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Lithium ion battery

A lithium-ion battery and electrolyte technology, applied in battery electrodes, secondary batteries, circuits, etc., can solve the problems of poor safety performance, poor rate performance and cycle performance of lithium iron manganese phosphate, and low discharge voltage platform, and achieve improvement. Safety performance, improving cycle performance and energy density, and realizing the effect of cycle performance

Active Publication Date: 2016-03-30
OPTIMUM BATTERY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the tap density and compaction density of lithium iron phosphate are low, and the discharge voltage platform is low (about 3.2V), which makes the energy density of lithium iron phosphate battery low. At present, the highest energy density of cylindrical 32650 type lithium iron phosphate battery is about 120Wh / Kg, which is difficult to meet the increasingly stringent requirements of new energy vehicles for cruising range
The advantage of ternary batteries applied to new energy vehicles lies in their high energy density (≥150Wh / Kg), but their safety performance is poor, and it is difficult to pass the acupuncture test, which requires a relatively complete battery management system to control
The advantages of lithium manganese iron phosphate batteries are good safety and high working voltage, but the rate performance and cycle performance of lithium manganese iron phosphate are poor
Therefore, there is still a lack of a lithium-ion battery with high safety performance, long cycle performance and high energy density in the art.

Method used

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Examples

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Embodiment 1

[0031] The battery model used is 32650 with a capacity of 5.6Ah and an energy density of 135Wh / Kg. The positive electrode uses a ternary material (LiNi 0.5 mn 0.3 co 0.2 o 2 ) and lithium manganese iron phosphate materials are mixed in a mass ratio of 50:50, the conductive agent is Super-P (conductive carbon black) and KS-6 (conductive graphite), and the binder is polyvinylidene fluoride. The negative electrode uses artificial graphite, the diaphragm adopts polyethylene double-sided ceramic diaphragm (12+2+2), and the assembled battery number is A.

Embodiment 2

[0033] The model of the battery used in this embodiment is 32650, the capacity is 5.7Ah, and the energy density is 135Wh / Kg. The positive electrode uses lithium iron phosphate, ternary material (LiNi 0.5 mn 0.3 co 0.2 o 2) and lithium manganese iron phosphate materials are mixed in a mass ratio of 40:27:33, the conductive agent is Super-P and KS-6, and the adhesive is polyvinylidene fluoride. The negative electrode uses artificial graphite, the diaphragm adopts polyethylene double-sided ceramic diaphragm (12+2+2), and the assembled battery number is B.

Embodiment 3

[0035] The model of the battery used in this embodiment is 32650, the capacity is 5.7Ah, and the energy density is 135Wh / Kg. The positive electrode uses lithium iron phosphate, ternary material (LiNi 0.5 mn 0.3 co 0.2 o 2 ) and lithium manganese iron phosphate material are mixed in a ratio of 40:27:33, the conductive agent is carbon nanotube CNTs, and the binder is polyvinylidene fluoride. The negative electrode uses artificial graphite, the diaphragm adopts polyethylene double-sided ceramic diaphragm (12+2+2), and the assembled battery number is C.

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Abstract

The invention is applicable to the field of lithium ion batteries, and provides a lithium ion battery comprising a cathode plate, an anode plate, a membrane and electrolyte, wherein the surface of the cathode plate is coated with cathode slurry including cathode active materials including lithium iron phosphate, ternary material and lithium manganese ferric phosphate; the ternary material is represented by the formula of LiNixCOyMn1-x-yO2, wherein x is less than 1 and more than 0, y is less than 1 and more than 0, and the sum of x and y is less than 1 and more than 0. The mass ratio of the lithium iron phosphate, ternary material and lithium manganese ferric phosphate is (10-60):(10-50):(10-50). The cathode slurry also includes conductive agents which are carbon nanotubes. The lithium ion battery provided by the invention is significantly improved in cycle performance, energy density and safety performance.

Description

technical field [0001] The invention belongs to the field of lithium ion batteries, and in particular relates to a lithium ion battery. Background technique [0002] With the continuous consumption and depletion of traditional fossil fuel energy, countries all over the world are trying their best to find new alternative energy sources. Lithium-ion batteries have become a research hotspot because of their advantages such as long cycle life, high energy density, no memory effect, and environmental protection. . In recent years, with the promotion and support of new energy industries around the world, new energy vehicles have ushered in a period of rapid development, and lithium-ion batteries have become an important energy supply for new energy batteries. [0003] At present, lithium-ion batteries used in the field of new energy vehicles mainly include lithium iron phosphate batteries, ternary batteries and lithium manganese iron phosphate batteries. Lithium iron phosphate h...

Claims

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Application Information

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IPC IPC(8): H01M10/0525H01M4/36H01M4/58H01M4/505H01M4/525
CPCH01M4/364H01M4/505H01M4/525H01M4/58H01M10/0525Y02E60/10
Inventor 刘熙林钱龙许辉黎明旭
Owner OPTIMUM BATTERY CO LTD
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