A kind of preparation method of fluorescent spandex material
A spandex and fluorescent technology, applied in rayon manufacturing, fiber chemical characteristics, fiber type, etc., can solve problems such as agglomeration, and achieve the effect of increasing the degree of bonding, convenient regeneration and strong fluorescent activity
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[0028] (1) Preparation of intermediate monomers
[0029] Add 2 mol of 6-hydroxy-2-naphthoic acid and 2.4 mol of catalyst triethylamine into 80 ml of dichloromethane solvent, stir evenly in an ice bath, then add 2.8 mol of acryloyl chloride dropwise to the solvent for 2 hours Completed, after 15 hours of reaction in ice bath, wash with dilute hydrochloric acid with a solute mass fraction of 20%, then deionized water, dry over anhydrous magnesium sulfate, and spin evaporate to obtain the reaction product, which is the naphthalene containing double bond Formic acid monomer, the intermediate monomer required by the present invention,
[0030] The approximate reaction equation of above-mentioned steps (1) is
[0031]
[0032] (2) Preparation of photoinitiator-loaded spandex
[0033] A. In the prepolymerization tank, first add DMAC and PTMG (polytetramethylene ether glycol, molecular weight 1500), and then add 4,4-MDI (4,4- Diphenylmethane diisocyanate), warming up to 50°C, pr...
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