A low-cost converter steelmaking deoxidation process

A converter steelmaking, low-cost technology, applied in the direction of manufacturing converters, etc., can solve the problems of high cost per ton of steel, increase of non-metallic inclusions, and carbonization of molten steel, so as to reduce the content of non-metallic inclusions, reduce oxide inclusions, and improve Effect of molten steel quality

Active Publication Date: 2018-08-31
RIZHAO BAOHUA NEW MATERIAL CO LTD
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Problems solved by technology

At present, the deoxidation methods used in the domestic industrial steelmaking production process mainly include: aluminum deoxidation method, adding metal aluminum to the molten steel in the ladle when tapping the steel. This deoxidation method is relatively simple, but the deoxidation effect is unstable, and Al is easy to form 2 o 3 Such non-metallic inclusions, small particles of such inclusions are not easy to float up into slag, resulting in an increase of non-metallic inclusions in steel, and the price of aluminum exceeds 10,000 yuan / ton, and the cost of steel per ton is high; carbon deoxidation method is added to the ladle before tapping For carbon-containing materials, this deoxidation method is relatively simple, and the deoxidation effect is also unstable, which is prone to safety hazards caused by molten steel "turning over" and will increase the carbon content of molten steel; there are also methods such as silicon-calcium alloy deoxidation method, core wire deoxidation method, etc. , although the deoxidation effect of these methods is better, but the cost is higher
[0003] For example, the patent "Converter Steelmaking Deoxidizer" (application number: 89105941.5) discloses that a deoxidizer is put into the ladle for deoxidation before tapping, and the composition of the deoxidizer is (% by weight): 65-96% CaC 2 , 4-35% SiC, this method is due to the deoxidation ability of Si, Ca>C, Si and Ca are deoxidized first in molten steel, and carbon is easy to react incompletely to produce carbon increase; patent "a low-cost electric arc furnace tapping deoxidation process "(Application No.: CN200710031301) discloses a three-step deoxidation process of carbon powder pre-deoxidation, ferrosilicon shallow deoxidation, and aluminum block deep deoxidation. Although this method can reduce the deoxidation cost, a large amount of aluminum is added to produce Al 2 o 3 Such inclusions are not easy to remove by slag, and increase the viscosity of molten steel, which is easy to cause flocculation in the casting machine

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  • A low-cost converter steelmaking deoxidation process

Examples

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Comparison scheme
Effect test

Embodiment 1

[0024] For killed steel (steel grade A36Cr) process steps:

[0025] (1) Open the ladle to the tapping position of the converter, open the bottom blowing system, and the bottom blowing flow rate is 300m 3 / h;

[0026] (2) The timing starts when the steel is placed in the shaking furnace, and 0.58 kg / t of carbon powder is added after 20 seconds of tapping (the amount added per ton of steel is 0.58 kg), and the carbon powder is added within 40 seconds after tapping. In order to better achieve carbon powder deoxidation, the bottom blowing flow rate is reduced to 200m after adding carbon 3 / h, at this time, the carbon powder deoxidizes to generate CO gas to participate in the stirring of molten steel. In addition, in order to prevent the molten steel from "turning over" by adding carbon powder too early and causing safety accidents, the general tapping time is about 7 minutes, so the appropriate time to add simple carbon powder is within 20-60 seconds after tapping to ensure that...

Embodiment 2

[0032] For killed steel (steel type Q345B3) deoxidation process steps:

[0033] (1) Open the ladle to the tapping position of the converter, open the bottom blowing system, and the bottom blowing flow rate is 250m 3 / h;

[0034] (2) The timing starts when the steel is placed in the shaking furnace, and 0.36kg / t of simple carbon powder is added after 40 seconds of tapping. After adding carbon, the bottom blowing flow rate is reduced to 150m 3 / h, the simple carbon powder is added within 60S after tapping;

[0035] (3) After the carbon powder is added at an interval of 25S, add a composite deoxidizer 1.5kg / t, and all the composite deoxidizers are added within the time range of 80S to 130S after tapping; the composition (mass fraction) of the composite deoxidizer is 47.5% silicon, 24.5% calcium, 28% barium.

[0036] Specifically, in this embodiment, the simple carbon powder is added in 60 s after tapping, and all the composite deoxidizers are added in 130 s.

Embodiment 3

[0038] For killed steel (steel type Q235B2) deoxidation process steps:

[0039] (1) Open the ladle to the tapping position of the converter, open the bottom blowing system, and the bottom blowing flow rate is 200m 3 / h;

[0040] (2) The timing starts when the steel is placed in the shaking furnace, and 0.17kg / t of simple carbon powder is added after 58 seconds of tapping. After adding carbon, the bottom blowing flow rate is reduced to 100m 3 / h, the simple carbon powder is added within 60S after tapping;

[0041] (3) After the carbon powder is added at an interval of 20S, add a composite deoxidizer 1.8kg / t, and all the composite deoxidizers are added within the time range of 130S to 180S after tapping; the composition (mass fraction) of the composite deoxidizer is 44.4% silicon, 25.9% calcium, 27.7% barium and 2% aluminum.

[0042] Specifically, in this embodiment, the simple carbon powder is added in 60 s after tapping, and all the composite deoxidizers are added in 180 s...

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Abstract

The invention discloses a low-cost converter steelmaking deoxidization process. The process is characterized in that in the converter steel tapping process, carbon powder and a composite deoxidization agent are added for segmented deoxidization, the content of total oxygen in molten steel is reduced by controlling the deoxidization occasion and optimizing the steel tapping deoxidization operation process, the low-price carbon powder and the composite deoxidization agent are used for replacing a traditional aluminum and iron deoxidization agent, deoxidization cost can be greatly reduced, and meanwhile, non-metallic inclusion is reduced. By means of the deoxidization process, the ratio of inclusion, with the level smaller than or equal to 1.5, in steel is increased to 98.21%, the continuous casting fluctuation flow rate is reduced to 0.32%, the deoxidization cost of each ton of steel is reduced by 1.58 RMB yuan, and profit margin is increased for enterprises while steel quality is improved.

Description

technical field [0001] The invention belongs to the technical field of steelmaking production, in particular to a low-cost converter steelmaking deoxidation process. Background technique [0002] Excessive oxygen is dissolved into the molten steel at the end of converter steelmaking, and the excess oxygen precipitates out when the molten steel solidifies to form oxide inclusions and bubbles, which directly affect the quality of cast slabs and steel products. Therefore, in the steelmaking process, it is necessary to reduce the oxygen content at the end of the converter, which is the source of inclusions in the steel. At present, the deoxidation methods used in the domestic industrial steelmaking production process mainly include: aluminum deoxidation method, adding metal aluminum to the molten steel in the ladle when tapping the steel. This deoxidation method is relatively simple, but the deoxidation effect is unstable, and Al is easy to form 2 o 3 Such non-metallic inclusi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C21C7/06C21C7/064C21C5/28
CPCC21C5/28C21C7/0006C21C7/0025C21C7/06C21C7/064C21C7/0645
Inventor 蒲锐张云田孙作迎朱国军王刚
Owner RIZHAO BAOHUA NEW MATERIAL CO LTD
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