Surface protection film, method for producing surface protection film, and optical member
A technology for protecting films and touch panels, applied to film/sheet-shaped adhesives, conductive paints, coatings, etc., can solve problems such as insufficient wettability, defective products, and poor wettability, and achieve Excellent wettability, excellent workability, and good stability over time
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Embodiment 1
[0262] [Preparation of Acrylic Binder Solution]
[0263] The aforementioned (meth)acrylic polymer (A) solution (40% by weight) was diluted to 20% by weight with ethyl acetate, and 500 parts by mass of the solution (100 parts by mass of solid content) was added as a crosslinking agent. 3 parts by mass (3 parts by mass of solid content) of the isocyanurate form of hexamethylene diisocyanate (manufactured by Nippon Polyurethane Industry Co., Ltd., Coronate HX), dibutyltin dilaurate (trade name: OL- 1. Tokyo Fine Chemical Co., Ltd.) (1% by mass of ethyl acetate solution) 3 parts by mass (0.03 parts by mass of solid content), as a crosslinking retarder, 3 parts by mass with respect to 100 parts by mass of the solvent (when converted) Acetylacetone and 0.05 parts by mass of polyethylene glycol (trade name: PEG400, number average molecular weight: 400, manufactured by Sanyo Kasei) as a polyether compound were mixed and stirred to prepare an acrylic adhesive solution.
[0264] [Produ...
Embodiment 2~10 and comparative example 1~4
[0267] Based on the compounding contents of Tables 1 to 3, a surface protection film was produced in the same manner as in Example 1.
[0268] Table 4 and Table 5 show the results of the above-mentioned various measurements and evaluations for the surface protection films of Examples and Comparative Examples.
[0269] The abbreviations in Table 1 and Table 3 are explained below.
[0270] 2EHA: 2-Ethylhexyl Acrylate
[0271] HEA: 2-Hydroxyethyl Acrylate
[0272] 4HBA: 4-Hydroxybutyl Acrylate
[0273] AA: Acrylic
[0274] ADEKA Pluronic 25R-1: Polyoxyethylene-polyoxypropylene block copolymer (manufactured by ADEKA, polyether compound)
[0275] Surfynol 420: Polyether compound of 2,4,7,9-tetramethyl-5-decyne-4,7-diol (manufactured by Nissin Chemical Co., Ltd., polyether compound)
[0276] Surfynol 485: Polyether compound of 2,4,7,9-tetramethyl-5-decyne-4,7-diol (manufactured by Nissin Chemical Co., Ltd., polyether compound)
[0277] Aqualon HS-10: Polyoxyethylene nonylprope...
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