A kind of preparation method of water-repellent and oil-repellent superfine fiber synthetic leather
A water-repellent, oil-repellent, ultra-fine fiber technology, applied in the direction of layered products, textiles, and papermaking, can solve the problems of poor air permeability, poor rebound effect, and poor mechanical properties of leather, and achieve good water and repellency. Good oil effect, good mechanical properties, and good rebound effect
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Embodiment 1
[0020] A method for preparing water-repellent and oil-repellent superfine fiber synthetic leather, comprising the following processing steps:
[0021] (1) Preparation of pretreatment agent: 25 parts by weight of fluorine-containing copolymer, 10 parts by weight of surfactant, 0.1 part by weight of dodecyl mercaptan, 1 part by weight of diacetone acrylamide coupling agent, and 100 parts by weight of deionized water 10 parts by weight are mixed evenly to obtain the pretreatment agent; the preparation method of fluorine-containing copolymer is to mix 15 parts by weight of trifluoroethyl acrylate, 5 parts by weight of propylene chloride, 6 parts by weight of acrylic acid, and 100 parts by weight of distilled water, and then add anhydrous 5 parts by weight of sodium sulfate and 3 parts by weight of ammonium persulfate, adjust the pH to make pH = 7.0, and continue stirring and reacting for 4 hours in the temperature range of 55°C to obtain a fluorine-containing copolymer; the surfact...
Embodiment 2
[0027] A method for preparing water-repellent and oil-repellent superfine fiber synthetic leather, comprising the following processing steps:
[0028] (1) Preparation of pretreatment agent: 28 parts by weight of fluorine-containing copolymer, 12 parts by weight of surfactant, 0.15 parts by weight of dodecyl mercaptan, 2 parts by weight of diacetone acrylamide coupling agent, and 100 parts by weight of deionized water 1,000 parts are mixed evenly to prepare the pretreatment agent; the preparation method of the fluorine-containing copolymer is to mix 17 parts by weight of trifluoroethyl acrylate, 8 parts by weight of propylene chloride, 7 parts by weight of acrylic acid, and 100 parts by weight of distilled water, and then add anhydrous 6 parts by weight of sodium sulfate and 4 parts by weight of ammonium persulfate were used to adjust the pH to 7.2, and the reaction was continued under stirring for 5 hours at a temperature of 56° C. to obtain a fluorine-containing copolymer. Su...
Embodiment 3
[0034] A method for preparing water-repellent and oil-repellent superfine fiber synthetic leather, comprising the following processing steps:
[0035] (1) Preparation of pretreatment agent: 30 parts by weight of fluorine-containing copolymer, 15 parts by weight of surfactant, 0.2 parts by weight of dodecyl mercaptan, 3 parts by weight of diacetone acrylamide coupling agent, and 100 parts by weight of deionized water 2 parts by weight are mixed evenly to obtain a pretreatment agent; the preparation method of fluorine-containing copolymer is to mix 20 parts by weight of trifluoroethyl acrylate, 10 parts by weight of propylene chloride, 8 parts by weight of acrylic acid, and 100 parts by weight of distilled water, and then add anhydrous 7 parts by weight of sodium sulfate and 5 parts by weight of ammonium persulfate were used to adjust the pH to 7.5, and the mixture was stirred and reacted for 6 hours at a temperature of 58° C. to obtain a fluorine-containing copolymer. Surfactan...
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