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A kind of preparation method of water-repellent and oil-repellent superfine fiber synthetic leather

A water-repellent, oil-repellent, ultra-fine fiber technology, applied in the direction of layered products, textiles, and papermaking, can solve the problems of poor air permeability, poor rebound effect, and poor mechanical properties of leather, and achieve good water and repellency. Good oil effect, good mechanical properties, and good rebound effect

Active Publication Date: 2017-09-05
福建新隆上超纤有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Therefore, in view of the above content, the present invention provides a method for preparing water and oil repellent microfiber synthetic leather, which solves the problem of poor air permeability, poor rebound effect and mechanical properties of leather with water and oil repellency in the prior art. bad question

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] A method for preparing water-repellent and oil-repellent superfine fiber synthetic leather, comprising the following processing steps:

[0021] (1) Preparation of pretreatment agent: 25 parts by weight of fluorine-containing copolymer, 10 parts by weight of surfactant, 0.1 part by weight of dodecyl mercaptan, 1 part by weight of diacetone acrylamide coupling agent, and 100 parts by weight of deionized water 10 parts by weight are mixed evenly to obtain the pretreatment agent; the preparation method of fluorine-containing copolymer is to mix 15 parts by weight of trifluoroethyl acrylate, 5 parts by weight of propylene chloride, 6 parts by weight of acrylic acid, and 100 parts by weight of distilled water, and then add anhydrous 5 parts by weight of sodium sulfate and 3 parts by weight of ammonium persulfate, adjust the pH to make pH = 7.0, and continue stirring and reacting for 4 hours in the temperature range of 55°C to obtain a fluorine-containing copolymer; the surfact...

Embodiment 2

[0027] A method for preparing water-repellent and oil-repellent superfine fiber synthetic leather, comprising the following processing steps:

[0028] (1) Preparation of pretreatment agent: 28 parts by weight of fluorine-containing copolymer, 12 parts by weight of surfactant, 0.15 parts by weight of dodecyl mercaptan, 2 parts by weight of diacetone acrylamide coupling agent, and 100 parts by weight of deionized water 1,000 parts are mixed evenly to prepare the pretreatment agent; the preparation method of the fluorine-containing copolymer is to mix 17 parts by weight of trifluoroethyl acrylate, 8 parts by weight of propylene chloride, 7 parts by weight of acrylic acid, and 100 parts by weight of distilled water, and then add anhydrous 6 parts by weight of sodium sulfate and 4 parts by weight of ammonium persulfate were used to adjust the pH to 7.2, and the reaction was continued under stirring for 5 hours at a temperature of 56° C. to obtain a fluorine-containing copolymer. Su...

Embodiment 3

[0034] A method for preparing water-repellent and oil-repellent superfine fiber synthetic leather, comprising the following processing steps:

[0035] (1) Preparation of pretreatment agent: 30 parts by weight of fluorine-containing copolymer, 15 parts by weight of surfactant, 0.2 parts by weight of dodecyl mercaptan, 3 parts by weight of diacetone acrylamide coupling agent, and 100 parts by weight of deionized water 2 parts by weight are mixed evenly to obtain a pretreatment agent; the preparation method of fluorine-containing copolymer is to mix 20 parts by weight of trifluoroethyl acrylate, 10 parts by weight of propylene chloride, 8 parts by weight of acrylic acid, and 100 parts by weight of distilled water, and then add anhydrous 7 parts by weight of sodium sulfate and 5 parts by weight of ammonium persulfate were used to adjust the pH to 7.5, and the mixture was stirred and reacted for 6 hours at a temperature of 58° C. to obtain a fluorine-containing copolymer. Surfactan...

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PUM

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Abstract

The invention relates to the technical field of preparation of leathers, provides a preparation method of water-repellent oil-repellent superfine fiber synthetic leather and solves the problem that the prior art leather with water and oil repellency has poor breathability, poor elasticity and poor mechanical properties. The preparation method comprises the following treatment steps: (1), preparing a pretreating agent; (2), spraying the pretreating agent obtained in step (1) to the surface of superfine fiber synthetic fiber, and standing for reacting and adsorbing; (3), preparing a water-repellent oil-repellent finishing agent which comprises the materials, according to following parts by weight, 20-30 parts of silicon dioxide, 10-15 parts of gelatin, 20-25 parts of nano rubber micro-powder, and 20-30 parts of acrylic emulsion; (4), soaking the superfine fiber synthetic leather treated in step (2) into the water-repellent oil-repellent finishing agent of step (3) for 60-75 min; (5), drying: drying a product obtained in step (4) by using plasma gas.

Description

technical field [0001] The invention relates to the technical field of leather preparation, in particular to a method for preparing water and oil repellent superfine fiber synthetic leather. Background technique [0002] With the increasing application fields of polyurethane microfiber synthetic leather (referred to as microfiber leather), the requirements for its water-repellent, oil-repellent and anti-fouling functions are also becoming stronger and stronger. Whether the material has the function of water repellency, oil repellency and antifouling is whether water or oil can wet the surface of the solid, and there are two ways to judge whether the water or oil can wet the solid surface: one is by comparing the surface of the solid Critical surface tension and interfacial tension between water or oil and solid. When the critical surface tension of solid surface is less than the surface tension between water or oil and solid, water or oil cannot wet the surface of the solid,...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06N3/08B32B33/00
CPCB32B33/00D06N3/08
Inventor 张树仁孙卫东
Owner 福建新隆上超纤有限公司
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