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Preparation process of a radiochromic label dosimeter

A technology of radiation discoloration and preparation technology, which is applied in the field of radiation discoloration label dosimeter and preparation technology, which can solve the problems of inconvenient use, difficult release, low drying temperature, etc., and achieve the goal of broadening the application range, uniform and smooth film formation, and avoiding wrinkles Effect

Active Publication Date: 2019-08-06
CHINA INSTITUTE OF ATOMIC ENERGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In 2013, Cai Zhanfan and others published a patent document titled "A Preparation Method for Radiation-Changing Film". The preparation method has the following defects: 1. Dry and solidify at a temperature of 10°C to 50°C and a humidity of 20% to 70% to form a film, the drying temperature is low, the curing and drying time is long, the environment is greatly affected, and the efficiency is low ; 2. The film-forming solution is evenly coated on the horizontal plane support, which is difficult to release the film and is easy to curl and wrinkle, and is not suitable for mass production; 3. The dose meter prepared by this preparation method in the radiation field also needs to be manually pasted It is inconvenient to use after pasting the adhesive layer on a certain position

Method used

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  • Preparation process of a radiochromic label dosimeter
  • Preparation process of a radiochromic label dosimeter

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] A radiochromic label dosimeter, the dosimeter comprises a sensitive layer 1, a base layer 2, an adhesive layer 3 and a release paper layer 4 in order from top to bottom; the thickness of the sensitive layer 1 is 75 μm, and the thickness of the base layer 2 The thickness is 50 μm.

[0040] The formula of the sensitive layer 1 includes polymer polyvinyl alcohol, acid-sensitive dye methyl orange, auxiliary color-changing substance chloral hydrate and first solvent water, the weight and number ratio of polymer, acid-sensitive dye, auxiliary color-changing substance, and solvent It is 100:0.2:10:700.

[0041] The formula of the base layer 2 includes a base layer material and a second solvent, wherein the base material is polyacrylate, and the second solvent is ethanol; the ratio of parts by weight of the base material to the solvent is 1:7;

[0042] The adhesive layer 3 and the peeling paper layer 4 are self-adhesive paper, wherein the self-adhesive paper is a double-sided ...

Embodiment 2

[0051] The difference from Example 1 is that the acid-sensitive dye is a mixture of methyl orange and bromocresol green, the ratio of parts by weight is 1:1, and the color of the dosimeter will change from green to red through yellow within a certain radiation dose range .

Embodiment 3

[0053] The difference from Example 1 is that the thickness of the sensitive layer is 50 μm, and the thickness of the base layer is 20 μm.

[0054] In the formula of the sensitive layer, the polymer is 100 parts (parts by weight), the acid-sensitive dye is 0.1 parts (parts by weight), the auxiliary discoloration substance is 5 parts (parts by weight), and the first solvent is 6000 parts (parts by weight). number of parts); the polymer is one of polyvinyl chloride (PVC), polyvinylidene chloride (PVDC), polyvinyl butyral (PVB), polymethyl methacrylate (PMMA), nylon or Various; the acid-sensitive dyes are dimethyl yellow, bromophenol blue, neutral red, alizarin red, crystal violet, bromocresol green, methylene blue, xylenol orange, alizarin, phenolphthalein, thymolphthalein One or more of , methyl violet, malachite green, thymol blue, bromothymol blue, methyl red, Congo red, aniline blue, bromocresol violet, and cresol red; The auxiliary discoloration substance is one or more of ...

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Abstract

The invention belongs to the technical field of dosimeters and discloses a radiated discoloring label dosimeter and a preparation process. The dosimeter comprises a sensitive layer, a base layer, an adhesive layer and a stripping paper layer in the sequence from top to bottom, wherein the sensitive layer is prepared from a polymer, an acid-sensitive dye, an auxiliary discoloring substance and a first solvent, and the base layer is prepared from a base layer material and a second solvent. The process includes the steps that 1, the polymer is dissolved in the first solvent; 2, the auxiliary discoloring substance and the acid-sensitive dye are added to obtain a first solution; 3, the base layer material is dissolved in the second solvent to obtain a second solution; 4, the non-setting adhesive is coated with the second solution, and the upper portion of the base layer is coated with the first solution; 5, drying is performed; 6, cutting is performed by adopting a die cutting machine and a half cutting mode. The radiated discoloring label dosimeter has the advantages that semi-quantitative or qualitative detection of irradiation dose can be performed, a formed film is uniform and flat, and mold release is not needed.

Description

technical field [0001] The invention belongs to the technical field of dosimeters, and in particular relates to a radiochromic label dosimeter and a preparation process. Background technique [0002] Radiation-changing label dosimeters are usually opaque adhesive labels that change color obviously under a certain amount of ionizing radiation. The dosimeter indicates the absorbed dose through the degree of color change. It can be used for visual observation and estimation of dose levels, and is suitable for qualitative and semi-quantitative applications. field. [0003] In 2013, Cai Zhanfan and others published a patent document titled "A Preparation Method for Radiation-Changing Film". The preparation method has the following defects: 1. Dry and solidify at a temperature of 10°C to 50°C and a humidity of 20% to 70% to form a film, the drying temperature is low, the curing and drying time is long, the environment is greatly affected, and the efficiency is low ; 2. The film-...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J7/24C09J7/25C09J7/20G01T1/04
CPCC09J7/22C09J7/245C09J7/255C09J2401/00C09J2421/00C09J2427/00C09J2429/00C09J2433/00C09J2467/00G01T1/04
Inventor 罗瑞叶宏生陈义珍徐利军张卫东李明
Owner CHINA INSTITUTE OF ATOMIC ENERGY
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