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Admixture for improving mechanical properties of cement-based materials and preparation method of admixture

A cement-based material and admixture technology, which is applied in the field of admixtures for cement-based material modification, can solve the problems of complex preparation process of the admixture, lowering the strength of the cement-based material, and high cost.

Active Publication Date: 2016-06-29
JIANGSU SOBUTE NEW MATERIALS +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0016] Existing admixtures cannot fundamentally solve the problem of brittleness of cement-based materials, and even if the problem can be alleviated to a certain extent, the strength of cement-based materials will be lowered, or the preparation process of admixtures is complicated, or the cost is too high, and Various bugs where the app is limited, etc.

Method used

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  • Admixture for improving mechanical properties of cement-based materials and preparation method of admixture
  • Admixture for improving mechanical properties of cement-based materials and preparation method of admixture
  • Admixture for improving mechanical properties of cement-based materials and preparation method of admixture

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0110] (1) Add polymerizable monomer A (code A1, polyethylene glycol methacrylate, -CH in the polyethylene glycol chain) to the reactor 2 CH 2 O-the average number of repeating units is 6, the terminal group is a hydroxyl group, and the dosage is 0.4 parts), polymerizable monomer B (4 parts of styrene (St)), siloxane D (8.09 parts of tetramethoxysilane (TMOS) and Tetraethoxysilane (44.30 parts of TEOS) and 270 parts of water, adjust the pH of the mixed solution to 10 with 1mol / LNaOH, fully stir and mix; logical N in the mixed solution 2 Divide O 2 , the temperature of the reactor was raised to 80°C, and the initiator (0.1 parts of ammonium persulfate APS dissolved in 29.9 parts of water) was added to the reactor under stirring conditions to initiate polymerization, and at the same time, the dropwise addition of siloxane D was started to the reactor. The remaining part (TMOS72.81 parts and TEOS398.66 parts) and polymerizable monomer E (St36 parts), timing since the initiator ...

Embodiment 2

[0113] (1) Add polymerizable monomer A (number A2, polyethylene glycol monomethyl ether acrylate, -CH in the polyethylene glycol chain) to the reactor 2 CH 2 O-the average number of repeating units is 22, the terminal group is methyl, and the dosage is 4 parts), polymerizable monomer B (methyl methacrylate (MMA) 50 parts), crosslinking agent C (number C2, ethylene glycol Diacrylate, -CH 2 CH 2 O-the average number of repeating units is 45, 2 parts), 6 parts of APS and 270 parts of water, fully stir and mix; use 1mol / LNaOH to adjust the pH of the mixed solution to 10, and pass N into the mixed solution 2 Divide O 2 , the temperature of the reactor was raised to 70°C, and the siloxane D (TEOS326.11 parts), the polymerizable monomer E (butyl acrylate (BA), 50 parts) and the initiator were evenly added dropwise to the reactor under stirring conditions. The solution (3.28 parts of sodium bisulfite SBS dissolved in 26.72 parts of water) initiates the polymerization. When the ini...

Embodiment 3

[0116] (1) Add polymerizable monomer A (code A3, polyethylene glycol monomethyl ether methacrylate, -CH in polyethylene glycol chain) to the reactor 2 CH 2 O-the average number of repeating units is 45, and the dosage is 10.00 parts), polymerizable monomer B (lauryl acrylate (LA) 160 parts), crosslinking agent C (divinylbenzene (DVB) 4 parts, commercial DVB contains position and para isomers), siloxane D (24.19 parts of phenyltriethoxysilane (PhTEOS) and 45.10 parts of TEOS) and 270 parts of water, stir and mix thoroughly; use 1mol / LH 2 SO 4 Adjust the pH of the mixture to 3, pass N into the mixture 2 Divide O 2 , the temperature of the reactor was raised to 60°C, and the initiator (2 parts of azobisisobutylamidine hydrochloride V50 dissolved in 28 parts of water) was added to the reactor under stirring conditions to initiate polymerization, and the reaction was started from the addition of the initiator The timer was used to react for 12 hours, and then the protection of ...

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Abstract

The invention discloses an admixture for improving mechanical properties of cement-based materials. The admixture is aqueous dispersion of organic-inorganic hybrid particles, the organic-inorganic hybrid particles account for 5-40% of the aqueous dispersion, and each particle is in a two-layer structure including an inner layer and an outer layer. The inner layers comprise organic components and inorganic components, wherein no covalent bond exists between the organic components and the inorganic components, and the inorganic components and the organic components are respectively connected through covalent bonds to form a polymer network. Each outer layer is a layer of electronegative organic polyelectrolytes with long side chains. The admixture for improving the mechanical properties of the cement-based materials is beneficial to improvement of compressive strength of the cement-based materials, and the more the admixture is doped, the more evidently the mechanical properties of the cement-based materials are improved.

Description

technical field [0001] The invention relates to the field of admixtures used for modifying cement-based materials, in particular to an admixture capable of improving the mechanical properties of cement-based materials. Background technique [0002] Cement-based materials refer to materials such as concrete, mortar, and grouting. As the most widely used building material in the world, cement-based materials continue to expand their application fields, but complex and diverse construction and use environments continue to put forward higher requirements for their performance. Therefore, improving their mechanical properties is an inevitable trend of its development. [0003] Ordinary cement-based material is a typical brittle material, which has high compressive strength, but obviously insufficient bending and tensile strength. In actual use, it is easy to produce various cracks or damage due to stress concentration or uneven force, making The durability decreases, which limit...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B20/10C04B22/06C04B24/26C04B24/16C08F212/08C08F220/28C08F220/06C08F230/08C08F283/06C08F2/44
CPCC04B20/1051C04B22/06C04B24/163C04B24/2647C04B24/2694C08F2/44C08F212/08C08F220/28C08F283/065C08F220/286C08F220/06C08F230/08C08F220/1812C08F222/102C08F220/1804
Inventor 舒鑫严涵杨勇黄振张建纲王秀梅张茜毛永琳冉千平
Owner JIANGSU SOBUTE NEW MATERIALS
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