubricant.

[0063] The PVC resin is a mixture of calcium carbide-based PVC resin and ethylene-based PVC resin in a weight ratio of 2:1.

[0064] The plasticizer is a mixture composed of diisononyl cyclohexane 1,2-dicarboxylate, triethyl citrate and epoxidized soybean oil in a weight ratio of 1.5:0.8:1.

[0065] The filler is a mixture of heavy calcium carbonate and light calcium carbonate at a weight ratio of 0.8:1.

[0066] The heat stabilizer is a mixture of calcium-zinc composite heat stabilizer and hydrotalcite heat stabilizer at a weight ratio of 0.8:1; the calcium-zinc composite heat stabilizer is ...

Embodiment 2

[0077] A kind of mildew-resistant PVC modified material, described mildew-proof PVC modified material comprises the raw material of following weight portion:

[0078] PVC resin 90 parts

[0079] 55 parts of plasticizer

[0080] Filler 22 parts

[0081] 4 parts heat stabilizer

[0082] Antifungal agent 1.5 parts

[0083] Synergist 0.7 parts

[0084] 0.3 parts of lubricant.

[0085] The PVC resin is a mixture of calcium carbide-based PVC resin and ethylene-based PVC resin at a weight ratio of 2.5:1.

[0086] The plasticizer is a mixture composed of diisononyl cyclohexane 1,2-dicarboxylate, triethyl citrate and epoxidized soybean oil in a weight ratio of 1.8:0.9:1.

[0087] The filler is a mixture of heavy calcium carbonate and light calcium carbonate at a weight ratio of 0.9:1.

[0088] The heat stabilizer is a mixture of calcium-zinc composite heat stabilizer and hydrotalcite heat stabilizer at a weight ratio of 0.9:1; the calcium-zinc composite heat stabilizer is compos...

Embodiment 3

[0099] A kind of mildew-resistant PVC modified material, described mildew-proof PVC modified material comprises the raw material of following weight portion:

[0100] PVC resin 100 parts

[0101] 60 parts of plasticizer

[0102] Filling agent 25 parts

[0103] Heat stabilizer 5 parts

[0104] 2 parts anti-fungal agent

[0105] Synergist 0.8 parts

[0106] 0.4 parts of lubricant.

[0107] The PVC resin is a mixture of calcium carbide-based PVC resin and ethylene-based PVC resin in a weight ratio of 3:1.

[0108] The plasticizer is a mixture composed of diisononyl cyclohexane 1,2-dicarboxylate, triethyl citrate and epoxidized soybean oil in a weight ratio of 2:1:1.

[0109] The filler is a mixture of heavy calcium carbonate and light calcium carbonate at a weight ratio of 1:1.

[0110] The heat stabilizer is a mixture of a calcium-zinc composite heat stabilizer and a hydrotalcite heat stabilizer at a weight ratio of 1:1; the calcium-zinc composite heat stabilizer is compose...

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Abstract

The invention relates to the PVC material technology field, and concretely relates to a mildew-resistant PVC modified material and a preparation method therefor. The mildew-resistant PVC modified material comprises the following raw materials, by weight, 80-120 parts of PVC resin, 50-70 parts of plasticizer, 20-30 parts of filler, 3-7 parts of heat stabilizer, 1-3 parts of mildew inhibitor, 0.6-1.0 part of synergistic agent and 0.2-0.6 part of lubricant. The above raw materials are employed, the weight ratios of the raw materials are controlled strictly, various performances of the prepared mildew-resistant PVC modified material exceed national standards, and the provided modified material is advantaged by good mildew-resistant effects, environmental protection, excellent temperature resistance, excellent weather resistance, high intensity, excellent shock resistance, good flame retardation effects, excellent processing property and excellent comprehensive properties.

Description

technical field [0001] The invention relates to the technical field of PVC materials, in particular to a mildew-resistant PVC modified material and a preparation method thereof. Background technique [0002] Polyvinyl chloride (PVC) is one of the earliest industrialized and widely used general-purpose thermoplastics. It has the advantages of light weight, high strength, insulation, flame retardancy, corrosion resistance, excellent comprehensive performance, low price and wide source of raw materials; but also There are the following disadvantages: 1. The toughness is poor, and it is easy to be brittle when impacted, so it cannot be used as a structural material. In addition, the brittleness of polyvinyl chloride is greatly affected by temperature. The lower limit of general PVC products is -15°C. The lower limit of use of PVC is -30°C; 2. Poor thermal stability, it begins to decompose HCl at 100°C, and decomposes more rapidly when it is higher than 150°C, and the melting tem...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/06C08L91/00C08L23/06C08L23/28C08L23/08C08K13/02C08K3/26C08K5/544C08K5/156B29C47/92B29C48/92
CPCC08L27/06B29C48/92B29C2948/92704C08K2201/003C08K2201/014C08L2201/02C08L2201/08C08L2205/025C08L2205/035C08L91/00C08L23/06C08L23/286C08L23/0853C08K13/02C08K2003/265C08K5/5435C08K5/156
Inventor 宁建华
Owner 广东祺龙科技有限公司
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