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A recyclable self-cleaning reflective polymer roofing waterproof membrane and its preparation method

A waterproofing membrane and polymer technology, applied in the field of building materials, can solve the problems of increasing the risk of cancer, shortening the service life of the membrane, and the separation of the coating from the base surface, improving processing fluidity, enhancing light stabilization efficiency, Degradation reduction effect

Active Publication Date: 2017-11-21
中建材苏州防水研究院有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Existing functional polymer waterproof membranes, such as a building heat insulation waterproof membrane disclosed in a Chinese invention patent with the publication number CN 104553093A, adopts a PVC waterproof layer, and a large amount of plasticizer needs to be added in the preparation of the PVC membrane. Improve the flexibility of the coil, but because the plasticizer does not chemically react with the PVC polymer, it is easy to migrate and seep out and gasify during use. The volatilized plasticizer not only endangers human health and increases the risk of cancer, but also Directly shorten the useful life of the coil
The Chinese utility model patent with the authorized announcement number CN 202727448 U discloses a CPE self-adhesive composite waterproof membrane with a reflective heat insulation layer and a building thermal insulation waterproof membrane disclosed by the Chinese invention patent with the publication number CN 104553093A. The metal aluminum foil layer is used as the reflective insulation layer of the coil. The aluminum foil has high hardness and high tensile strength, but its tear strength is small, so it is easy to tear, especially in bad weather. It is most likely to be damaged; moreover, the aluminum foil itself is easily oxidized and the color becomes darker, and the color will fade due to wind friction, acid rain erosion, etc., and long-term use will gradually lose the reflective effect
The authorized announcement number is CN 202106601 U Chinese utility model patent discloses a high-strength antifouling self-cleaning waterproof coiled material, in which the PVDF protective coating layer is used as the self-cleaning layer to achieve the antifouling effect, but the PVDF coating layer on the surface of the coiled material and the lower surface There are big differences in the tensile strength, elongation at break and high and low temperature resistance of the PVC embryo film layer, which may cause the hollowing and cracking of the coating and the base surface after the alternation of seasons; at the same time, the smooth surface During the overlapping process of PVDF coating, whether it is bonding or welding, it will affect the lapping effect, and the weak lapping between the coils will directly cause water channeling and leakage
[0004] To sum up, although there are various self-cleaning and heat-insulating polymer coils in the prior art, these coils have unsatisfactory long-term anti-fouling effects, or the reflective heat-insulating layer is prone to failure, or multi-layer composites and complicated processes , or the construction is difficult, or the durability is poor, and these waterproof membranes cannot be recycled

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] This embodiment provides a recyclable self-cleaning reflective polymer roofing waterproofing membrane. Its raw material formula is as follows in parts by weight: SEBS thermoplastic elastomer (TSRC 6159) 35 parts; TPU thermoplastic polyurethane (Lubrizol R185) 25 parts 5 parts of titanium dioxide (R706); 3 parts of naphthenic oil; 20 parts of hydrophobic silica (AEROSIL 200); 0.32 parts of anti-ultraviolet agent (UV-531); 0.45 parts of light stabilizer (HALS 2020); agent (B225) 0.2 parts.

[0027] The preparation method of waterproof membrane is as follows:

[0028] (a) Dry the thermoplastic polyurethane at 90°C for 3 hours for later use;

[0029](b) Mix 35 parts of SEBS thermoplastic elastomer (TSRC 6159) with 3 parts of naphthenic oil in proportion to obtain oil-extended block copolymer SEBS, and then mix with 25 parts of dried thermoplastic polyurethane (Lubrizol R185), 0.32 parts of anti-ultraviolet agent (UV-531), 0.45 parts of light stabilizer (HALS 2020), 0.2 pa...

