Emulsion leaking stopping agent and preparing method thereof

A plugging agent and emulsion technology, which is applied in the field of emulsion plugging agent and its preparation, can solve the problems of difficult plugging agent, single plugging material and method, and repeated leakage, so as to increase the success rate of plugging and improve retention effect of ability

Active Publication Date: 2016-05-11
CHINA PETROLEUM & CHEM CORP +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

During the entire period before the 1970s, high-viscosity drilling fluid plus bridge plugging materials (sawdust, mica, straw, mud balls, bricks, etc.) and cement plugs were mainly used. The plugging materials and methods were single, often resulting in Failure of lost circulation treatment
However, in the case of severe lost circulation, the composite lost circulation ag

Method used

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  • Emulsion leaking stopping agent and preparing method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Add 12.50g of acrylamide as the first monomer, 10.00g of acryloyloxyethyl dimethyl benzyl ammonium chloride as the second monomer, 2.25g of butyl acrylate as the third monomer, and 2.25g of butyl acrylate as the fourth monomer 0.25g of N,N-methylenebisacrylamide and 200.00g of distilled water, mechanically stirred to form a turbid liquid; add 400.00g of synthetic base oil to the turbid liquid, and continue to add 1.00g of tetramethylammonium bromide , 0.75g of nonylphenol polyoxyethylene ether; cooling to 2°C in an ice-water bath, adding 0.0013g of sodium persulfate and 0.0013g of sodium bisulfite; passing inert gas nitrogen into the aqueous solution and keeping it for 60 minutes; under nitrogen atmosphere, Raise the temperature to 10° C., stir and react for 10 hours to obtain an emulsion sample.

Embodiment 2

[0023] Add 95.0g of acrylamide as the first monomer, 1.00g of methacryloxyethyltrimethylammonium chloride as the second monomer, 2.00g of vinyl acetate as the third monomer, and 2.00g of vinyl acetate as the fourth monomer in a 1000mL four-necked bottle. 0.010g of N,N-methylenebisacrylamide and 150.00g of distilled water, mechanically stirred to form a turbid liquid; add 300.00g of synthetic base oil to the turbid liquid, and continue to add 3.92g of tetramethylammonium bromide , 2.94g of nonylphenol polyoxyethylene ether; cooling to 2°C in an ice-water bath, adding 0.025g of sodium persulfate and 0.025g of sodium bisulfite; passing inert gas nitrogen into the aqueous solution and keeping it for 60 minutes; under nitrogen atmosphere, Raise the temperature to 30° C., stir and react for 10 hours to obtain an emulsion sample.

Embodiment 3

[0025] In a 1000mL four-necked bottle, add 50.00g of sodium acrylate to the first monomer, 29.80g of methacryloyloxyethyl dimethyl benzyl ammonium chloride to the second monomer, and 20.00g of hydroxypropyl methacrylate to the third monomer , the fourth monomer diacetone acrylamide 0.20g and distilled water 300.00g, and continue to add tetramethylammonium bromide 4.00g, nonylphenol polyoxyethylene ether 3.00g; ice-water bath cooling to 2 ° C, add persulfuric acid Sodium 0.016g, sodium bisulfite 0.016g; inert gas nitrogen was passed into the aqueous solution and kept for 60 minutes; under nitrogen atmosphere, the temperature was raised to 80°C, and the emulsion sample was obtained after stirring and reacting for 8 hours.

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Abstract

The invention relates to an emulsion leaking stopping agent in oil-and-gas-field well-drilling leaking stopping operation and a preparing method thereof, in particular to a gel-expansion leaking stopping agent with molecules containing functional groups capable of enhancing the interaction with the stratum. The leaking stopping agent is prepared from four monomers in a copolymerized mode; the first monomer supplies hydrophilia to the leaking stopping agent and promotes water expansion of materials; the second monomer is a cationic monomer, supplies groups with positive charges and improves attraction between the charges of the leaking stopping agent and charges of the leakage hole way well wall; the third monomer is a un-saturation organosilicone-coupling-agent monomer and can improve the retention capability of the leaking stopping agent in a leakage layer; the fourth monomer is a polyunsaturated bond functional monomer and enables the leaking stopping agent to form chemical crosslinking. According to the emulsion leaking stopping agent, aqueous solution polymerization is adopted, the technology is simple, and operation is convenient. The prepared leaking stopping agent has the advantages that water expansion capacity is high; as the leaking stopping agent contains the multiple functional groups capable of mechanically interacting with the leakage layer, the retention capability of the leaking stopping materials in the leakage layer can be improved.

Description

technical field [0001] The invention relates to an emulsion plugging agent in oil and gas field drilling plugging operations and a preparation method thereof, in particular to an emulsion plugging agent capable of cementing formations. Background technique [0002] Lost circulation is a complex problem in drilling operations. It causes drilling fluid to leak from the wellbore into the lost channel, which not only consumes a lot of mud and plugging materials, but also may cause well collapse, pipe sticking, blowout, and even lead to the scrapping of the wellbore, etc. Major accidents cause huge economic losses. Plugging material is an essential substance in the process of drilling leak prevention and plugging, and its performance directly affects the success rate of plugging construction. [0003] In the 1960s, the country began to apply the plugging material to deal with lost circulation, and carried out some basic research work. During the entire period before the 1970s, ...

Claims

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Application Information

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IPC IPC(8): C09K8/44C08F220/56C08F220/06C08F220/34C08F220/18C08F222/38C08F218/08C08F220/28C08F220/58C08F4/40
Inventor 朱魁袁俊秀周成华庞雨微逯贵广封心领胡德云杨国兴张珍王权阳李尧
Owner CHINA PETROLEUM & CHEM CORP
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