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High-performance water-based epoxy resin automobile paint and preparation method thereof

A water-based epoxy resin and epoxy resin technology, used in epoxy resin coatings, anti-corrosion coatings, coatings, etc., can solve the problems of large dispersed phase size and poor stability, and achieve low cost, good stability, and adhesion. high effect

Inactive Publication Date: 2016-08-24
HUBEI JIAJI SYNTHESIS MATERIALS CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the emulsion prepared by the phase inversion method is affected by the addition of emulsifiers, the size of the dispersed phase is too large, and the stability is poor.

Method used

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  • High-performance water-based epoxy resin automobile paint and preparation method thereof
  • High-performance water-based epoxy resin automobile paint and preparation method thereof
  • High-performance water-based epoxy resin automobile paint and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] The preparation method of high-performance water-based epoxy resin automobile coating of the present invention, step is:

[0033] a. Preparation of emulsifier X

[0034] Add 10 parts of epoxy resin E20 and 50 parts of polypolyol PEG6000 in parts by weight into a four-necked flask equipped with a stirrer, a condenser tube and a thermometer, and add the catalyst boron trifluoride dropwise after the two are completely melted. 0.5 part of diethyl ether complex, react at 100°C for 3 hours, add 60 parts of deionized water to obtain light yellow transparent epoxy resin emulsifier X;

[0035] b. Preparation of component A

[0036] Add 3 parts by weight of emulsifier X (prepared in step a) and 3 parts of co-solvent propylene glycol methyl ether to 60 parts of epoxy resin E20, control the temperature of the system at 50 ° C, stir rapidly for 50 minutes, and then add it dropwise. Ionized water until the viscosity of the system suddenly decreases and a uniform emulsion is formed ...

Embodiment 2

[0042] The preparation method of high-performance water-based epoxy resin automobile coating of the present invention, step is:

[0043] a. Preparation of emulsifier X

[0044] 10 parts by weight of epoxy resin E44 and 50 parts of polypolyol PEG4000 are added to a four-necked flask equipped with a stirrer, a condenser tube and a thermometer, and the catalyst dilauric acid dilaurate is added dropwise after the two are completely melted. 1 part of butyltin was reacted at 80°C for 4 hours, and 60 parts of deionized water was added to obtain light yellow transparent epoxy resin emulsifier X;

[0045] b. Preparation of component A

[0046] Add 3 parts by weight of emulsifier X (prepared in step a) and 4 parts of cosolvent ethylene glycol butyl ether to 60 parts of epoxy resin E44, control the temperature of the system at 50 °C, stir rapidly for 40 minutes, drop by drop Add deionized water until the viscosity of the system suddenly decreases to form a uniform emulsion, and continu...

Embodiment 3

[0052] The preparation method of high-performance water-based epoxy resin automobile coating of the present invention, step is:

[0053] a. Preparation of emulsifier X

[0054] Add 10 parts of epoxy resin E51 and 50 parts of polypolyol PPG3000 in parts by weight into a four-necked flask equipped with a stirrer, condenser tube and thermometer, and add the catalyst triphenylphosphine dropwise after the two are completely melted. 0.8 parts, react at 90°C for 5 hours, add 60 parts of deionized water to obtain light yellow transparent epoxy resin emulsifier X;

[0055] b. Preparation of component A

[0056] Add 3 parts by weight of emulsifier X (prepared in step a) and 2 parts of diethylene glycol monomethyl ether as a cosolvent to 60 parts of epoxy resin E51, control the temperature of the system at 60°C, and stir rapidly for 30 minutes. Add deionized water dropwise until the viscosity of the system suddenly decreases and a uniform emulsion is formed, and continue to add deioniz...

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PUM

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Abstract

The invention discloses a high-performance water-based epoxy resin automobile paint and a preparation method thereof. The automobile paint comprises the following components in parts by weight: 30-60 parts of component A and 30-90 parts of component B. The component A comprises 30-60 parts of epoxy resin M, 1-10 parts of emulsifier X, 1-10 parts of cosolvent and 30-60 parts of deionized water. The component B comprises 0-30 parts of pigment, 10-30 parts of amine curing agent, 30-60 parts of deionized water, 0.1-3 parts of organosilicon leveling agent, 0.1-3 parts of polylol wetting agent, 1-5 parts of dispersing agent, 0.1-2 parts of preservative, 0.5-2 parts of emulsifier Y, 0.2-2 parts of pH regulator and 0.2-2 parts of defoaming agent. The whole paint uses water as the medium and only needs a small amount of cosolvent, so the VOC (volatile organic compound) content is greatly lowered, and the environmental pollution is small. The phase-reversal method used for preparing the water-based epoxy resin emulsion directly adopts mechanical dispersion without chemical reaction, and thus, has the advantages of simple equipment and low cost.

Description

technical field [0001] The invention relates to the field of chemical materials, in particular to a high-performance water-based epoxy resin automotive coating and a preparation method thereof. Background technique [0002] Due to its high chemical stability, corrosion resistance, good adhesion and mechanical properties, epoxy resin is widely used in construction, shipbuilding, automobiles, aerospace, machinery manufacturing, chemical building materials and other fields, especially in coatings It is more widely used in the industrial field. However, most epoxy coatings are solvent-based at present. With the development of society and the improvement of environmental protection awareness, people's requirements for chemical products are becoming more and more stringent. The coating industry is developing in the direction of high efficiency, energy saving, and ecology. [0003] The automobile industry is one of the four pillar industries in my country, and the demand for autom...

Claims

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Application Information

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IPC IPC(8): C09D163/00C09D5/08C09D7/12C09D7/00
CPCC09D163/00C08L2205/025C08L2205/035C09D5/08C09D7/20C09D7/65C08L63/00C08L71/02
Inventor 张智力管蓉潘恒张探鲁德平叶红
Owner HUBEI JIAJI SYNTHESIS MATERIALS CO LTD
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