Embodiment 2

[0033] This example provides a recyclable self-cleaning reflective polymer roofing waterproof membrane. The raw material formula of the membrane is as follows: SEBS thermoplastic elastomer (Kraton G1652) 40 parts; TPU thermoplastic polyurethane (BASF 1195A) 20 parts; 8 parts of titanium dioxide (R960); 4 parts of white oil; 27 parts of hydrophobic silica (WACKER N-20); 0.4 parts of anti-ultraviolet agent (UV-350); 0.4 parts of light stabilizer (BASF C81); Antioxidant (HP-136) 0.2 parts.

[0034] The preparation method of waterproof membrane is as follows:

[0035] (a) Dry the thermoplastic polyurethane at 100°C for 2 hours for later use;

[0036] (b) Mix 40 parts of SEBS thermoplastic elastomer (Kraton G1652) and 4 parts of white oil uniformly in proportion to obtain oil-extended block copolymer SEBS, and then mix with 20 parts of dried thermoplastic polyurethane (BASF 1195A ), 0.32 parts of anti-ultraviolet agent (UV-350), 0.45 parts of light stabilizer (BASF C81), and 0.2 ...

Embodiment 3

[0040] This example provides a recyclable self-cleaning reflective polymer roof waterproofing membrane. The raw material formula of the membrane is as follows: SEBS thermoplastic elastomer (Kraton G1633) 45 parts; TPU thermoplastic polyurethane (LubrizolR185) 25 parts 6 parts; titanium dioxide (R706) 6 parts; hydrogenated naphthenic oil 3 parts; hydrophobic silica (HL-200) 20 parts; anti-ultraviolet agent (UV-328) 0.25 parts; light stabilizer (HALS 2020) 0.5 parts; Antioxidant (IRGAFOS 168) 0.2 parts.

[0041] The preparation method of waterproof membrane is as follows:

[0042] (a) Dry the thermoplastic polyurethane at 90°C for 3 hours for later use;

[0043] (b) 45 parts of SEBS thermoplastic elastomer (Kraton G1633) and 3 parts of hydrogenated naphthenic oil were evenly mixed in proportion to obtain oil-extended block copolymer SEBS, and then mixed with 25 parts of dried thermoplastic polyurethane ( LubrizolR185), 0.25 parts of anti-ultraviolet agent (UV-328), 0.5 parts o...

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Abstract

The invention relates to a recyclable self-cleaning reflective high polymer roof waterproof roll and a preparation method thereof.The waterproof roll is prepared from, by weight, 30-50 parts of SEBS thermoplastic elastomer, 10-30 parts of thermoplastic polyurethane, 3-8 parts of titanium dioxide, 2-5 parts of filling oil, 15-35 parts of hydrophobic silica, 0.1-0.5 part of ultraviolet-resistant agent, 0.1-0.5 part of light stabilizer and 0.1-0.3 part of antioxidant.No plasticizer is added into a formulation, and a co-extrusion process is not used for multilayer compositing, so that recycling, regeneration, environment protection and energy conservation are realized on the basis that good antifouling, self-cleaning, reflective, heat-insulating, weather-proof and waterproof functions are guaranteed.The preparation method is simple in process and convenient to operate.

Description

technical field [0001] The invention belongs to the technical field of building materials and relates to a waterproof coiled material, in particular to a recyclable self-cleaning reflective polymer roof waterproof coiled material and a preparation method thereof. Background technique [0002] Recently, due to changes in building design and the use of new building components, higher and higher requirements have been placed on roof waterproofing membranes. The "Twelfth Five-Year" Comprehensive Work Plan for Energy Conservation and Emission Reduction issued by the State Council in August 2011 requires reducing energy waste and reducing exhaust emissions, and regards building energy conservation as an important part of my country's energy strategy. The report of the 18th National Congress of the Communist Party of China puts forward for the first time "promoting green development, circular development, and low-carbon development" and "building a beautiful China". However, durin...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L53/02C08L75/04C08K13/02C08K3/36C08K3/22
CPCC08L53/02C08L2201/08C08L2205/03C08L75/04C08L91/00C08L91/06C08K13/02C08K3/36C08K2003/2241
Inventor 王晓莉王文斌董洲卢建华杨胜
Owner 中建材苏州防水研究院有限公司